2021 MRS Spring Meeting

Meeting content will be available through May 31
at https://mrs2021.cd.pathable.com/.


All times listed are Eastern Daylight Time.

Symposium EN08 : Progress in Understanding Charge Transfer at Electrochemical Interfaces in Batteries

2021-04-22   Show All Abstracts

Symposium Organizers

Vijayakumar Murugesan, Pacific Northwest National Laboratory
Nav Nidhi Rajput, Tufts University
Rajeev Surendran Assary, Argonne National Laboratory
Kevin Zavadil, Sandia National Laboratories
EN08.01: NMR Analysis of Heterogeneous Interfaces
Session Chairs
Karl Mueller
Vijayakumar Murugesan
Thursday PM, April 22, 2021
EN08

10:30 AM - *EN08.01.01
Unraveling the Chemistry and Transport of Multi-Valent Cations in the Bulk and at Interfaces

Karl Mueller1,Venkateshkumar Prabhakaran1,Grant Johnson1,Linda Wangoh1,Yingge Du1,Kee Sung Han1,Jian Zhi Hu1,Ying Chen1,Rajeev Surendran Assary2,Vijayakumar Murugesan1

Pacific Northwest National Laboratory1,Argonne National Laboratory2

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10:55 AM - *EN08.01.02
Exploring Transition Metal-Complexes as Redox Mediators in Li-O2 Battery

Aninda Bhattacharyya1,Subhankar Mandal1

Indian Institute of Science1

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11:20 AM - EN08.01.03
Insights into the Functionality of an Alkylated LixSiyOz Interphase for High Energy Cathodes from High Sensitivity NMR Spectroscopy

Shira Haber1,Rosy Sharma2,3,Arka Saha2,3,Arava Zohar1,Malachi Noked2,3,Michal Leskes1

Weizmann Institute of Science1,Bar-Ilan University2,Bar-Ilan Institute of Nanotechnology and Advanced Materials3

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11:35 AM - EN08.01.05
Solvation Structures, Molecular-Level Dynamics and Evolution of Electrolytes in Solution and at Interfaces Using Advanced NMR Techniques

Jian Zhi Hu1,Ying Chen1,Kee Sung Han1,Nathan Hahn2,Kevin Zavadil2,Kristin Persson3,Vijayakumar Murugesan1,Karl Mueller1

The Joint Center for Energy Storage Research (JCESR), Pacific Northwest National Laboratory1,Sandia National Laboratories2,Lawrence Berkeley National Laboratory3

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11:50 AM - EN08.01.06
Multivalent Electrolytes: Controlling Interfacial Resiliency Through Selective Cation Coordination

Nathan Hahn1,2,Kevin Zavadil1,2

Sandia National Laboratories1,Joint Center for Energy Storage Research2

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12:05 PM - EN08.01
Discussion Time


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EN08.02: Ion Transport Across Interfaces
Session Chairs
Nav Nidhi Rajput
Kevin Zavadil
Thursday PM, April 22, 2021
EN08

1:00 PM - *EN08.02.01
Ion Clustering in Electrolytes—Implications on Electrochemical Stability and Transport Properties

Boris Kozinsky1,2

Harvard University1,Bosch Research2

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1:25 PM - EN08.02.02
ALD Niobium Oxide for Improved Rate Capability and Cycle Life of Cathode Films for Li-Ion Batteries

Abdessalem Aribia1,Jordi Sastre-Pellicer1,Xubin Chen1,Gilshtein Evgeniia1,Ayodhya Tiwari1,Yaroslav Romanyuk1

Empa–Swiss Federal Laboratories for Materials Science and Technology1

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1:40 PM - *EN08.02.03
Mechanisms of Diffusive Charge Transport and Surface Adsorption in Redox-Active Polymer Solutions

Charles Sing1,Liliana Bello1

University of Illinois at Urbana-Champaign1

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2:05 PM - EN08.02.04
Cooperative Anion Effects for Reversible Plating/Stripping of Divalent Metals

Justin Connell1,Milena Zorko1,Garvit Agarwal1,Mengxi Yang1,Chen Liao1,Rajeev Surendran Assary1,Dusan Strmcnik1,Nenad Markovic1

Argonne National Laboratory1

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2:20 PM - EN08.02.05
Realizing Reversible Magnesium Plating/Stripping by Interface Controls

Jaegeon Ryu1,2,Hui Wang1,2,Yuyan Shao1,2

Pacific Northwest National Laboratory1,Joint Center for Energy Storage Research2

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2:35 PM - EN08.02
Discussion Time


