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Symposium EC1 : Redox Activity on the Molecular Level—Fundamental Studies and Applications

2016-11-28   Show All Abstracts

Symposium Organizers

Susan Odom, University of Kentucky
Mitchell Anstey, Davidson College
Luis Campos, Columbia University
Neil Tomson, University of Pennsylvania
EC1.1: Redox Shuttles and Mitigators in Energy Storage Devices
Session Chairs
Susan Odom
Neil Tomson
Monday AM, November 28, 2016
Sheraton, 3rd Floor, Berkeley AB

8:00 AM - *EC1.1.01
The Vital Role of Molecular Redox Mediators and Phase Transfer Catalysts in Aprotic Metal-Oxygen Batteries

Chun Xia 1 , Dipan Kundu 1 , Robert Black 1 , Ivan Kochetkov 1 , Russel Fernandes 1 , Youenn Pointel 1 , Linda Nazar 1

1 Department of Chemistry University of Waterloo Waterloo Canada

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8:30 AM - *EC1.1.02
Mediating the Redox Reactions at the O 2 Electrode in Li-O 2 Batteries

Peter Bruce 1 , Xiangwen Gao 1 , Yuhui Chen 1 , Lee Johnson 1

1 Departments of Materials and Chemistry University of Oxford Oxford United States Minor Outlying Islands

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9:00 AM - *EC1.1.03
#xD; Electroactive Ionic Liquids as Redox Systems in Energy Storage Devices

Dominic Rochefort 1 , Bruno Gelinas 1 , Han Jin Xie 1

1 University of Montreal Montreal Canada

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9:30 AM - EC1.1.04
Redox Activity of Pseudohalides for Energy Enhancement and Overcharging Protection in Electrochemical Capacitors

Krzysztof Fic 1 , Barbara Gorska 1 , Paulina Bujewska 1 , Francois Beguin 1 , Elzbieta Frackowiak 1

1 Poznan University of Technology Poznan Poland

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9:45 AM -
BREAK

EC1.2: Non-Aqueous Redox Flow Batteries
Session Chairs
Peter Bruce
Linda Nazar
Monday AM, November 28, 2016
Sheraton, 3rd Floor, Berkeley AB

10:15 AM - *EC1.2.01
The Impact of Inter-Pendant Interactions on the Electrochemical Response of Redox-Active Polymers for Size-Exclusion Flow Batteries

Mark Burgess 1 , Kenneth Hernandez-Burgos 1 , Etienne Chenard 1 , Gavvalapalli Nagarjuna 1 , Kevin Cheng 1 , Jeffrey Moore 1 , Joaquin Rodriguez-Lopez 1

1 University of Illinois at Urbana-Champaign Urbana United States

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10:45 AM - EC1.2.02
Chemical and Electrochemical Charging of Redox-Targeting Lithium-Sulfur Flow Batteries

Jingfa Li 1 2 , Liuqing Yang 1 , Boyu Yuan 1 3 , Jim Lee 1

1 National University of Singapore Singapore Singapore, 2 Nanjing University of Information Science and Technology Nanjing China, 3 Jiangsu Normal University Xuzhou China

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11:00 AM - EC1.2.03
Lessons from Nature on the Design of Nonaqueous Flow Battery Electrolytes

Patrick Cappillino 1 , Haobo Huang 1 , Rachael Howland 1

1 Chemistry and Biochemistry University of Massachusetts Dartmouth Dartmouth United States

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11:15 AM - EC1.2.04
Pushing the Energy Storage Limit of Catholyte for Rechargeable Flow Batteries

Ruidong Yang 1 , Kensuke Takechi 1

1 Toyota Research Institute of North America Ann Arbor United States

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11:30 AM - EC1.2.05
Electrochemical Interrogation of Redox Active Polymer Particles for Energy Storage

Kenneth Hernandez-Burgos 1 , Jingshu Hui 1 , Zachary Gossage 1 , Mark Burgess 1 , Jeffrey Moore 1 , Joaquin Rodriguez-Lopez 1

1 University of Illinois at Urbana-Champaign Urbana United States

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11:45 AM - EC1.2.06
Subtractively Normalized In Situ FTIR for Resolving Complex Reaction Mechanisms in Non-Aqueous Electrolytes

Emily Carino 2 3 , Rajeev Assary 1 3 , Nenad Markovic 1 3 , Fikile Brushett 4 3

2 Argonne National Laboratory Lemont United States, 3 Joint Center for Energy Storage Research Lemont United States, 1 Argonne National Laboratory Chicago United States, 4 Chemical Engineering Massachusetts Institute of Technology Cambridge United States

