Symposium Organizers
Jianguo Mei, Purdue University
Hanying Li, Zhejiang University
Joon Hak Oh, Pohang University of Science and Technolog (POSTECH)
Tse Nga Ng, University of California, San Diego
Symposium Support
MilliporeSigma (Sigma-Aldrich Materials Science)
MA02.03: Processing and Microstructure III
Session Chairs
Alexander Ayzner
Tse Nga Ng
Wednesday AM, April 04, 2018
PCC West, 100 Level, Room 102 BC
8:00 AM - MA02.03.01
Materials Structure Measurements for Flexible Electronics Manufacturing
Dean DeLongchamp1
National Institute of Standards and Technology1
Show AbstractThere remain significant challenges in achieving stable, high performance organic semiconductor devices from scalable manufacturing methods. We address this using synchrotron-based X-ray scattering and a variety of optical methods to observe the structure of films in-situ as they dry. I will review our studies of systems including organic photovoltaics (OPVs) which can achieve nearly 10 % power conversion efficiency (PCE), and organic thin film transistors (OTFTs) that can achieve high (>1 cm2/Vs) hole or electron mobility. I will emphasize commonalities and differences among systems, and attempt to classify the processing behavior of systems based on traits such as diffraction strength (~crystallinity). There is a surprising diversity of solidification mechanisms among organic semiconductor systems. Some are dominated by the nanoscale crystallization of the components, whereas others appear to be dominated by liquid-liquid phase separation. I will also touch on the role of additive ink formulations. Examples of good performance can be found for systems that have many different types of final morphologies that are produced by different solidification mechanisms.
The diversity of morphologies that can produce high performance in organic semiconductors suggests that there is no single morphological trait that can be depended on to predict performance. New measurements may be needed that can probe the nanoscale distribution of molecular orientation. I will describe our further development of resonant soft X-ray scattering, which combines principles of spectroscopy, small-angle scattering, real-space imaging, and molecular simulation to produce a molecular scale structure measurement that probes these previously inaccessible aspects of organic semiconductor morphology.
8:30 AM - MA02.03.02
Morphology of Conjugated Polymer Films from Controlled Polymer Solution Conformation
Yanchun Han1
Changchun Institute of Applied Chemistry1
Show AbstractOrganic semiconducting polymers have garnered interest for their numerous applications in lightweight, flexible and solution-processable devices including organic field effect transistors (OFETs), organic light-emitting diodes, organic photovoltaics, biomedical devices and sensors. In addition to tuning the chemical structure of the materials, the role of morphology has been identified as a key parameter in determining device performance. Use of conjugated polymers in optoelectronic devices requires thin films to be cast from appropriate solutions. The solubility of the polymer is, however, restricted by the strong π-π interaction and the large chain rigidity that greatly lowers the entropy of mixing. Conjugated polymers are seldom molecularly dispersed in solution even through attaching flexible short side chains to the conjugated backbone. Abundant evidence have demonstrated that the conjugated segments tend to form submicrometer aggregate domains in the solutions. The internal structure of these aggregates and the nature of the interaction leading to the aggregation has however not been addressed unequivocally. Furthermore, detailed correlations between molecular properties, solution aggregation structures, and the ultimate film performances of organic semiconductors are still largely unknown. Our study indicated that polymer chain conformation (in solution, during film formation and post treatment by solvent annealing) is important in determining the final film morphology. First, the photophysics and solution aggregation behavior of different conjugated polymers, which strongly depends on polymer molecular weight, conjugated length, solvent quality and temperature for a specific polymer system are investigated. Moreover, their determinant effects for the final morphology in the cast films will be discussed in detail.
9:00 AM - MA02.03.03
Carrier Transport and Trapping Phenomena in Pentacene Thin Films
Masakazu Nakamura1,Min-Cherl Jung1,Ryosuke Matsubara2
Nara Institute of Science and Technology1,Shizuoka University2
Show AbstractPentacene is one of the most extensively studied semiconducting materials for organic thin-film transistors (OTFTs) and has been still a benchmark material in this research field. Understanding the bottlenecks of carrier transport in pentacene OTFT is therefore important to maximize the performance of OTFTs using not only this benchmark material but also any semiconducting small molecules. In this presentation, the reality of the carrier transport band and traps in practical polycrystalline organic thin films is explained by making pentacene into a representative case [1]. The major topics included are as follows: grain morphology and crystal structure of pentacene thin films, energy barriers at grain boundaries, potential fluctuation in a grain, equations to express the overall carrier mobility in polycrystalline films, carrier traps at organic/insulator interface, and influence of surface chemical modification on the electronic structures.
[1] R. Matsubara et al.: Chapter 10, Mobility limiting factors in practical polycrystalline organic thin films in Electronic Processes in Organic Electronics: Bridging Nanostructure, Electronic States and Device Properties, ed. H. Ishii et al., pp. 185–225, Springer, 2014.
9:30 AM - MA02.03.04
Vapour-Induced Demixing in Solution-Processed Ferroelectric Films for Organic Memory Applications
Jasper Michels1,Hamed Sharifi1,Kamal Asadi1
Max Planck Institute for Polymer Research1
Show AbstractCost-effective production of flexible organic memory devices requires ambient solution casting of ferroelectric polymers, such as poly(vinylidene fluoride) (PVDF) and poly(vinylidene fluoride-co-trifluoroethylene) (P(VDF-TrFE)). However, condensation of water vapor from the environment into the drying fluid film causes phase separation, which yields a fluid state morphology comprising polymer-rich micro-droplets in a solvent–rich medium. As a consequence, the dry polymer films are rough, which leads to a low production yield of working devices. Whereas this process of vapor-induced phase separation (VIPS) is used advantageously in the production of microporous polymer membranes, it is hence to be avoided in the manufacture of thin-film organic memory devices. Through microscopic analysis, device characterization and numerical calculations we identify a processing window for smooth films, determined by the solvent’s evaporation rate and hygroscopicity, as well as the ambient humidity. Modeling of the multi-component out-of-equilibrium phase dynamics demonstrates how microstructure and feature sizes emerge during simultaneous solvent evaporation and water condensation. The numerical simulations yield morphologies consistent with experimentally observed structures and demonstrate how domain size and phase composition depend on the relative humidity of the environment. Interestingly, calculations and experiments seem to support a scenario wherein the dominant feature size in the dry polymer film is to a large extent already determined in the early stages of demixing.
9:45 AM - MA02.03.05
Understanding the Influence of Process Parameters on the Meniscus Guided Coating of Highly Crystalline Organic Thin Films
Robby Janneck1,2,Paul Heremans1,2,Jan Genoe1,2,Cedric Rolin1
IMEC1,KU Leuven2
Show AbstractHighly crystalline thin films of organic semiconductors offer great potential for the realization of high-performance, low-cost flexible electronics. These films are commonly fabricated using meniscus guided coating techniques such as solution shearing, dip coating or zone casting. In order to increase the film crystallinity, and thereby its carrier mobility, process optimization is usually carried through trial-and-error approaches to determine the right combination of semiconductor, solvent, temperature, surface treatment, coating speed and annealing treatment. Only few reports present systematic parameter studies that convey clear understanding and provide guidelines for future experiments.