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EN08.03: Interphases for Ion Intercalation
Session Chairs
Rajeev Surendran Assary
Kevin Zavadil
Thursday PM, April 22, 2021
EN08

4:00 PM - *EN08.03.01
Optimizing Bulk and Interfacial Kinetic Limitations in Nanostructured Battery Materials

Sarah Tolbert1

University of California, Los Angeles1

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4:25 PM - *EN08.03.02
Probing Local Ion Intercalation Processes Through Electro-Chemo-Mechanical Coupling Behaviors

Nina Balke1,Wan-Yu Tsai1

Oak Ridge National Laboratory1

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4:50 PM - EN08.03.03
Advanced Electrode/Electrolyte Interphases for High Voltage Lithium Metal Batteries

Wu Xu1,Xiaodi Ren1,Xianhui Zhang1,Ji-Guang Zhang1

Pacific Northwest National Laboratory1

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5:05 PM - EN08.03.04
Designing Stable Electrode/Electrolyte Interphases for Lithium-Ion Batteries with Low-Flammability Electrolytes

Hao Jia1,Yaobin Xu1,Xianhui Zhang1,Sarah Burton1,Mark Engelhard1,Peiyuan Gao1,Chongmin Wang1,Wu Xu1

Pacific Northwest National Laboratory1

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5:20 PM - EN08.03.05
Ion Clustering and Transport in MgCl2-Based Electrolytes for Rechargeable Magnesium Batteries

Vallabh Vasudevan1,Mingchao Wang1,Nick Birbilis2,Nikhil Medhekar1

Monash University1,The Australian National University2

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5:35 PM - EN08.03
Discussion Time


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EN08.04: Computation and Modelling of Electrochemical Interfaces
Session Chairs
Nav Nidhi Rajput
Rajeev Surendran Assary
Friday AM, April 23, 2021
EN08

8:15 PM - *EN08.04.01
Single Molecule Charge Transport at Electrode Interfaces

Charles Schroeder1,Jialing Li1

University of Illinois at Urbana-Champaign1

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8:40 PM - EN08.04.02
Interfacial Solvation Dynamics of Multivalent Cations—Peculiarities and General Principles of Ion Solvation Engineering

Artem Baskin1,2,David Prendergast2,John Lawson1

NASA Ames Research Center1,Lawrence Berkeley National Laboratory2

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8:55 PM - *EN08.04.03
Atomic-Scale Insight into Charge Transfer Processes at Electrochemical Interfaces

Donald Siegel1

University of Michigan–Ann Arbor1

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9:20 PM - EN08.04.04
Interfacial Reactivity of Electrolytes in Multivalent Batteries—Insights from Density Functional Theory Calculations and XPS Experiments

Garvit Agarwal1,Swadipta Roy2,Venkateshkumar Prabhakaran2,Grant Johnson2,Vijayakumar Murugesan2,Rajeev Surendran Assary1

Argonne National Laboratory1,Pacific Northwest National Laboratory2

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9:35 PM - EN08.04
Discussion Time


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2021-04-23   Show All Abstracts

Symposium Organizers

Vijayakumar Murugesan, Pacific Northwest National Laboratory
Nav Nidhi Rajput, Tufts University
Rajeev Surendran Assary, Argonne National Laboratory
Kevin Zavadil, Sandia National Laboratories
EN08.05: Theoretical Analysis of Interfacial Reactivity
Session Chairs
Nav Nidhi Rajput
Rajeev Surendran Assary
Friday AM, April 23, 2021
EN08

8:00 AM - *EN08.05.01
Elucidating Cation Electrodeposition—The Roles of Electrolyte Composition and Surface Structure

Perla Balbuena1,Stefany Angarita-Gomez1,Fernando Soto1

Texas A&M University1

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8:25 AM - EN08.05.02
Effects of Functionalized Cathode and Electrolyte Composition on Structure and Dissolution of Polysulfide Species in Li-S Batteries

Rasha Atwi1,Nav Nidhi Rajput1

Stony Brook University, The State University of New York1

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8:40 AM - EN08.05.03
WITHDRAWN EN08.05.03 4/22/2021 Modeling First Stages of Solid-Electrolyte Interphase (SEI) in LiPF6/EC Electrolytes Using Molecular Dynamics Simulations

