Program - Symposium GG: Membranes

1999 MRS Spring Meeting & Exhibit
April 5-9, 1999
San Francisco, CA
Meeting Chairs: Katayun Barmak, James S. Speck, Raymond T. Tung, Paul D. Calvert

SESSION GG1: INORGANIC MEMBRANES

Chair: C. Jeffrey Brinker
Tuesday Morning, April 6, 1999
Salon 14 (M) 8:30 AM GG1.1
TEMPERATURE AND PRESSURE DEPENDENCE OF LIGHT GAS MIXTURE PERMEATION THROUGH SAPO-34 MEMBRANES. Joseph C. Poshusta, Eric A. Pape, Vu A. Tuan, John L. Falconer, Richard D. Noble , Univ of Colorado, Dept of Chemical Engineering, Boulder, CO.

8:45 AM GG1.2
MICROPOROUS SILICA MEMBRANE FOR CO₂ REMOVAL FROM NATURAL GAS. Chung-Yi Tsai ¹, Siu-Yue Tam¹, C. Jeffrey Brinker², The University of New Mexico, NSF Center for Micro-Engineered Materials^1,2, Sandia National Laboratories², The Advanced Materials Laboratory, Albuquerque, NM.

9:00 AM *GG1.3
SYNTHESIS AND PERMEATION PROPERTIES OF CERAMIC-SUPPORTED ORIENTED MFI-TYPE MEMBRANES. Michael Tsapatsis , George Xomeritakis Department of Chemical Engineering, University of Massachusetts, Amherst, MA.

9:30 AM GG1.4
DEFECT FREE MOLECULAR SIEVE COMPOSITE MEMBRANES. Tina M. Nenoff , Steven G. Thoma, Daniel Trudell, Alejandra V. Chavez, Phillip Pohl, Sandia National Labs, Albuquerque, NM.

9:45 AM GG1.5
"ZEOLITE-LIKE" SOL-GEL SILICA MEMBRANE. Sujit Naik ¹, Chung-Yi Tsai¹, C. Jeffrey Brinker^1,2, Roger Assink²; ¹The University of New Mexico, NSF Center for Micro-Engineered Materials and ²Sandia National Laboratories, Advanced Materials Laboratory, Albuquerque, NM.

10:00 AM BREAK

10:30 AM GG1.6
IN-SITU COUNTER DIFFUSION CVD FOR PORE SIZE CONTROL OF INORGANIC POROUS MEMBRANE. Yasuyuki Egashira , Nobuhiko Mori, Yasushi Funakoshi and Korekazu Ueyama, Osaka Univ., Graduate School of Engineering Science, Division of Chemical Engineering, Osaka, JAPAN.

10:45 AM GG1.7
MOLECULAR SIEVE MEMBRANES VIA LASER ABLATION. Kenneth J. Balkus, Jr. , Ashley Scott, Trindad Munoz, University of Texas at Dallas, Department of Chemistry, Richardson, TX.

11:00 AM GG1.8
MICROFABRICATED INORGANIC MEMBRANES FOR PROTEIN SEPARATION AND IMMUNOISOLATION. Tejal A. Desai , Dept. of Bioengineering, University of Illinois at Chicago, IL; Derek Hansford and Mauro Ferrari, University of California, Berkeley, CA.

11:15 AM GG1.9
STEAM-RESISTANT $\gamma$ -ALUMINA MEMBRANES. Arian Nijmeijer, Henk Kruidhof, Henk Verweij and Manon Timmerman-Oude Wolbers , Inorganic Materials Science, University of Twente, Enschede, NETHERLANDS.

11:30 AM GG1.10
FABRICATION OF UF MEMBRANES BY LAMINATION TECHNIQUE USING NANOPARTICLE DERIVED CERAMIC FOILS. R. Nonninger , B. Walter, O. Binkle, H. Schmidt, Institut fuer Neue Materialien gem. GmbH, Saarbruecken, GERMANY.

11:45 AM GG1.11
A CO₂ GAS SENSOR OF La₂O₃ - LOADED SiO₂-SnO₂ MEMBRANE BY SOL-GEL TECHNIQUE. Nishengliang , Chen Yuquan, Luo Wei, Pan Min, Dept. of BME, Zhejiang University, Hangzhou, P.R.CHINA.

SESSION GG2: POLYMER MEMBRANES

Chair: Dibakar Bhattacharyya
Tuesday Afternoon, April 6, 1999
Salon 14 (M) 1:30 PM *GG2.1
GAS SEPARATION MEMBRANE MATERIALS: NEW DEVELOPMENTS AND FUTURE NEEDS. W.J. Koros , Chemical Engineering Department, The University of Texas at Austin, TX.