Here, we present a systematic study over the impact of three important process parameters on the zone-casting of highly crystalline thin films. First, we explore the influence of ten different substrate surface treatments on thin film morphology and electrical characteristics. These surface treatments result in largely different surface energies and therefore largely different wetting envelopes. Nevertheless, we see that, as long as the solvent is fully wetting the substrate, the surface treatment only has a negligible influence on the morphology of the coated layers, but can still have a huge impact on the electrical characteristics. From this study, guidelines for choosing the right substrate-solvent combination can be extracted. Furthermore, we show how choosing the right solute concentration can result in larger processing windows and therefore higher coating speeds. Optimized coating speeds show similar electrical performances, while the drop in performance at higher speeds is less pronounced for solutions with higher solute concentrations. Finally, we also show the impact low temperature annealing has on the OTFT performance, resulting in a significant reduction of the threshold voltage. We attribute this to a beneficial reorganization of the organic semiconductor underneath the source and drain contact.
Combining these studies with our recently developed lateral homo-epitaxial fabrication technique, we demonstrate bottom-gate top contact thin film transistors based on highly crystalline C8-BTBT films with mobilities above 10 cm2/Vs and parameter spreads below 10% over 400 devices. These films behave almost twice as good as regularly evaporated poly-crystalline thin films, showing the potential of highly crystalline thin film transistors for large area electronics.
10:30 AM - MA02.03.06
Large-Area Plastic Nano-Electronics
Thomas Anthopoulos1
King Abdullah University of Science and Technology1
Show AbstractRecent advances in the field of organic optoelectronics have been driven primarily by the development of advanced semiconductors and an improved understanding of the structure-processing-property relationships. In this talk, I will present an alternative approach for the manufacturing of a plethora of organic optoelectronic devices using a simple and highly scalable manufacturing technique namely adhesion-lithography (a-Lith) – an innovative method that can be used to pattern symmetric or asymmetric coplanar nanogap electrodes with arbitrarily large aspect ratio. I will show how a-Lith can be combined with organic functional materials to produce a plethora of functional devices including; self-aligned gate transistors, radio frequency diodes and energy harvesting circuits, multi-colour organic light-emitting nanodiodes, photodetectors and multilevel non-volatile memory devices, to name but a few. Despite the early stage of development a-Lith can already be viewed as promising alternative to conventional nano-patterning techniques for application in large-volume nanoscale optoelectronics.
11:00 AM - MA02.03.07
Bioinspired Assembly of Organic Semiconductors
Ying Diao1,Erfan Mohammadi1,Hyunjoong Chung1,Ge Qu1,Fengjiao Zhang1
University of Illinois at Urbana-Champaign1
Show AbstractMolecular assembly, crystallization and controlled phase transition have played a central role in the development of modern electronics and energy materials. Recent years, printed electronics based on semiconducting molecular systems have emerged as a new technology platform that promise to revolutionize the electronics and clean energy industry. In contrast to traditional electronic manufacturing that requires high temperature and high vacuum, these new electronic materials can be solution printed at near ambient conditions to produce flexible, light-weight, biointegrated forms at low-cost and high-throughput. However, it remains a central challenge to control the morphology of semiconducting molecular systems across length scales. The significance of this challenge lies in the order of magnitude modulations in device performance by morphology parameters across all length scales.
This challenge arises from the fact that directed assembly approaches designed for conventional hard materials are far less effective for soft matters that exhibit high conformational complexity and weak, non-specific intermolecular interactions. On the other hand, biological systems have evolved to assemble complex molecular structures highly efficiently. We are eager to transfer the wisdom of living systems to developing printed electronics technologies as to enable next generation electronics for clean energy and healthcare. In this talk, we present new insights and strategies we recently developed for controlling multi-scale assembly and transformation of semiconducting molecules. We learned from living systems and designed bioinspired assembly processes, allowing molecules to put themselves together cooperatively into highly ordered structures otherwise not possible with significantly improved electronic properties. We discovered molecular design rules that impart dynamic and switchable electronic properties through the mechanism of molecular cooperativity – a mechanism ubiquitous in nature. These new solid-state properties could potentially enable new sensing and actuation mechanisms not possible before.
11:30 AM - MA02.03.08
Crystal Engineering of Organic Semiconductors Toward Outstanding Optoelectronic Properties
Yonggang Zhen1,Ping He1,Zongpeng Zhang1,Deyang Ji1,Eiichi Nakamura2,Wenping Hu1,3
Institute of Chemistry, CAS1,The University of Tokyo2,Tianjin University3
Show AbstractTailoring crystal polymorph and co-assembly into bicomponent or multicomponent solids are two important strategies of crystal engineering to improve the optoelectronic properties of organic semiconductors, which is highly challenging due to the weak nondirectional intermolecular interactions in organic solids.
Herein, we report the controllable growth of different crystal phases of organic semiconductors, i.e. pentacene1, thienoacene (BDTDT)2 and phthalocyanine derivatives (TiOPc)3 through polymorph induction of surface nanogrooves, solution supersaturation or vapor transport temperature gradient. The surface nanogrooves is highly important to induce the growth of orthorhombic phase pentacene films with extremely high mobility up to 30.6 cm2 V-1 s-1. The big discrepancies of charge transport in two different crystal polymorphs for BDTDT (8.5 vs. 18.9 cm2 V-1 s-1) and TiOPc (0.1 vs. 26.8 cm2 V-1 s-1) were observed clearly. In the case of BDTDT, we recognized the importance of electronic couplings of (HOMO-1) to charge transport behaviour, which is generally ignored to account for the carrier mobility. In the case of TiOPc, we demonstrated experimentally that inter-layer electronic couplings may result in a drastic decrease of charge mobilities utilizing field-effect transistors if the coupling direction perpendicular to the current direction.
Furthermore, a solid solution of two porphyrin derivatives was achieved by in-situ heating their soluble precusors mixture.4 Organic solar cells based on the solid solution was demonstrated for the first time, resulting in a power conversion efficiency value much higher than the devices using the single component. Last but not the least, we demonstrate the photocurrent generation of molecular heterojunction co-crystals. Theoretical calculations reveals the different charge recombination degree of these two co-crystals, indicating that molecualr stacking plays an important role in the photovoltaic effects. This work opens an avenue to develop molecular scale p-n junction cocrystals as a promising donor-acceptor contacting mode for application in organic solar cells.5
1. Ji, D.; Xu, X.; Jiang, L.; Amirjalayer, S.; Jiang, L.; Zhen, Y.*; Zou, Y.; Yao, Y.; Dong, H.; Yu, J.; Fuchs, H.; Hu, W., J. Am. Chem. Soc. 2017, 139, 2734.
2. He, P.; Tu, Z.; Zhao, G.; Zhen, Y.*; Geng, H.; Yi, Y.*; Wang, Z.; Zhang, H.; Xu, C.; Liu, J.; Lu, X.; Fu, X.; Zhao, Q.; Zhang, X.; Ji, D.; Jiang, L.; Dong, H.; Hu, W.*, Adv. Mater. 2015, 27, 825.
3. Zhang, Z.; Jiang, L.; Cheng, C.; Zhen, Y.*; Zhao, G.; Geng, H.; Yi, Y.*; Li, L.; Dong, H.; Shuai, Z.; Hu, W.*, Angew. Chem. Int. Ed. 2016, 55, 5206.
4. Zhen, Y.; Tanaka, H.*; Harano, K.; Okada, S.; Matsuo, Y.*; Nakamura, E.*, J. Am. Chem. Soc. 2015, 137, 2247.
5. Zhang, H.; Jiang, L.; Zhen, Y.*; Zhang, J.; Han, G.; Zhang, X.; Fu, X.; Yi, Y.*; Xu, W.*; Dong, H.; Chen, W.; Hu, W.*; Zhu, D., Adv. Electron. Mater. 2016, 2, 1500423.