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EC1.3/ES2.2: Joint Session: Redox-Active Molecules in RFB
Session Chairs
Susan Odom
Dominic Rochefort
Wei Wang
Monday PM, November 28, 2016
Sheraton, 2nd Floor, Liberty BC

1:30 PM - *EC1.3.01/ES2.2.01
On the Electrochemical and Chemical Reactions of Anthraquinone Disulfonic Acid in Aqueous Electrolytes

Fikile Brushett 1 2 , Thomas Carney 1 2 , Steven Collins 1

1 Massachusetts Institute of Technology Cambridge United States, 2 Joint Center for Energy Storage Research Argonne United States

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2:00 PM - *EC1.3.02/ES2.2.02
Adopting Organic Electrochemistry to Redox Flow Batteries

Xiaoliang Wei 1 4 , Wei Wang 1 , Wentao Duan 1 4 , Lu Zhang 2 4 , Fikile Brushett 3 4 , Zheng Yang 1 4 , Bin Li 1 , Zimin Nie 1 , Vijayakumar Murugesan 1 4 , David Reed 1 , Vincent Sprenkle 1

1 Pacific Northwest National Laboratory Richland United States, 4 Joint Center for Energy Storage Research Argonne United States, 2 Argonne National Laboratory Argonne United States, 3 Massachusetts Institute of Technology Cambridge United States

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2:30 PM - EC1.3.03/ES2.2.03
Towards Lean Electrolytes for Nonaqueous Redox Flow Batteries

Jarrod Milshtein 1 2 , Sydney Laramie 2 3 , Tanya Breault 2 3 , Levi Thompson 2 3 , Fikile Brushett 2 4

1 Materials Science and Engineering Massachusetts Institute of Technology Cambridge United States, 2 Joint Center for Energy Storage Research Lemont United States, 3 Chemical Engineering University of Michigan Ann Arbor United States, 4 Chemical Engineering Massachusetts Institute of Technology Cambridge United States

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2:45 PM - EC1.3.04/ES2.2.04
Validating a Size-Exclusion Approach to Non-Aqueous Redox Flow Batteries Using Redox Active Polymers

Elena Montoto 1 , Gavvalapalli Nagarjuna 1 , Jeffrey Moore 1 2 3 , Joaquin Rodriguez-Lopez 1

1 Chemistry University of Illinois at Urbana-Champaign Urbana United States, 2 Materials Science and Engineering University of Illinois at Urbana-Champaign Urbana United States, 3 Beckman Institute of Advanced Science and Technology, University of Illinois at Urbana-Champaign Urbana United States

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3:00 PM -
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3:30 PM - *EC1.3.05/ES2.2.05
Building Stable Radical Cations for Non-Aqueous Redox Flow Batteries

Lu Zhang 1 , Siu On Tung 4 , Rajeev Assary 1 , Fikile Brushett 2 , Wentao Duan 3 , Xiaoliang Wei 3 , Larry Curtiss 1 , Levi Thompson 4

1 Argonne National Laboratory Lemont United States, 4 Department of Chemical Engineering University of Michigan Ann Arbor United States, 2 Department of Chemical Engineering Massachusetts Institute of Technology Cambridge United States, 3 Electrochemical Materials and Systems Pacific Northwest National Laboratory Richland United States

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4:00 PM - *EC1.3.06/ES2.2.06
Organic Aqueous Flow Batteries for Massive Electrical Energy Storage

Michael Aziz 1

1 Harvard University Cambridge United States

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4:30 PM - EC1.3.07/ES2.2.07
Anthraquinone Derivatives in Aqueous Flow Batteries

Michael Gerhardt 1 , Liuchuan Tong 1 , Rafael Gomez-Bombarelli 1 , Qing Chen 1 , Alan Aspuru-Guzik 1 , Roy Gordon 1 , Michael Aziz 1

1 Harvard University Cambridge United States

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4:45 PM - EC1.3.08/ES2.2.08
Molecular Interactions in Quinone-Based Flow Batteries

Qing Chen 1 2 , Liuchuan Tong 3 , Andrew Wong 1 , Rafael Gomez-Bombarelli 1 , Alan Aspuru-Guzik 3 , Roy Gordon 1 , Michael Aziz 1

1 Harvard University Cambridge United States, 2 Hong Kong University of Science and Technology Hong Kong Hong Kong, 3 Harvard University Cambridge United States

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2016-11-29   Show All Abstracts