Lorena Alzate-Vargas1,Jean-Luc Fattebert1,Srikanth Allu1

Oak Ridge National Laboratory1

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8:55 AM - EN08.05.04
Understanding Ion Transport and Interfacial Stability in Fluorine Containing Lithium Argyrodite Electrolytes for Solid-State Lithium-Sulfur Batteries

Badri Narayanan1,Varun Shreyas1,William Arnold1,Saransh Gupta1,Jacek Jasinski1,Gamini Sumanasekera1,Hui Wang1

University of Louisville1

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9:10 AM - EN08.05.05
Late News: DFT Sampling Study on Ion Transfer at Heterogeneous Solid-Solid Interfaces in Batteries

Yoshitaka Tateyama1,2,Keitaro Sodeyama1,2,Bo Gao1

National Institute for Materials Science1,Kyoto University2

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9:25 AM - EN08.05
Discussion Time


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EN08.06: Metal Anode Interfacial Design
Session Chairs
Vijayakumar Murugesan
Kevin Zavadil
Friday PM, April 23, 2021
EN08

11:45 AM - *EN08.06.01
Controlling Interphase Generation and Interfacial Charge Transfer at Magnesium Anode–Electrolyte Interfaces

Brett Helms1,Sung-Ju Cho1,Benjamin Cousineau2,Jingbo Zhao1,Emily Carino3,Julian Self1,Kristin Persson1,2,Rajeev Surendran Assary3,Garvit Agarwal3,Kevin Zavadil4

Lawrence Berkeley National Laboratory1,University of California, Berkeley2,Argonne National Laboratory3,Sandia National Laboratories4

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12:10 PM - EN08.06.02
Sodium Stripping and Plating from Na-β"-Alumina Ceramics beyond 1000 mA/cm2

Daniel Landmann1,Gustav Graeber1,Meike Heinz1,Corsin Battaglia1

Empa–Swiss Federal Laboratories for Materials Science and Technology1

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12:25 PM - EN08.06.03
Kinetic- vs Diffusion-Driven Three–Dimensional Growth in Magnesium Metal Battery Anodes

Janna Eaves-Rathert1,Kathleen Moyer1,Murtaza Zohair1,Cary Pint1,2

Vanderbilt University1,Iowa State University of Science and Technology2

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12:40 PM - EN08.06.04
Dendrite Formation during Charging of Li-Metal Batteries: Transport Limitations within the SEI Control Dendrite Initiation

Adam Maraschky1,Rohan Akolkar1

Case Western Reserve University1

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12:55 PM - EN08.06.05
Superior Lithium Metal Anode Composed of Porous Carbon Electrodes Layered with Metal-Organic Framework

Juran Noh1,Wenmiao Chen1,Yutao Huang1,Peng Wu1,Jian Tan1,Hong-cai Zhou1,Choongho Yu1

Texas A&M University1

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1:10 PM - EN08.06.06
Late News: High-Performance Low-Temperature Molten Sodium Batteries Enabled by Improved Charge Transfer Across Interfaces

Martha Gross1,Stephen Percival1,Rose Lee1,Amanda Peretti1,Mark Rodriguez1,Erik Spoerke1,Leo Small1

Sandia National Laboratories1

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1:15 PM - EN08.06.07
Late News: Electrochemistry of the NaI-AlBr3 Low Temperature Molten Salt System—Implications for Applied Battery Performance

Stephen Percival1,Rose Lee1,Martha Gross1,Amanda Peretti1,Leo Small1,Erik Spoerke1

Sandia National Laboratories1

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1:20 PM - EN08.06
Discussion Time


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EN08.07: X-Ray Spectroscopy of Interfacial Process
Session Chairs
Vijayakumar Murugesan
Kevin Zavadil
Friday PM, April 23, 2021
EN08

2:15 PM - EN08.07.01
Lithium Interface Dynamics in Coated LiFePO4 Nanoparticles

Peter Benedek1,Xueyan Zhao1,Emanuel Billeter2,Elisabetta Nocerino3,Ola Forslund3,Nami Matsubara3,Andreas Borgschulte2,Fanni Juranyi4,Martin Månsson3,Vanessa Wood1

ETH Zürich1,Empa–Swiss Federal Laboratories for Materials Science and Technology2,KTH Royal Institute of Technology3,Paul Scherrer Institute4

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2:30 PM - EN08.07.02
Using Operando SQUID Magnetometry to Monitor Charge Transfer Processes in Li- and Na-Ion Battery Cathodes