11:45 AM - MA02.03.09
Atomic Groove Epitaxy of Linear Molecules on Aligned Poly(tetrafluoroethylene)
Toshihiko Tanaka1,2,Masamitsu Ishitobi3,Tetsuya Aoyama2,Hirohito Umezawa1
National Institute of Technology, Fukushima College1, RIKEN2,Sumitomo Chemical Co. Ltd.3
Show AbstractMolecular orientation of organic semiconductors is crucial for its performance of their device applications such as OFET. Many orientation processes including wet ones have been investigated and the oriented growth on an alignment layer is one of the most convenient method as it has been utilized in manufacturing liquid crystal displays for a long time. The first author has been fascinated by an poly(tetrafluoroethylene)(PTFE)alignment layer since he saw a letter by Wittmann and Smith in 1991.1 Although the unique non-sticking and poor wetting properties of PTFE is rather undesirable for applications, its two remarkable features are quite important: one is a wide variety of the materials oriented on it and the other is some cases (linear conjugated molecules such as bisazo dyes2,3, a bisethyne3, or a bisazomethine4) where an extremely high degree of orientation (exceeding 0.9 of an uniaxial order) can be achieved. Hence, the purpose of this presentation is to show its unique orientation mechanism we found, thus being a theoretical model for designing a novel alignment layer for organic electronics.
We have been investigating the mechanism by a molecular dynamics (MD) simulation and have just concluded that a negatively charged shallow “atomic groove” between two adjacent PTFE chains orients linear molecules by trapping them along the the groove.3 It is formed by the weak helix of the chain and its charge is due to fluorine atoms, thus the mechanism being quite unique as the other properties of PTFE. The dynamics simulates adsorption of each single molecule on a surface consisting of eight C32F66 chains uniaxially aligned in a plane. The orientational order was estimated from the dichroism in their polarized absorption spectra and correlate well with those estimated from the calculations. This atomic groove effect was first discovered in 20025 and furthermore some modification of the F charge recently demonstrated the significant contribution of its negative charge. Recent progress in computing ability enabled us to simulate the difference in the orientation by tiny changes in a molecule end. Such accuracy ensures the validation of the conclusion. If you can design an alignment layer showing such negatively charged atomic grooves on its surface, it will have the two features of aligned PTFE.
This work is supported by JSPS-KAKENHI(JP17K4996).
[1] J. C. Wittmann, P.Smith., Nature, 352, 414 (1991); [2] T. Tanaka, et al., Langmuir, 17, 2197 (2001); [3] T. Tanaka, M. Ishitobi, Chem. Lett., accepted (2017); [4] T. Tanaka, et al., Chem. Lett., 40, 1170(2011); [5] T. Tanaka, M. Ishitobi, J. Phys. Chem. B, 106, 564 (2002).
MA02.04: Processing and Microstructure IV
Session Chairs
Wednesday PM, April 04, 2018
PCC West, 100 Level, Room 102 BC
1:30 PM - MA02.04.01
What Governs Polymorphic Stability?
Yueh-Lin (Lynn) Loo1
Princeton University1
Show AbstractThe weak intermolecular forces inherent to molecular crystals give rise to polymorphism, or the ability for these materials to adopt multiple solid-state packing arrangements. Differences in molecular packing can result in distinct materials properties of the same compound (e.g., diamond vs. graphite), making polymorphism of general interest to the materials community. Yet, our collective understanding of this phenomenon remains inadequate. Calculations can shed light on the energetic landscape across different polymorphs but predictions for which phases are preferentially accessed remain challenging because accessibility is often dictated by kinetics (i.e., processing), as opposed to thermodynamics (i.e., energetics). In this talk, I will highlight a framework we have developed that directly correlates the presence of short intermolecular contacts with polymorphic accessibility. Subtle changes in the molecular chemistry do not significantly affect the possible solid-state packing arrangements, but do result in differences in the non-covalent intermolecular interactions that ultimately lead to preferential access to specific polymorphs. Starting with a series of core-chlorinated naphthalene diimide derivatives, we show this framework to be widely applicable to compounds ranging from molecular semiconductors to pharmaceutics, such as rotinavir, and biological building blocks, such as guanine. In this era of machine learning and materials by design, this framework can identify which polymorphs, among those available, are practically accessible and stable, thereby extending the predictive power of the solid-state properties of molecular materials prior to synthesis.
2:00 PM - MA02.04.02
Solvent-Vapor Annealing of Single Conjugated-Polymer Nanoparticles
John Lupton1
University of Regensburg1
Show AbstractSingle-molecule spectroscopy has provided unprecedented access to underlying structure-function relations of highly disordered conjugated polymers such as P3HT [1], but is often considered of only limited utility in illuminating molecular characteristics in the solid state. This perception has changed with the introduction of single-molecule solvent-vapor annealing techniques, which allow the deterministic growth of multichain aggregates – mesoscopic nanoparticles – to mimic bulk material characteristics while retaining the low degree of heterogeneity characteristic of a sub-ensemble experiment. Such single aggregates reveal that exciton generation in bulk films is an inherently intermolecular process, involving scores of polymer chains because of the prevalent process of singlet-singlet annihilation. As a consequence, even large aggregates containing many polymer chains exhibit deterministic single-photon emission in the form of photon antibunching [2]. A corollary of this effect is strong triplet-polaron quenching in large multichain aggregates, which leads to the disappearance of triplet-exciton photon correlation signatures in particles grown by controlled solvent-vapor annealing [3].
Most recently, it has become possible to directly image the growth and arrangement of multichain aggregates during annealing. Annealing promotes chain ordering, which strengthens the intrinsic J-aggregate character of polymer chains. Once the solvent molecules are removed by drying, cofacial stacking of these carefully ordered chains is encouraged, which gives rise to pronounced H-aggregate spectral characteristics. This drying process, on the level of single nanoparticles, is highly reversible and can be repeated many times to show a controlled switching between J- and H-type characteristics. Single-particle annealing therefore offers a unique window to monitoring the dynamics of solvent removal from polymer films, in real time, during processing [4].
[1] Thiessen, Vogelsang, Lupton et al., PNAS 110, 3550 (2013)
[2] Stangl, Vogelsang, Lupton et al., PNAS 112, 5560 (2015)
[3] Steiner, Lupton, Vogelsang, JACS 139, 9787 (2017)
[4] Eder, Vogelsang, Lupton et al., Nature Comm. 10.1038/s41467-017-01773-0 (2017)
2:15 PM - MA02.04.03
Studying Lamellar-Like Morphologies of Conjugated Polymers Through a New Symmetry-Inspired Model
Cristina Greco1,Kurt Kremer1,Kostas Daoulas1
Max Planck Institute for Polymer Research1
Show AbstractDue to their ease of processability and mechanical flexibility, conjugated polymers are attractive materials for organic electronics. Though substantial progress has been made in enhancing their charge transport properties, clear design guidelines are still difficult to establish. A fundamental reason resides in the intimate connection between charge transport and morphology [1]. Morphologies of conjugated polymers are complex and diverse, and thus hard to predict and characterize. In addition, identifying the structural features that are most crucial for charge transport is not trivial. One interesting recent observation is that, to achieve high mobilities, perfect lamellar order is not necessary [2]. Morphologies with only partial lamellar order (“lamellar-like”) can either originate from the intrinsic properties of the polymer, as exemplified by the microstructures of some aggregating materials [2] and by the smectic mesophases of liquid-crystalline polymers [3], or can be induced by processing, e.g. with chain aligning techniques [4].