Symposium Organizers

Susan Odom, University of Kentucky
Mitchell Anstey, Davidson College
Luis Campos, Columbia University
Neil Tomson, University of Pennsylvania
EC1.4: Conjugated Polymers and Supramolecular Structures
Session Chairs
Mitchell Anstey
Erwin Reisner
Aron Walsh
Xiaoliang Wei
Tuesday AM, November 29, 2016
Sheraton, 3rd Floor, Berkeley AB

8:30 AM - *EC1.4.01
Redox-Active Molecule-Based Frameworks for Energy Storage—Rechargeable Li Batteries of Molecular Clusters, MOFs and COFs

Kunio Awaga 1

1 Nagoya University Nagoya Japan

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9:00 AM - EC1.4.02
Understanding the Redox Properties of Perylene Bisimide Based Self-Assembled Materials

Martijn Zwijnenburg 1

1 University College London London United Kingdom

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9:00 AM - EC1.4.03
Composite Metal-Organic Assemblies—Redirecting Electron Transfer

Renata Balgley 1 , Michal Lahav 1 , Milko Van der Boom 1

1 Weizmann Institute of Science Rehovot Israel

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9:15 AM - *EC1.4.04
Electrifying Metal-Organic Frameworks—Absolute Electron Energies

Aron Walsh 1

1 Imperial College London London United Kingdom

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9:45 AM - EC1.4.05
Covalent Organic Framework-Graft-Polysulfide as Cathode for High-Performance Lithium-Sulfur Batteries

Yang Wu 1 , Zhongyue Zhang 1 , Kunio Awaga 1

1 Research Center for Materials Science and Department of Chemistry Nagoya University Nagoya Japan

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10:00 AM - *
BREAK

10:30 AM - *EC1.4.06
Redox Activity in Conjugated and Organic Radical Polymers

Jodie Lutkenhaus 1 2

1 Artie McFerrin Department of Chemical Engineering Texas Aamp;M University College Station United States, 2 Department of Materials Science and Engineering Texas Aamp;M University College Station United States

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11:00 AM - EC1.4.07
Hybrid Organic Electrodes—The Rational Design and Synthesis of High-Energy Redox-Active Pendant Decorated Polypyrroles for Electrochemical Energy Storage

Luxi Shen 1 , Masato Mizutani 1 , Geoffrey Coates 1 , Hector Abruna 1

1 Cornell University Ithaca United States

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11:15 AM - EC1.4.08
Elucidating the Charge Transfer Mechanism in Conjugated Radical Polymers

Fei Li 1 , Jodie Lutkenhaus 1 2

1 Artie McFerrin Department of Chemical Engineering Texas Aamp;M University College Station United States, 2 Department of Materials Science amp; Engineering Texas Aamp;M University College Station United States

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11:30 AM - EC1.4.09
Investigation of Charge and Mass Transfer of an Electro-Active Nitroxide Radical Polymer

Shaoyang Wang 1 , Fei Li 1 , Jodie Lutkenhaus 1

1 Artie McFerrin Department of Chemical Engineering Texas Aamp;M University College Station United States

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11:45 AM - EC1.4.10
Elucidating Solid State Redox Reaction Rate and Stability in Radical Polymer Thin Films

Bryan Boudouris 1

1 Purdue University West Lafayette United States

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EC1.5: Synthesis and Catalysis
Session Chairs
Kevin Moeller
Chad Risko
Tuesday PM, November 29, 2016
Sheraton, 3rd Floor, Berkeley AB

1:30 PM - *EC1.5.01
Unifying the Redox Reactivity of Complementary Heterogeneous and Homogeneous Oxygen Evolution Catalysis

Daniel Nocera 1

1 Harvard University Cambridge United States

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2:00 PM - *EC1.5.02
Closing the Redox Cycle in Artificial Photosynthesis

Erwin Reisner 1

1 University of Cambridge Cambridge United Kingdom

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2:30 PM - *EC1.5.03
Electrochemical and Photoredox Approaches to Metal-Free Ring-Opening Metathesis Polymerization

Andrew Boydston 1

1 University of Washington Seattle United States

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3:00 PM - EC1.5.04
Mesoporous Copper/Manganese Oxide-Catalyzed Coupling of Alkynes—Combination of Morphological Design and Redox Chemistry

Sourav Biswas 1 , Angelo Rossi 1 , Steven Suib 1

1 University of Connecticut Storrs Mansfield United States

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EC1.6: Poster Session
Session Chairs
Mitchell Anstey
Susan Odom
Tuesday PM, November 29, 2016
Hynes, Level 1, Hall B

8:00 PM - EC1.6.01
Redox Flow Battery Involving Graphene Quantum Dot and Fe2+/Fe3+