2:00 PM GG2.2
NANOPOROUS GAS TRANSPORT IN SEMICRYSTALLINE BLOCK COPOLYMERS. Peter Kofinas , Peter L. Drzal, Sufi R. Ahmed, University of Maryland, Dept of Materials and Nuclear Engineering, College Park, MD.

2:15 PM GG2.3
PERMEATION OF NOBLE GASES THROUGH POLYMER MEMBRANES STUDIED WITH A MASS SPECTROMETER. Holger Norenberg , G.D.W. Smith, G.A.D. Briggs, University of Oxford, Department of Materials, Oxford, UNITED KINGDOM; T. Miyamoto, Y. Tsukahara, Technical Research Institute, Toppan Printing Company, Sugito Takanodai, JAPAN.

2:30 PM *GG2.4
BASIS OF PERMEABILITY/SELECTIVITY TRADEOFF RELATIONS IN POLYMERIC GAS SEPARATION MEMBRANES. Benny D. Freeman , NC State Univ, Dept of Chemical Engineering, Raleigh, NC.

3:00 PM BREAK

3:30 PM GG2.5
STRUCTURE-PROPERTY RELATIONSHIPS IN PROTON-CONDUCTING MEMBRANES: QUANTIFICATION OF CROSSLINKING AND CORRELATION WITH SWELLING AND OTHER PROPERTIES. Hans-Peter Brack , Guenther G. Scherer, Paul Scherrer Institute, Electrochemistry, Villigen PSI, SWITZERLAND; Daniel Fischer, Gustav Peter, Zuercher Hochschule Winterthur, Chemistry Department, Winterthur, SWITZERLAND.

3:45 PM GG2.6
THERMAL DEGRADATION OF RADIATION-GRAFTED FILMS AND MEMBRANES. Hans-Peter Brack , Gunther G. Scherer, Paul Scherrer Institute, Electrochemistry Dept, Villigen PSI, SWITZERLAND; Denise Ruegg, Heiner G. Bohrer, Zurcher Hochschule Winterthur, Chemistry Dept, Winterthur, SWITZERLAND.

4:00 PM GG2.7
PSEUDOCROWN ETHERS AS FIXED SITE CARRIERS IN FACILITATED TRANSPORT MEMBRANES. Brian J. Elliott , W. Brinson Willis and Christopher N. Bowman, University of Colorado, Dept. of Chemical Engineering, Boulder, CO.

4:15 PM GG2.8
PRELIMINARY RESULTS ON IN VITRO AND IN VIVO BIOCOMPATIBILITY OF CHITOSAN-XANTHAN POLYIONIC COMPLEX. Fatiha Chellat, Maryam Tabrizian , Ecole Polytechnique, Biomedical Engineering Inst, Montreal, Qc, CANADA; Severian Dumitriu, Estaban Chornet, Sherbrooke Univ, Dept of Chemical Engineering, Sherbrooke, Qc, CANADA; Charles Hilaire Rivard, Ste Justine Hospital, Montreal, Qc, CANADA; L'hocine Yahia, Ecole Polytechnique, Biomedical Engineering Inst, Montreal, Qc, CANADA.

4:30 PM GG2.9
ELECTROCHEMICALLY PRODUCED MEMBRANES FOR ULTRAFILTRATION AND REVERSE-OSMOSIS. Lidia Kolzunova , Inst of Chemistry, Far East Dept, Russian Academy of Sciences, Vladivostok, RUSSIA.

4:45 PM GG2.10
POLYMER MEMBRANES AS SENSITIVE ELEMENTS OF IMMUNOSENSORS. Tetyana Panasyuk, Sergiy Piletísky, Ganna Elíska, Inst of Molecular Biology and Genetics, Dept of Translational Mechanisms of Genetic Information, Kyiv, UKRAINE; Rinat Nigmatullin, Inst of Colloid and Water Chemistry, Dept of Physical Chem of Membranes, Kyiv, UKRAINE; Mikhaylo Bryk , National Univ ´ Kyiv-Mohyla Academiaª, Dept of Chemistry, Kyiv, UKRAINE.

SESSION GG3: BIOMEMBRANES

Chair: David Needham
Wednesday Morning, April 7, 1999
Salon 14 (M) 8:30 AM GG3.1
THE MECHANOCHEMISTRY OF LIPID VESICLES EXAMINED BY MICROPIPET MANIPULATION TECHNIQUES. David Needham , Department of Mechanical Engineering and Materials Science, Duke University, Durham, NC.