Here we present a simple model that enables the study of morphologies with lamellar-like order, at device-relevant length scales. Nonbonded interactions responsible for biaxiality of chain orientation and for stacking are described by anisotropic soft potentials, constructed in a top-down manner on the basis of symmetry considerations. Bonded interactions are introduced bottom-up, to capture the conformational characteristics of the polymer under study. Considering polyalkylthiophenes as a test system, we perform Monte Carlo simulations of chains of various lengths, starting from different initial configurations. Lamellar-like morphologies are obtained, either as mono- or polydomains. The type of lamellar-like order realized is characterized by computing 2D scattering patterns, which can be easily compared with experimental GIWAXS data. We conclude that the obtained morphologies correspond to a lamellar-like smectic mesophase, an organization that was also reported in experiments [3]. We analyze conformational properties, quantifying in a simple way the length of conjugated segments and identifying connectivity pathways between the lamellae. In perspective, atomistic detail can be reintroduced via backmapping, allowing for prediction of charge transport [5].
[1] S. Himmelberger, A. Salleo, MRS Commun. 2015, 5, 383.
[2] R. Noriega, J. Rivnay, K. Vandewal, F. P. V. Koch, N. Stingelin, P. Smith, M. F. Toney, A. Salleo, Nat. Mater. 2013, 12, 1038.
[3] Z. Wu, A. Petzold, T. Henze, T. Thurn-Albrecht, R. H. Lohwasser, M. Sommer, M. Thelakkat, Macromolecules 2010, 43, 4646.
[4] L. Hartmann, K. Tremel, S. Uttiya, E. Crossland, S. Ludwigs, N. Kayunkid, C. Vergnat, M. Brinkmann, Adv. Funct. Mater. 2011, 21, 4047.
[5] P. Gemünden, C. Poelking, K. Kremer, K. Daoulas, D. Andrienko, Macromol. Rapid Commun. 2015, 36, 1047.
3:30 PM - MA02.04.04
Chemical and Morphological Control of Interfacial Self-Doping for Efficient Organic Solar Cells
Thomas Russell1,2,Yao Liu1,Marcus Cole1,Yufeng Jiang2,Paul Kim1,Dennis Nordlund3,Todd Emrick1
University of Massachusetts Amherst1,Lawrence Berkeley National Laboratory2,Stanford Synchrotron Radiation Laboratory3
Show AbstractSolution-based processing of materials for electrical doping of organic semiconductor interfaces is attractive for boosting the efficiency of organic electronic devices with multilayer structures. To simplify this process, self-doping perylene diimide (PDI)-based ionene polymers were synthesized, combining semiconductor PDI components with electrolyte dopants embedded within the polymer backbone. Functionality contained within the PDI monomers suppressed their aggregation, affording self-doping interlayers with controllable thickness when processed from solution into organic photovoltaic devices (OPVs). Optimal results for interfacial self-doping led to increased power conversion efficiencies (PCEs) of the fullerene-based OPVs from 2.62% to 10.64%, and of the non-fullerene-based OPVs from 3.34% to 10.59%. These ionene interlayers enable chemical and morphological control of interfacial doping and charge transport, demonstrating that effective conductive channels are crucial for charge transport in doped organic semiconductor films. Using the interlayers with efficient doping and charge transport, both fullerene- and non-fullerene-based OPVs were achieved PCEs exceeding 9% over interlayer thicknesses ranging from ~3 to ~40 nm.
4:00 PM - MA02.04.05
Materials and Devices Towards High Performance Thick-Film Polymer Solar Cells
Fei Huang1
South China Univ of Technology1
Show AbstractHerein, we report our efforts on the development of new materials and devices for high performance thick film polymer solar cells (PSCs), which are more compatible for roll-to-roll printing process. A series of high mobility electron donor materials and cathode interfacial materials were designed and synthesized. The resulting PSCs based on these newly developed materials exhibited promising performance with a thick interlayer and light-harvesting layer [1-5]. It was also found that the introduction of highly crystalline small molecule donors into ternary PSCs is an effective way to enhance the charge transport and thus increase the active layer thickness of ternary PSCs that are more suitable for roll-to-roll production than previous thinner devices [6]. These works may provide new solutions for preparing both active layer and interlayer for PSCs and also make them potential candidates to be employed in high performance large area PSC module device in the future.
References
[1] Y. C. Jin, Z. M. Chen, S. Dong et al. Adv. Mater. 2016, 28, 9811.
[2] Y. Jin, L. Ying, F. Huang et al. Adv. Energy. Mater. 2017, 1700944.
[3] Z. Wu, C. Sun, S. Dong et al. J. Am. Chem. Soc. 2016, 138, 2004.
[4] C. Sun, Z. Wu, Z. Hu et al. Energy Environ Sci. 2017, 10, 1784.
[5] S. Dong, K. Zhang, Z. C, Hu et al. Adv. Mater. 2017, 29, 1701507.
[6] B. Fan, K. Zhang, X. F. Jiang et al. Adv. Mater. 2017, 10, 1606396.
[7] B. Fan, L. Ying, Z. Wang et al. Energy Environ. Sci. 2017, 10, 1243.
[8] G. C. Zhang, K. Zhang, Q. W. Yin et al. J. Am. Chem. Soc. 2017, 139, 2387.
4:30 PM - MA02.04.06
Shy Organic Photovoltaics—Visually Attractive Digitally Printed Solar Modules with Hidden Interconnects
Kai Cheong Tam1,Philipp Maisch1,Hans-Joachim Egelhaaf1,C. Brabec2,1
ZAE Bayern e.V.1,University of Erlangen-Nuremberg2
Show AbstractOne of the biggest attractions of the organic photovoltaics (OPV) technology is the easiness with which it can be integrated. However, despite its semitransparency and wide variety of colours, a major unresolved challenge is to fabricate optically inconspicuous organic photovoltaic modules (OPV-M) that can be integrated into visually demanding products. This is dominantly due to the visual obstruction from Z-interconnection lines inherent to module processing with classical patterning methods. We now present for the first time a solution to this problem, which utilizes a visually seamless interconnection method to elegantly minimize the conspicuity of the interconnection regime. We realize such invisible interconnects by inkjet printing highly conductive silver lines or dots, which penetrate the solar cell stack and form an electrical connection between adjacent cells. Topographical and cross-sectional images of the interconnection region are taken to illustrate how the connection is formed. Photos of the modules are also provided to showcase the stark visual difference between the classical and the new approach implemented in this work. Beside the minimal power conversion efficiencies (PCE) loss when transferred from small (0.1 cm2) single cells to 3-cell solar modules (3 cm2), we also demonstrate the effective connection between cells by special measurement structures that can precisely measure the specific interconnection resistance down to 1.5 mΩcm2. Finite element (FEM) simulation further rationalizes the excellent electrical cell-to-cell connection established with this interconnection technology. We combine this technology with a variable-geometry module design into an innovative digital inkjet printing platform for the production of state-of-the art but visually attractive solar modules. The full potential of this concept is demonstrated by various fully inkjet printed semitransparent OPV-M portraits and logos with area over 84cm2 and efficiencies over 3.5%.
4:45 PM - MA02.04.07
Organic Tandem Photovoltaics Combining Solution-Processed Non-Fullerene Acceptor and Vacuum-Deposited Subcells with 15% Efficiency
Xiaozhou Che1,Yongxi Li1,Yue Qu1,Stephen Forrest1
Univ of Michigan1
Show AbstractOrganic photovoltaic cells (OPVs) offer a light weight and potentially cost-effective approach for solar energy harvesting. Recent studies on solution processed, non-fullerene acceptors (NFAs) has led to single junction cell efficiencies > 13%. Here we report a tandem OPV structure with a NFA-based near infrared subcell spin-coated on a visible-absorbing subcell grown by vacuum thermal evaporation (VTE). A novel charge recombination zone completely protects the VTE layers from dissolution during deposition of the NFA-based active layer. The tandem cell achieves the power conversion efficiency of 15.0%. This work demonstrates the feasibility of combining subcells with different processing techniques for achieving efficient OPVs, providing flexibility over current multijunction designs.