Kalathur Santhanam 1 , M. Hernandez-Rivera 1 , Zachary Protich 1

1 Rochester Institute of Technology Rochester United States

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8:00 PM - EC1.6.02
Supported Platinum Nanoparticles—Mechanistic Details on the Flattening Mechanism under Potentiostatic Control

Sarah Wieghold 1 , Lea Nienhaus 2 , Armin Siebel 1 , Maximilian Krause 1 , Patricia Wand 1 , Martin Gruebele 3 , Ueli Heiz 1 , Friedrich Esch 1

1 Technische Universität München Garching Germany, 2 Massachusetts Institute of Technology Cambridge United States, 3 University of Illinois Urbana United States

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8:00 PM - EC1.6.03
Electrochemical Activation of SF6 and Subsequent Reactivity to Solid Phases in Nonaqueous Li Cells

Yuanda Li 1 , Aliza Khurram 1 , Betar Gallant 1

1 Massachusetts Institute of Technology Cambridge United States

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8:00 PM - EC1.6.04
Redox-Medated Coordination Behavior of Gallium Complexes

Ryan Zarkesh 1 , Mitchell Anstey 2

1 Sandia National Laboratories Livermore United States, 2 Davidson College Davidson United States

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8:00 PM - EC1.6.05
Overcharge Self-Regulated Li-Ion Battery Based on LiFePO4 via a Solid State Combined Cathode

Fei Gu 1 2 3 , Kichang Jung 4 , Alfredo Martinez-Morales 1 2 3

1 Materials Science and Engineering Program University of California, Riverside Riverside United States, 2 Winston Chung Global Energy Center, University of California, Riverside Riverside United States, 3 College of Engineering Center for Environmental Research and Technology, University of California, Riverside Riverside United States, 4 Department of Chemical and Environmental Engineering University of California, Riverside Riverside United States

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8:00 PM - EC1.6.06
Synthesis and Characterization of an Iron/Reduced Graphene Oxide Catalyst for Polymer Electrolyte Membrane Fuel Cells

Rebecca Isseroff 1 2 , Allen Green 1 , Likun Wang 2 , Simon Lin 2 , Tatiana Zaliznyak 3 , Sunil Dehipawala 4 , Yash Samantary 5 , Tzvi Heimowitz 6 , Aviva Landau 7 , Hongfei Li 2 , Miriam Rafailovich 2

1 Lawrence High School Cedarhurst United States, 2 Materials Science and Engineering Stony Brook University Stony Brook United States, 3 Marine Sciences Stony Brook University Stony Brook United States, 4 Queens College Flushing United States, 5 Syosset High School Syosset United States, 6 DRS Yeshiva High School for Boys Woodmere United States, 7 Yeshiva High School for Girls Queens United States

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2016-11-30   Show All Abstracts

Symposium Organizers

Susan Odom, University of Kentucky
Mitchell Anstey, Davidson College
Luis Campos, Columbia University
Neil Tomson, University of Pennsylvania
EC1.7: Organic Electronics
Session Chairs
Stephen Barlow
Andrew Boydston
Luis Campos
Thomas Hamann
Wednesday AM, November 30, 2016
Sheraton, 3rd Floor, Berkeley AB

8:00 AM - *EC1.7.01
Coupling Electron Transfer and Bond Cleavage to Moderate the Reactivity of Strong Reductants

Stephen Barlow 1 , Zhenan Bao 2 , Lawrence Bottomley 1 , Alexandr Fonari 3 , Song Guo 1 , Evgheni Jucov 3 , Antoine Kahn 4 , Norbert Koch 5 , Xin Lin 4 , Megan Mann 1 , Seth Marder 1 , Swagat Mohapatra 1 , Karttikay Moudgil 1 , Benjamin Naab 2 , Chad Risko 6 , Tatiana Timofeeva 3 , Berthold Wegner 5 , Siyuan Zhang 1

1 Georgia Institute of Technology Atlanta United States, 2 Stanford University Stanford United States, 3 New Mexico Highlands University Las Vegas United States, 4 Princeton University Princeton United States, 5 Humboldt University of Berlin Berlin Germany, 6 University of Kentucky Lexington United States

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8:30 AM - EC1.7.02
Beating the Thermodynamic Limit—n-Doping of a Low Electron Affinity Organic Semiconductor via UV Irradiation

Xin Lin 1 , Berthold Wegner 2 , Kyung Min Lee 1 , Karttikay Moudgil 3 , Barry Rand 1 4 , Stephen Barlow 3 , Seth Marder 3 , Norbert Koch 2 , Antoine Kahn 1

1 Princeton University Princeton United States, 2 Humboldt-Universität zu Berlin Berlin Germany, 3 Georgia Institute of Technology Atlanta United States, 4 Andlinger Ctr for Energy amp; Enviro Princeton United States