8:45 AM GG3.2
FOLDING AND RESPREADING IN LUNG SURFACTANT - INFLUENCE OF CHAIN LENGTH OF LIPIDS AND PRESENCE OF PROTEINS. Karlheinz Graf , Anja von Nahmen, Joseph A. Zasadzinski, Dept of Chemical Engineering, University of California, Santa Barbara, CA; Gerhard Schwarz, Dept of Biophysical Chemistry, Biocenter of the University, Basel, SWITZERLAND; Alan J. Waring, Dept of Pediatrics, Drew University-King Medical Center and University of California, Los Angeles, CA.

9:00 AM GG3.3
VESOSOMES - A NEW DRUG DELIVERY SYSTEM. Edward Kisak , Bret Coldren, Michael Kennedy, Dirk Trommeshauser, Joseph A. Zasadzinski, Univeristy of California at Santa Barbara, Dept of Chemical Engineering, Santa Barbara, CA.

9:15 AM GG3.4
THE PRODUCTION OF LIPID VESICLES BY EXTRUSION THROUGH POLYCARBONATE MEMBRANES. P. Patty, C. Asman, D.G. Hunter and B.J. Frisken , Burnaby, CANADA.

9:30 AM GG3.5
ELASTIC PROPERTIES AND MICROSTRUCTURES OF CATANIONIC SURFACTANTS. Hee-Tae Jung , J.A. Zasadzinski, Department of Chemical Engineering and Materials, University of California, Santa Barbara, CA; Dan Iampietro, E.W. Kaler, Department of Chemical Engineering, University of Delaware, Newark, DE.

9:45 AM GG3.6
REVERSIBLE COLLAPSE PROCESSES IN MIXED LIPID-PROTEIN-FILMS. Anja von Nahmen , Dawn Takamoto, Karlheinz Graf, Junqi Ding, Joseph Zasadzinski, University of California at Santa Barbara, Dept. of Chemical Engineering, Santa Barbara, CA; Ka Yee C. Lee, University of Chicago, Dept. of Chemistry, Chicago, IL; Alan Waring, University of California at Los Angeles, CA; MLK, Drew University Medical Center and Perinatal Labs, Los Angeles, CA.

10:00 AM BREAK

10:30 AM *GG3.7
MICROMECHANICS OF A RELATIVELY SIMPLE AND NATURAL BIOMEMBRANE COMPOSITE. D. Discher , J. Lee, D. Wong, C. Picart, University of Pennsylvania, Philadelphia, PA.

11:00 AM GG3.8
POLYMOSOMES: NOVEL CAPSULAR STATES OF DI-BLOCK COPOLYMERS. D. Discher , B. Discher, J. Lee, Y. Won^*, D. Ege, F. Bates^*, D. Hammer, University of Pennsylvania, Philadelphia, PA; ^*University of Minnesota, MN.

11:15 AM GG3.9
MASS-ELECTRO ANALYSIS OF LIPID MEMBRANES FOR CHINESE WINE TASTING SENSING MODEL. Chen Yuquan, Pan Min , Dept of BME, Zhejiang Univ, Hangzhou, P.R.CHINA.

11:30 AM GG3.10
VARIABLE TEMPERATURE FLUID STAGE FOR AFM. Srinivas Manne, Richard K. Workman , University of Arizona, Dept of Physics, Tucson, AZ.

11:45 AM GG3.11
INTERACTIONS BETWEEN POLY(2-ETHYLACRYLIC ACID) AND LIPID BILAYER MEMBRANES: EFFECTS OF CHOLESTEROL AND GRAFTED POLY(ETHYLENE GLYCOL). David Needham, Jeff Mills and Gary Eichenbaum, Department of Mechanical Engineering and Materials Science, Duke University, Durham, NC.

SESSION GG4: HYBRID MEMBRANES

Chair: Benny D. Freeman
Wednesday Afternoon, April 7, 1999
Salon 14 (M) 1:30 PM GG4.1
CHALLENGING PERVAPORATION SEPARATIONS USING POLYMERIC AND ZEOLITE MEMBRANES. Dhaval S. Shah , Dibakar Bhattacharyya, University of Kentucky, Dept. of Chemical and Materials Engineering, Lexington, KY; Ajit Ghorpade, SmithKline Beecham Corporation, King of Prussia, PA.

1:45 PM GG4.2
HYBRID POLYIMIDE-SILICA MEMBRANES FOR GAS SEPARATION. Eva Marand , Chris J. Cornelius, Nicolas G. Vidonic, Virginia Polytechnic Institute and State University, Department of Chemical Engineering, Blacksburg, VA.

2:00 PM GG4.3
MONOLAYERS OF AMPHIPHILIC FULLERENE DERIVATIVES CONTAINING AN AZOBENZENE CHROMOPHORE. Kei Oishi , Masahito Sano, Seiji Shinkai, Chemotransfiguration Project, JST, Fukuoka, JAPAN.