MA02.05: Poster Session I: Organic Electronics—Processing, Microstructure and Multifunctioning I
Session Chairs
Wednesday PM, April 04, 2018
PCC North, 300 Level, Exhibit Hall C-E
5:00 PM - MA02.05.01
Solution-Processed Transparent Electrode for Organic Optoelectronics
Antonio Gaetano Ricciardulli1,Sheng Yang1,2,Gert-Jan Wetzelaer1,Xinliang Feng2,Paul Blom1
Max-Planck-Institut für Polymerforschung1,Center for Advancing Electronics Dresden (CFAED) and Department of Chemistry and Food Chemistry, Technische Universität Dresden2
Show AbstractIndium Tin Oxide (ITO) has been widely used as transparent conductive electrode (TCE) in optoelectronics. However, it suffers from high production costs, dwindling supplies, limited chemical and mechanical stability. Therefore, seeking for an efficient alternative to ITO as TCE is of great significance. As first step we have investigated solution-processed transparent electrodes based on electrochemical exfoliated graphene (EG)[1], characterized by remarkable properties (C/O ratio 17.9), high yield (78%) and low cost. Uniform and smooth electrodes have been obtained by spray-coating of a high-quality EG dispersion on both rigid and flexible substrates. Compared to previous reported solution processed graphene based TCEs, our EG electrodes show improved features (i.e. sheet resistance, Rs, as low as 0.18 kΩ sq–1).[2] However, the organic solar cells (OSCs) based on these pristine EG electrodes exhibit power conversion efficiency (PCE) typically 40% lower than their ITO analogues. Hence, in order to enhance performances of the devices, keeping a feasible approach, we have developed a mixed-dimensional structure (1D-2D) using AgNWs and EG.[3] Compared with pristine EG these hybrid TCEs exhibit a dramatic decrease of the sheet resistance Rs from 78 to 13.7 Ω sq-1 combined with an optical transparency of 89%. In addition the surface roughness (RMS) reduces from 16.4 to 4.6 nm and their mechanical and chemical stability is enhanced. The spray-coated hybrid AgNWs-EG TCEs have been successfully implemented in OSCs and polymer LEDs (PLEDs), which output remarkable efficiencies that are equivalent with their commercial ITO-based counterparts. To the best of our knowledge these are the first solution-processed transparent electrodes that match the performance of ITO based TCEs.[3]
[1] S. Yang, A. G. Ricciardulli, S. Liu, R. Dong, M. R. Lohe, A. Becker, M. A. Squillaci, P. Samori, K. Mullen, X. Feng, Angew. Chem. Int. Ed. 2017, 56, 6669.
[2] A. G. Ricciardulli, S. Yang, X. Feng, P. W. M. Blom, ACS Appl. Mater. Interfaces 2017, 9, 25412.
[3] A. G. Ricciardulli, S. Yang, G. A. H. Wetzelaer, X. Feng, P. W. M. Blom, Submitted.
5:00 PM - MA02.05.02
Polymer Fiber Electronics and Their Applications as Microfluidics Interconnections
Boxue Chen1
University of Texas at Austin1
Show AbstractThere has been a rising demand for more complex chips and multi-chips integration in microfluidics. However, chip-to-chip and chip-to-world interconnections remain simple, i.e. plastic tubing, due to its very different melting processing techniques, materials properties and insufficient knowledge of fiber electronics. These challenges can be addressed by applying new device structures and new sensing materials made available by multimaterial fiber processes, which have recently emerged as a material platform for a variety of sensing modalities. In this work, we present a new strategy that integrates different functional units, such as pumping or sensing units, into the multimaterial fibers as microfluidics interconnections.
Hundreds of meters of uniform fibers with cross-sections of 2x1 mm were produced through a thermal drawing processing. The basic structure of fiber consists a 1x0.5 mm hollow core as a fluid channel inside of polycarbonate (PC) cladding. Two conductive polymer films made of carbon black doped polyethylene (CPE, 25 um) are placed adjacent to the hollow core. CPE films are electrically insulated from the fluid channel by a thin dielectric film of polycarbonate (5 um), and can be electrically connected on the fiber surfaces with silver paint.
Multiple microfluidics-related functions, such as flowrate sensor and fluid pump, have been demonstrated with this specific fiber design. Here we specifically focus on demonstrating a hybrid in-fiber multi-segment thermal flow sensor design that enables extended measurement range at high flow-rate sensitivity and low flow resistance. We start with a first-order heat-transfer analysis to establish the analytical temperature response of a long hot film in a fiber microfluidic channel. This model predicts a limited range of linear flow-rate response for a single-segment sensor, which is confirmed by measurement. We then explore multi-segment structure sensors with a significantly extended operational range in both numerical simulations and experiments.
We report integrated multi-segment fiber flow rate sensors that combines high sensitivity (0.38 V/(uLmin-1)), large dynamic range (0-200 uL/min) and small pressure drop (8 Pa at 100 uL/min), in a 1mm x 0.5mm fluidic channel embedded in a multi-material fiber. Depends on the flow rate region of interest, one or multiple appreciate segments can be measured for the best performance, which enables us to extend measurement range within a single device. Comparing to widely used metal films, new sensing materials CPE provides 20 times higher TCR (0.09 K-1) and 107 times higher resistivity (0.2 Ωm), allowing us to obtain low pressure drop while maintaining high sensitivity. High sensitivity, low pressure drop and wide measurement range together qualify our fiber sensors as very promising functional microfluidics interconnections. Our work opens up many new opportunities for microfluidics research and is extremely suitable for biomedical applications.
5:00 PM - MA02.05.03
Near-Infrared, Flexible and Transparent Photodetector Based on Electrolyte-Gated Organic Transistor with Lonogel/Silver Nanowire Membranes
Haihua Xu1,Qingqing Zhu1
Shenzhen University1
Show AbstractWearable electronics are essential for continuous monitoring of physiological.However, commercial wearable devices such as smart watches, bracelets and glasses, are poorly skin-mountable and bulky since their sensors are fabricated by rigid inorganic semiconductor materials. Thus, there exist obvious motion-relative disturbances on sensing information obtained from these sensors. One practicable solution is to adopt flexible electronics especially epidermal electronics that can be ultrathin, lightweight and stretchable. Although great progress has been made on epidermal electronics, it is evident that these availble epidermal electronics still have drawbacks such as high power consumption, sophisticated process and high cost To address these issues, solution-processable electrolyte-gated organic transistors which have low-voltage, easy-process and high sensitivity, are developed as promising wearable electronics devices. Here, we develop flexible and highly photodetectors based on electrolyte-gated organic transistors with ionogel/silver nanowire membranes. Random network of silver nanowire (AgNW), which is used as a transparent and flexible electrode, exhibits high conductivityand excellent mechanical flexibility. The ionogel/AgNW nanocomposite membrane, in which AgNW was directly embedded into an ionogel-type gate dielectric layer, shows a large capacitance (~2µF/cm2),low sheet resistance and ultra-high optical transparency (T > 90%). In the electrolyte-gated organic transistor device, we chose a heterojunction active layer formed by blending a high hole mobility and narrow-bandgap polymer semiconductor (PSC) with an inorganic quantum dots (QDs) and silver nanoparticles(AgNPs) . Thanks to the large mobility difference between PSC and QDs as well as large carrier trapping effects of AgNPs, the device exhibits high responsivity of 7.5×105 AW-1 and ultrahigh sensitivity (~7.5×105). Transient photocurrent response at different light intensitiesreveals the device has shorter photoresponse time at lower light intensity, contrary to that of traditional phototransistors with oxide gate dielectrics. We suggest this difference is originated from the existing strong interactions between photogenerated hole carriers and anions that can induce extra long-lived trap states. It is noting that our device presents a large 3dB bandwidth of ~100 Hz. Therefore, our device is capable of detecting low-frequency pulse signals.To evaluate the utility for flexible electronic applications, we carried out bend-radius dependent measurements. It is noteworthy that the sensitivity remains in the level of 105 when bending device to a radius as small as 2 mm. Owing to fast and air-stable operations, we believe the device can be taken as a very promising photosensing module for constructing smart wearable devices in the future.