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8:45 AM - EC1.7.03
Electrochemical Insights in Doping Behavior and Charge Transport of the Electron Conducting Polymer P(NDI2OD-T2)

Daniel Trefz 1 , Adrian Ruff 1 2 , Roman Tkachov 1 3 , Anton Kiriy 3 , Sabine Ludwigs 1

1 University of Stuttgart Stuttgart Germany, 2 Analytical Chemistry - Center for Electrochemical Sciences (CES) Ruhr-Universität-Bochum Bochum Germany, 3 Leibniz Institute of Polymer Research Dresden e.V. Dresden Germany

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9:00 AM - *EC1.7.04
Fluxional Pi-Electronics—Attenuated Aromaticities and Spins in Organic Electronic Materials

John Tovar 1

1 Johns Hopkins University Baltimore United States

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9:30 AM - *
BREAK

10:00 AM - *EC1.7.05
Establishing Fundamental Connections between Molecular Redox Events and the Performance of Organic-Based Electronic and Energy Storage Devices

Chad Risko 1

1 University of Kentucky Lexington United States

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10:30 AM - EC1.7.06
A Computational Investigation into Steric Manipulation of Small-Molecule Oxidation Potentials for Energy-Storage Applications

Corrine Elliott 1 , Matthew Casselman 1 , Subrahmanyam Modekrutti 1 , Chad Risko 1 2 , Susan Odom 1

1 University of Kentucky Lexington United States, 2 Center for Applied Energy Research Lexington United States

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10:45 AM - EC1.7.07
Potential Tuning in Redox Active Organic Materials— Toward an all Organic Li-Ion Battery with Higher Output Voltage

Alae Eddine Lakraychi 1 2 4 , Jean-Pierre Bonnet 2 4 , Philippe Poizot 3 , Matthieu Becuwe 2 4 , Franck Dolhem 1 4

1 Laboratoire de Glycochimie, des Antimicrobiens et des Agroressources Amiens France, 2 Laboratoire de Réactivité et Chimie des Solides Amiens France, 4 Réseau sur le stockage électrochimique de l'énergie Amiens France, 3 Institut des Matériaux Jean Rouxel Amiens France

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11:00 AM - EC1.7.08
Triptycene-Based Quinone Molecules Showing Multi-Electron Redox Behaviors for High Capacity and High Energy Organic Cathode Materials

Ji Eon Kwon 1 , Chang Seok Hyun 2 , Young Jun Ryu 2 , Byeong-Kwan An 2 , Soo Young Park 1

1 Depmartment of Materials Science and Engineering Seoul National University Seoul Korea (the Republic of), 2 Department of Chemistry The Catholic University of Korea Bucheon Korea (the Republic of)

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11:15 AM - EC1.7.09
Polyviologen-Based Composite Materials for Redox Application

Nianxing Wang 1 , Pia Damlin 1 , Carita Kvarnstroem 1

1 University of Turku Turku Finland

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11:15 AM - EC1.7.10
Highly Fluorescent Thiazolothiazole Viologens with Active Electrochromism

Alexis Woodward 1 , Justin Kolesar 1 , Sara Hall 1 , Michael Walter 1

1 University of North Carolina, Charlotte Charlotte United States

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EC1.8: Interfacial Redox Reactions
Session Chairs
Mitchell Anstey
Susan Odom
Wednesday PM, November 30, 2016
Sheraton, 3rd Floor, Berkeley AB

1:30 PM - *EC1.8.01
Organic Electrochemistry and Addressable Libraries—Developing Site-Selective Synthetic Methods for the Construction of Complex Molecular Surfaces

Kevin Moeller 1

1 Washington University in St. Louis St. Louis United States

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2:00 PM - *EC1.8.02
Manipulation of Electron-Transfer Dynamics in Dye-Sensitized Solar Cells Employing Cobalt-Based Redox Shuttles

Thomas Hamann 1

1 Michigan State University East Lansing United States

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2:30 PM - EC1.8.03
Measurement of Potential-Dependent Electron Transfer Coefficients for Sub-Populations of Tethered Redox Active Molecules

Hsiao-Chu Lin 1 , Yilong Zheng 1 , Nathan Polaske 1 , Dominic McGrath 1 , S. Scott Saavedra 1 , Erin Ratcliff 1

1 University of Arizona Tucson United States

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2:45 PM - *EC1.8.04
Single-Molecule Diodes with High Rectification Ratios through Environmental Control

Latha Venkataraman 1 2

1 Applied Physics Columbia University New York United States, 2 Chemistry Columbia University New York United States

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