Stefan Topolovec1,Gregor Klinser1,Heinz Krenn2,Roland Würschum1

Graz University of Technology1,University of Graz2

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2:45 PM - EN08.07.03
Atomic-scale Computational Study of the Solid Electrolyte Interphase in Na-Ion Batteries with a Nanoporous Hard Carbon Anode

Emilia Olsson1,Qiong Cai1

University of Surrey1

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3:00 PM - *EN08.07.04
Synchrotron Characterization of Chemo-Mechanical Transformations in All-Solid-State Batteries

Kelsey Hatzell1,Marm Dixit1

Vanderbilt University1

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3:25 PM - EN08.07.05
Phase Controlled Synthesis and Properties of Mn3O4 Spinel Oxides Electrodes for Multivalent Batteries Using Molecular Beam Epitaxy

Linda Wangoh1,ZhenZhong Yang1,Le Wang1,Mark Bowden1,Karl Mueller1,Vijayakumar Murugesan1,Yingge Du1

Pacific Northwest National Laboratory1

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3:40 PM - EN08.07
Discussion Time


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EN08.08: Chemical Imaging of Interfaces
Session Chairs
Nav Nidhi Rajput
Kevin Zavadil
Friday PM, April 23, 2021
EN08

5:15 PM - *EN08.08.01
Identifying Intact Electrode Interfaces with Cryogenic Electron Microscopy

Katherine Jungjohann1,Daniel Long1,Steven Randolph2,Renae Gannon3,Luara Merrill4,Subrahmanyam Goriparti4,Katharine Harrison4

Center for Integrated Nanotechnologies1,Thermo Fisher Scientific2,University of Oregon3,Sandia National Laboratories4

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5:40 PM - EN08.08.02
The Effect of Anions in the Calcium Solvation Under Operando Conditions Probed by In Situ Soft X-Ray absorption spectroscopy

Feipeng Yang1,Xuefei Feng1,Jinghua Guo1,2

Lawrence Berkeley National Laboratory1,University of California, Santa Cruz2

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5:55 PM - *EN08.08.03
Unveiling a New Facet in Magnesium Battery Electrochemistry

Rana Mohtadi1,Oscar Tutusaus1

Toyota Research Institute of North America1

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6:20 PM - EN08.08.04
Multimodal Characterization of Electrodeposited Calcium Metal and Its Native Interphases for Next-Generation Battery Applications

Scott McClary1,Daniel Long1,Paul Kotula1,Mark Rodriguez1,Timothy Ruggles1,Katherine Jungjohann1,Kevin Zavadil1

Sandia National Laboratories1

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6:35 PM - EN08.08.05
Late News: Scanning Electrochemical Cell Microscopy Based Nanoscale Electrochemistry Study

Jiali Zhang1,Byong Kim1

Park Systems, Inc.1

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6:50 PM - EN08.08
Discussion Time


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EN08.09: Interfaces for Redox Flow Battery
Session Chairs
Rajeev Surendran Assary
Kevin Zavadil
Saturday AM, April 24, 2021
EN08

8:15 PM - *EN08.09.01
Accessible Electrode Surface Area and Its Impact on Redox Flow Battery Performance

Fikile Brushett1,2

Massachusetts Institute of Technology1,Joint Center for Energy Storage Research2

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8:40 PM - EN08.09.02
Mechanisms Underlying the Electrochemical Oxidation of Nitroxide Radicals in Ethaline Deep Eutectic Solvent

Nora Shaheen1,Mahesh Ijjada1,Miomir Vukmirovic2,Rohan Akolkar1

Case Western Reserve University1,Brookhaven National Laboratory2

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8:55 PM - *EN08.09.03
Reaction Rate Mapping at Electrodes for Redox Flow Batteries—Impacts of Adsorption and Electrode Structure

Joaquin Rodriguez-Lopez1,Dipobrato Sarbapalli1,Michael Counihan1,Tylan Watkins2,Kevin Zavadil2

University of Illinois at Urbana-Champaign1,Sandia National Laboratories2

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9:20 PM - EN08.09.04
WITHDRAWN 4/19/21 en08.09.04 Modulation of the Electrochemical Rate Constants and Electrical Currents, in Nanoscale Battery Electrodes

Prab Bandaru1,Hidenori Yamada1

University of California, San Diego1

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9:35 PM - EN08.09.05
Binding Energies and Electronic Coupling Calculations of Redox Flow Molecules at the Carbon Surface

Jason Howard1,Larry Curtiss1

Argonne National Laboratory1

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9:50 PM - EN08.09
Discussion Time


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