5:00 PM - MA02.05.04
The Key Role of In-Plane Transport Pathways for Out-of-Plane Charge Percolation in Bulk Heterojunctions
Jeremy Mehta1,Jeffrey Mativetsky1
Binghamton University Physics1
Show AbstractSolution processed organic bulk heterojunctions (BHJs) are promising for enabling low-cost, green, and flexible photovoltaics. The BHJ architecture, with its nanoscale interpenetrating donor-acceptor structure, allows for ample light absorption in a thin (hundreds of nanometer thick) active layer, while satisfying the need for a high density of donor-acceptor interfaces for exciton dissociation. Nevertheless, the highly heterogeneous nanostructured active layer, with its locally varying composition, crystallinity, and miscibility between components, leads to a complex landscape for charge transport. Little is known about the impacts of local BHJ structure on charge percolation across the active layer (out-of-plane).
In this presentation, we will delineate key structural features that impact out-of-plane charge transport in small molecule:fullerene BHJ active layers comprising p-DTS(FBTTh2)2:PC71BM. A series of 15 BHJ films with varying compositions and degrees of phase separation were characterized electrically by conductive atomic force microscopy (C-AFM) and structurally by grazing incidence x-ray diffraction (GIXD). C-AFM was used to quantify and map local hole mobility, while GIXD provided the crystallite size and population along π-π and alkyl stacking directions. These experiments show that the strongest predictor of out-of-plane charge carrier mobility across all morphologies is the in-plane π-π crystallinity within a film. This result is further supported by nanoscale hole mobility maps that show a halo of moderate hole mobility regions concentrated around high hole mobility hot spots, indicating lateral access of charge from the surrounding regions to the hot spots. Additional insight into the dependence of hole mobility on active layer composition and phase separation is provided by percolation theory. This analysis provides clues about the differences in domain connectivity that affect hole transport efficiency when the degree of phase separation is increased.
5:00 PM - MA02.05.07
Surface-Directed Multiscale Assembly of High-Performance Polymer Semiconductors for Printed Electronics
Erfan Mohammadi1,Fengjiao Zhang1,Ying Diao1
University of Illinois at Urbana Champaign1
Show AbstractPrinted electronics based on solution processable semiconducting polymers has emerged as a burgeoning technology that promises to revolutionize electronics manufacturing from transistors, sensors, solar cells, light-emitting diodes (LEDs), to medical devices. Unlike traditional electronic manufacturing that requires elevated temperature and high vacuum, organic electronics can be printed at near ambient conditions on flexible substrates to produce light-weighted, biointegrated electronics at low cost and large scale. It is well-known that substrate surface properties have a profound impact on morphology of thin films solution coated atop and the resulting solid-state properties. Therefore, it is important to establish general design rules to better understand surface-induced crystallization and develop material-agnostic methods for controlling morphology across multiple length scales at once during coating, not only to enable large-scale manufacturing of high-performance devices, but also for elucidating charge transport mechanism in conjugated polymers.
We have demonstrated that by modulating the free energy barrier to heterogeneous nucleation multiscale morphology of donor-accepter (D-A) conjugated polymers can be controlled during meniscus-guided solution coating [1, 2]. Lower nucleation free energy is associated with faster polymer crystallization addressing the disparity in time scales of polymer assembly and high-throughput coating. By conducting in-depth morphology characterizations, we concluded that surfaces with lower free energy barrier would increase thin film crystallinity, degree of molecular ordering and extent of domain alignment in synergy with unidirectional-flow. Notably, the enhanced morphology led to a significant increase in the charge carrier mobility in organic field-effect transistors along the polymer backbone as well as the pi-pi stacking direction. We further developed a free energy model, for the systems following classical nucleation theory, relating the substrate surface energy to the penalty of heterogeneous nucleation from solution in the thin film geometry. The model correctly predicts the experimental trend. The introduced generic model introduced is a significant step towards establishing design rules and understanding the critical role of substrates in determining morphology of solution coated thin films. Our methodology and mechanistic understanding have broad implications, given the importance of surface-induced crystallization across many disciplines.
References:
1- Zhang, F.*; Mohammadi, E.*; Luo, X.; Strzalka, J.; Mei, J.; Diao, Y. Lanmguir 2017, 8, 16070.
2- Mohammadi, E.; Zhao, C.; Zhang, F.; Qu, G.; Meng, Y.; Zhao, X.; Mei, J.; Zuo, J.; Shukla, D.; Diao, Y. Nat. Comm. 2017, 8, 16070.
5:00 PM - MA02.05.09
Tuning Molecule Diffusion to Control the Phase Separation of p-DTS(FBTTh2)2/EP-PDI Blend System via Thermal Annealing
Jiangang Liu1,3,Qiuju Liang1,2,Yanchun Han1,3
Changchun Institute of Applied Chemistry1,University of Chinese Academy of Sciences2,Chinese Academy of Sciences3
Show AbstractInterpenetrating bulk-heterojunction structure with domain size of 10-20 nm is the ideal morphology for carrier generation, separation and transportation in organic solar cells. However, film morphology of p-DTS(FBTTh2)2/EP-PDI blend systems is always far from satisfactory for nano-structure of optimal devices. When the weight ratio of p-DTS(FBTTh2)2/EP-PDI is greater than 8:2 or smaller than 4:6, large phase separation structure is observed induced by p-DTS(FBTTh2)2 or EP-PDI crystallization. When the ratio of p-DTS(FBTTh2)2/EP-PDI changes from 7:3 to 5:5, no obvious phase separation can be detected. In order to obtained the interpenetrating structure with domain size of 10-20 nm, we tuned the molecule diffusion of p-DTS(FBTTh2)2 and EP-PDI by thermal annealing. When the annealing temperature is T < Tm EP-PDI + Ta or T > Tc p-DTS(FBTTh2)2 - Tb (T is thermal annealing temperature, Ta and Tb are constants), molecule diffusion rate of both p-DTS(FBTTh2)2 and EP-PDI are too slow or too fast, resulting in no phase separation or large phase separation morphology. When T is between Tm EP-PDI + Ta and Tc p-DTS(FBTTh2)2 - Tb, p-DTS(FBTTh2)2 crystallized and formed framework. Thus p-DTS(FBTTh2)2 crystallization inhibited massive crystallization of EP-PDI, leading to the formation of bi-continuous phase separation structure. As a result, we constructed the phase diagram according to different blend ratio and thermal annealing temperature of the p-DTS(FBTTh2)2/EP-PDI crystalline-crystalline small molecule blend system. Furthermore, we revealed the phase separation mechanism and summarized guideline to construct bi-continuous phase separation structure with proper domain size and phase purity. Based on the bi-continuous phase separation structure we got, high performance of 4.25% power conversion efficiency was obtained.