2:15 PM GG4.4
PROPERTIES OF COMPOSITE MEMBRANES PREPARED FROM PVDF AND INORGANIC PARTICLES. Aldo Bottino, Gustavo Capannelli, Valentina D'Asti, Paolo Piaggio , Genova Univ, Genova, ITALY.

2:30 PM GG4.5
ORGANIC-INORGANIC MEMBRANES PREPARED FROM POLYETHERDIAMINE AND EPOXY-CONTAINING INORGANIC PRECURSORS. S.P. Nunes , K.V. Peinemann, E. Rikowski, GKSS-Research Center, Geesthacht, GERMANY; M.L. Sforca, I.V.P. Yoshida, University of Campinas, BRAZIL.

2:45 PM GG4.6
FABRICATION, CHARACTERIZATION AND UTILIZATION OF NEW TYPES OF MEMBRANES. Younan Xia , Byron Gates, Univ of Washington, Seattle, WA.

3:00 PM BREAK

SESSION GG5: BILAYER/MULTILAYER MEMBRANES AND SENSORS

Chair: Dennis E. Discher
Wednesday Afternoon, April 7, 1999
Salon 14 (M) 3:30 PM GG5.1
OIL-SWOLLEN BILAYERS BY A MYELIN TRANSMEMBRANE PROTEIN AND BY SYNTHETIC PEPTIDES. N. Taulier, C. Nicot, M. Waks, LIP, CNRS 7623, Universitè Paris VI, Paris, FRANCE; R. Ober, LPMC, CNRS 792, Collège de France, Gif-sur-Yvette, FRANCE; T. Gulik-Krzywicki, CGM, CNRS 2420, Gif-sur-Yvette, FRANCE; R.S. Hodges, P. Semchuk, PENCE Medical Center, University of Alberta, CANADA; and W. Urbach , ENS, LPS, CNRS, Paris, FRANCE.

3:45 PM GG5.2
PYROLYZED RESISTS FOR BIO-MEMS APPLICATIONS. Marc Madou , Ohio State University, Department of Materials Science and Engineering and Department of Chemistry, Columbus, OH.

4:00 PM GG5.3
ORDERED ASSEMBLY OF PROTEINS ON SURFACES. Leonidas G. Bachas , J. Wang, W. Huang, Department of Chemistry, University of Kentucky, Lexington, KY; S. Viswanath, J. Liu, D. Bhattacharyya, Department of Chemical & Materials Engineering, University of Kentucky, Lexington, KY.

4:15 PM GG5.4
CALMODULIN-MEDIATED REVERSIBLE IMMOBILIZATION OF ENZYMES. Vesna Schauer-Vukasinovic, Greta Schrift, Sylvia Daunert , University of Kentucky, Department of Chemistry, Lexington, KY.

4:30 PM GG5.5
COEXISTENCE OF BUCKLED AND FLAT MONOLAYERS: MORE EVIDENCES FOR SURFACTANT PROTEINS TO KEEP MONOLAYERS STABLE. Junqi Ding ¹, Anja von Nahmen¹, Alan Waring², Joseph Zasadzinski^1*, Robert Notter³, ¹Department of Chemical Engineering, University of California, Santa Barbara, CA; ²MLK, Drew University Medical Center and Perinatal Labs, Harbor, UCLA, CA; ³Department of Pediatrics and Environmental Medicine, University of Rochester, Rochester, NY.

4:45 PM GG5.6
EFFECT OF MONOVALENT IONS ON THE SWELLING OF MULTILAMELLAR PHOSPHOLIPID VESICLES. Stine S. Korreman , Niels Boye Olsen and Dorthe Posselt, Roskilde University, Dept. of Math. and Physics, Roskilde, DENMARK.

SESSION GG6: POSTER SESSION: MEMBRANES

Chair: C. Jeffrey Brinker
Wednesday Evening, April 7, 1999
8:00 P.M.
Salon 7 (M) GG6.1
NON-NEWTONIAN RHEOLOGY OF FATTY ACID LANGMUIR MONOLAYERS. Daniel K. Schwartz , Ani Ivanova, Tulane Univ, Dept of Chemistry, New Orleans, LA.

GG6.2
DEVELOPMENT OF "NEW LIPID" BY THE AGGREGATION OF SYNTHETIC 10-ALKYL ISOALLOXAZINES IN AQUEOUS MEDIA. Shveta Chaudhary , Abha Awasthi, S.M.S. Chauhan, Department of Chemistry, University of Delhi, Delhi, INDIA.