MRS Meetings and Events

 

EN02.08.14 2022 MRS Fall Meeting

Improved Charge Balance in Green Perovskite Light-Emitting Diodes with Atomic-Layer-Deposited Al2O3

When and Where

Nov 30, 2022
8:00pm - 10:00pm

Hynes, Level 1, Hall A

Presenter

Co-Author(s)

William Gunnarsson1,Zhaojian Xu1,Nakita Noel1,Barry Rand1

Princeton University1

Abstract

William Gunnarsson1,Zhaojian Xu1,Nakita Noel1,Barry Rand1

Princeton University1
Perovskite light-emitting diodes (LEDs) have experienced a rapid increase in efficiency over the last several years and are now regarded as promising low-cost devices for displays and communication systems. However, it is often challenging to employ ZnO, a well-studied electron transport material, in perovskite LEDs due to chemical instability at the ZnO/perovskite interface and charge injection imbalance caused by the relatively high conductivity of ZnO. In this work, we address these problems by depositing an ultrathin Al<sub>2</sub>O<sub>3</sub> interlayer at the ZnO/perovskite interface, allowing the fabrication of green-emitting perovskite LEDs with a maximum luminance of 21,815 cd/m<sup>2</sup>. Using atomic layer deposition, we can precisely control the Al<sub>2</sub>O<sub>3</sub> thickness and thus fine-tune the electron injection from ZnO, allowing us to enhance the efficiency and operational stability of our LEDs.

Keywords

perovskites

Symposium Organizers

Jin-Wook Lee, Sungkyunkwan University
Carolin Sutter-Fella, Lawrence Berkeley National Laboratory
Wolfgang Tress, Zurich University of Applied Sciences
Kai Zhu, National Renewable Energy Laboratory

Symposium Support

Bronze
ACS Energy Letters
ChemComm
MilliporeSigma
SKKU Insitute of Energy Science & Technology

Session Chairs

Jin-Wook Lee
Carolin Sutter-Fella
Wolfgang Tress

In this Session

EN02.08.01
Utilisation of PEDOT as a Hole Selective Layer for Reproducible Efficient Tin-Based Perovskite Solar Cells with the DMSO-Free Solvent System

EN02.08.02
Tuning the Surface Potential of Hybrid Perovskite Active Layers Through Interfacial Engineering Using Fluorinated Compounds

EN02.08.03
Hole-Transporting Self-Assembled Monolayer Enables 23.1%-Efficient Single-Crystal Perovskite Solar Cells with Enhanced Stability

EN02.08.04
Solvent Engineering of NiOx Solutions for Rapid Depositions as Hole Transporting Layers for Flexible Perovskite Solar Cells

EN02.08.05
Potentiometry of Operating Perovskite-Based Devices with Kelvin Probe Force Microscopy

EN02.08.06
Low Temperature Synthesized Y:SnO2 as an Effective Electron Transport Layer for Inverted Perovskite Solar Cells on Flexible ITO-PET Substrate

EN02.08.08
Enabling Perovskite/Perovskite/Silicon Triple Tandem Based on Transparent Conductive Adhesive Lamination Process

EN02.08.09
Defect-Stabilized Tin-Based Perovskite Solar Cells Enabled by Multi-Functional Molecular Additives

EN02.08.10
Perovskite-Based Multijunction Solar Cells for Efficient Continuous Solar-Assisted Water Splitting

EN02.08.11
In Situ Metrology of Hybrid Halide Perovskite Single Crystals—Investigating Growth Dynamics of Inverse Temperature Crystallisation

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