5:00 PM - MA02.05.10
AC-Photothermal Measurements of the Transverse Thermal Diffusivity of Organic Semiconductors—Analysis and Results
Maryam Shahi1,Joseph Brill1
University of Kentucky1
Show AbstractKnowledge of the thermal conductivity (k) of new materials is essential for their application in both electronic (high k desired) and thermoelectric (low k desired) devices. We have developed a simplified ac-photothermal apparatus [1] for measurement of the transverse (i.e. through-plane for partly aligned polymers and interlayer for layered crystals) thermal diffusivity, D = k/c, where c is the specific heat per volume, of small samples. Our technique is essentially the Fourier transform of the laser flash method. The sample, with a typical area of 5 mm^2 and heated on its front side with chopped light, is placed in the dewar of an MCT detector close to the detector, which measures the thermal radiation from the back of the sample. For optically opaque samples, an analysis of the complex frequency dependence of the detector signal gives the transverse diffusivity; results will be presented for free-standing PEDOT:PSS films and samples of cellulose nanofibrils coated with PEDOT:PSS (samples provided by X. Crispin, Linkoping U.) For samples which are not opaque, the same analysis, overlooking the finite optical absorption length, can lead to a very large overestimate of the diffusivity. On the other hand, including the effect of finite absorption in the analyses can make their results less definitive. Here we show how the technique and analysis can be adapted for less absorbing samples and present our results for TIPS-pentacene (provided by J. Anthony, U. Kentucky), correcting the value we previously presented [1]. Research supported by NSF Grant # DMR-1262261
[1] J. W. Brill, et al, J. Appl. Phys. 118, 235501 (2015)
5:00 PM - MA02.05.11
High-Performance Non-Volatile Organic Transistor Memory via Energetic-Engineering of Small-Molecule Based Heterostructures
Wen Li1,Wei Huang1,2
Nanjing University of Posts and Telecommunications1,Nanjing Tech University2
Show AbstractThe rapid development of the information technology industry has led to the ever-increasing demand for mass data storage that has driven research towards high-capacity memory devices. Multi-level memory (MLM) enables high-density data storage per unit area without reducing the size of memory cells, hence overcoming downscaling limitations of lithography technology as well as reducing manufacturing costs. Owing to their multi-bit storage capability, non-destructive read-out, low cost, and good compatibility with flexible substrates, non-volatile organic field-effect transistor (OFET) memory has been regarded as a highly-promising candidate for applications in next-generation, large-area printed electronics.[1] To date, considerable efforts have been devoted to improving the charge-trapping capacity of OFET memory devices by developing functional gate dielectrics. In fact, the ability to tune the charge-trapping property within the organic semiconductor layer could also enable OFETs with memory functionality but currently has received far less attention from the research community.
In this work, non-volatile OFET memory devices based on pentacene/N,N′-ditridecylperylene-3,4,9,10-tetracarboxylic diimide (P13)/pentacene trilayer organic heterostructures are demonstrated.[2] The judiciously-controlled discontinuous n-type P13 film embedded into p-type pentacene layers can not only provide electrons in the semiconductor layer that facilitates electron trapping; it also works as charge trapping sites, which is attributed to the quantum well-like pentacene/P13/pentacene organic heterostructures. The synergistic effects of charge trapping in the discontinuous P13 film together with the gate-dielectric-modification charge-trapping layer, composed of poly(4-vinylphenol), can drastically improve the memory performance. The devices exhibit excellent non-volatile memory characteristics with stable data endurance characteristics of 3,000 programming/erasing cycles and long data retention time (extrapolated to >10 years). MLM characteristics with four stable data storage states are achieved due to the high charge capacity as well as the large memory window. Moreover, the trilayer organic heterostructures are also successfully applied to flexible non-volatile memory devices that remain excellent memory performance even after 10,000 bending cycles (bending radius = 10 mm), demonstrating their extraordinary mechanical properties. This study introduces novel organic heterostructures for the fabrication of high-capacity OFET memory devices for applications in next-generation printed electronics. More importantly, the concept of the quantum well-like organic heterostructures provides general guidelines to construct high-performance multi-bit OFET memory from the large library of organic materials to form similar energetically-favourable hetero-systems.
References
[1] Y.-H. Chou, et al., Polym. Chem., 2015, 6, 341-352.
[2] W. Li, et al., Adv. Sci., 2017, 4, 1700007.
5:00 PM - MA02.05.12
Solution-Grown Organic Single-Crystalline Heterojunctions
Huanbin Li1,Jiake Wu1,Ruihan Wu1,Guobiao Xue1,Yuhui Yang1,Hongzheng Chen1,Hanying Li1
Zhejiang University1
Show AbstractOrganic heterojunctions with high mobility are typically desired in order to achieve high performance devices such as complementary circuits, organic light emitting diodes (OLEDs) and organic solar cells. Thus, organic single crystals are ideal candidates for the junctions as they have the potential to exhibit the superior charge transport properties among organic materials with ordered molecular packing compared with their amorphous or polycrystalline counterparts. Despite the great efforts that have been made to fabricate organic single crystalline heterojunctions, there are still difficulties in fabricating organic single crystalline heterojunctions via a convenient solution method. Here, we demonstrate a facile one-step solution method to grow several organic single crystalline heterojunctions from a droplet of mixed solutions containing two types of organic semiconductor molecules. One example of the obtained heterojunctions demonstrates multiple properties like charge transport as well as charge recombination and electronic devices based on the obtained heterojunction have been made as light-emitting field-effect transistors (LEFETs).
5:00 PM - MA02.05.13
Can Addition of PVDF Affect the Electronic and Structural Landscape of Organic Photovoltaics?
Aditi Khirbat1,Ilaria Bargigia1,Giovanni Maria Matrone2,Mark Losego1,Carlos Silva1,Gitti Frey3,Natalie Stingelin1
Georgia Institute of Technology1,Imperial College London2,Technion - Israel Institute of Technology3
Show AbstractIn recent years, polymeric materials have attracted vast interest in the field of organic electronics, photonics and bioelectronics. One widespread use of π-conjugated polymers has been seen in the area of organic photovoltaics (OPVs). This is because of the promise this interesting class of ‘plastics’ offer for good processability and mechanical flexibility, and their potential to open pathways to print or coat devices onto any surface, including large-area structures. However, due to the low dielectric constant of most polymers (∼2 to ∼4), dissociation of coulombically-bound, photo-generated excitons into fully separated charges is challenging, resulting in high recombination losses and low device efficiencies [1]. We demonstrate here that blending of polymers may allow us to combine desired properties of individual components to enhance exciton generation, charge separation and transport, without the need to introduce all functionalities in a single material. We present a strategy to provide pathways that should assist to manipulate the dielectric constant of OPV blends by introducing poly(vinylene fluoride) (PVDF) [2] into donor:acceptor blends using solution deposition methods. We show that PVDF affects the phase morphology and other relevant microstructural features of the donor:acceptor system. For this purpose, we use binary (donor polymer:PVDF) and ternary (donor:acceptor:PVDF) phase diagrams constructed from differential scanning calorimetry (DSC) and visualized by vapor phase infiltration (VPI) [3] and scanning electron microscopy (SEM) techniques. We correlate photo-physical processes and device characteristics with these ternary blend microstructures, and demonstrate that by controlling device phase morphology and its dielectric properties, we gain an additional tool to manipulate device functions.
[1] Y. Tamai et al., J. Phys. Chem. Lett. 2015, 6, 3417−3428
[2] K. Asadi et al., Appl. Phys. Lett. 2011, 98, 183301
[3] S. Obuchovsky et al., Solar Energy Materials & Solar Cells. 2015, 280–283
5:00 PM - MA02.05.14
Ultrathin Ion-Gel Film Displaying High Capacitance at Megahertz Switching Frequency—A Promising Solid-State Gate Insulator Material, for Low-Voltage Thin-Film Transistors, Enabled by Initiated Chemical Vapor Deposition (iCVD)
Minghui Wang1,Andong Liu1,2,Stefan Schroeder1,Junjie Zhao1,Karen Gleason1
Massachusetts Institute of Technology1,Harvard Medical School2
Show AbstractThin film transistors (TFTs), especially organic TFTs (OTFTs), play a key role in enabling the next-generation flexible electronics. Nevertheless, challenges remain on developing TFTs with low power consumption. A common solution to reduce power consumption is to reduce operation voltage by increasing the capacitance of a gate insulator material, because capacitance is inversely related to the voltage. To this end, ionic liquid gel (ion-gel) based solid-state electrolytes are promising replacement for traditional inorganic or organic high-k dielectric materials, because they have much higher capacitance than that of traditional dielectric materials (e.g., 1-10 µF cm-2 versus 0.1 µF cm-2). The high capacitance of ion-gel originates from the formation of electrical double layers (EDLs) at gate/ion-gel and ion-gel/semiconductor interfaces. However, the capacitance of an ion-gel film generally reduces rapidly at switching frequencies higher than 10-100 KHz, preventing its application in megahertz (MHz) TFTs. The high frequency limitation stems from the overall slow polarization/diffusion rate of ions within the insulating layer. The past researches, pioneered by Frisbie and Lodge groups, focused on maximizing the ionic conductivity to enhance the high frequency capacitance. On the other hand, reducing the thickness of an ion-gel insulating layer (e.g., to sub-micron) should, in theory, improve its frequency response too. But, it is extremely challenging to prepare pinhole-free sub-micron ion-gel layers via solution-based techniques. Herein, we employed a solvent-free technique, initiated chemical vapor deposition (iCVD), to first deposit ultrathin dry polymer films, followed by injecting ionic liquid into these swellable polymer films to form ion-gel films as thin as 20 nm. These ultrathin pinhole-free ion-gel films can retain a capacitance greater than 1 µF cm-2 at a frequency up to 1 MHz, making them promising gate insulator materials for low-voltage MHz TFTs. In addition, ion-gel films obtained from this new strategy is soft substrate (e.g., plastics) compatible, and patternable, which are beneficial for fabricating soft electronics.
5:00 PM - MA02.05.15
Two-Dimensional N-Type Molecular Single-Crystalline Films with High Charge Carrier Mobility
Cong Wang1,Xiaotao Zhang1,Wenping Hu1
Tianjin University1
Show AbstractTwo-dimensional (2D) crystal films of organic semiconductors have attracted widespread attention for large-area and low-cost flexible optoelectronics due to their unique advantages of molecular designability, excellent flexibility and solution processability. The 2D crystal films of a series of p-type organic semiconductors are grown up to centimeter size with thickness of several molecular layers by “solution epitaxy” and a carrier mobility exceed 10 cm2 V-1 s-1 is achieved in our previous work. However, it remains challenging to achieve high mobility, air-stable and solution-processed organic field-effect transistors (OFETs) based on 2D crystal films of n-type materials with a performance comparable to that of p-type organic semiconductors. Here, a modified technique is demonstrated to grow 2D single crystals of n-type organic semiconductors from solution, enabling high-mobility electron transport in OFET devices.
5:00 PM - MA02.05.16
Field-Plate Design Optimization for High-Voltage Organic Thin-Film Transistors
Andy Shih1,Akintunde Akinwande1
Massachusetts Institute of Technology1
Show AbstractDesign of a high-voltage organic thin film transistor (HVOTFT) with the addition of a bottom field plate have shown improvements in the critical and breakdown field via numerical simulation. Such a field plate can help push the boundaries of high-voltage operation in organic thin film transistors (OTFT) technology beyond a drain to source voltage (VDS) of 500 V while being controlled by a low gate to source voltage VGS. High-voltage operation is not well developed in OTFT technology, and would allow the integration of HVOTFTs with large electrostatic MEMS actuators or photovoltaic systems on glass. The HVOTFT is designed with a dual accumulation region and dual threshold voltage to minimize the electric field peak within the channel. The design is also compatible with low temperature processing, self-assembled monolayer treatments and organic semiconductor solution-processing, for low cost and flexible applications.
5:00 PM - MA02.05.18
Side-Chain Functionalized DPP Copolymer Semiconductors for Stretchable and Self-Healable Organic Transistors
Sang Jin Lee1,Satej Dharmapurikar2,Moo Yeol Lee1,Changduk Yang2,Joon Hak Oh1
Pohang University of Science and Technology (POSTECH)1,Ulsan National Institute of Science and Technology (UNIST)2
Show AbstractStretchable electronic devices have attracted extensive interest because of their potential applications for next-generation wearable electronic devices. Intrinsically stretchable semiconducting layers are important for the fabrication of large-area and simple integration processing of electronic devices with uniform electronic properties. The stretchability of semiconducting layers can be enhanced by rational molecular structure design of the side-chain or backbone of conjugated polymers. Recently, the side-chain engineering has been focused on the field of polymeric electronics since it can greatly enhance the solubility and electrical properties of polymers. Herein, we report diketopyrrolepyrrole(DPP)-based copolymers functionalized with urethane side-chain for applications as stretchable electronics. These polymers have three different backbone units. Because of the dynamic non-covalent bonding of urethanes, the fabricated semiconducting layers showed good stretchability as well as self-healable properties. Our results demonstrate the high potentials of urethane side-chain substituted DPP-based polymers for next-generation wearable electronics.
5:00 PM - MA02.05.19
Small Molecule Organic Photovoltaic Modules Fabricated via Halogen-Free System with Roll-to-Roll Compatible Scalable Printing Method
Youn-Jung Heo1,Yen-Sook Jung1,Kyeongil Hwang1,Jueng-Eun Kim1,DaeHee Lim1,Yunseul Kim1,Dong-Yu Kim1
Gwangju Institute of Science and Technology1
Show AbstractOrganic conjugated molecules have a great potential for cost-competitive, large-area and high throughput mass production on mechanically flexible substrate. In particular, small molecule, which is one of the organic conjugated molecules, have several distinct advantages such as well-defined molecular structure, high purity, and less batch-to-batch variation. During recent years, organic solar cells based on the small molecules have accomplished considerable progress, reaching the PCEs over 10%. Now, for further advances in this field, printed or halogen free fabricated small molecule solar cells should be also demonstrated. In this study, blend films of small molecules, benzodithiophene terthiophene rhodanine (BTR) and PC71BM were slot-die coated using a halogen-free solvent system. Moreover, for up-scaling production, we fabricated small molecule solar cells with not only time-consuming solvent vapor annealing (SVA) treatment but also more roll-to-roll compatible solvent additive approaches. The suitability of halogen-free additive method for up-scaling production was analyzed by using UV-vis absorption, EQE, AFM, TEM, SCLC, Light intensity and 2D-GIWAXS measurements. As a result, high efficiencies of 7.46% and 6.56% were achieved from time-consuming solvent vapor annealing (SVA) treatment and roll-to-roll compatible solvent additive approaches, respectively. After successful verification of our roll-to-roll compatible additive method on small-area devices, we finally demonstrated large-area photovoltaic modules composed of 4 stripes with a total active area of 10 cm2, achieving a power conversion efficiency (PCE) of 4.8%.
5:00 PM - MA02.05.20
High Performance Solid Polymer Electrolyte Atomic Switching Device Using poly-4-vinylphenol (PVP)/poly(melamine-co-formaldehyde) (PMF)
Dong-Ho Kang1,Jin-Hong Park1
Sungkyunkwan University1
Show AbstractAtomic switches, which are operated by the formation/decomposition mechanism of conduction filaments (redox-based electrochemical reactions), have been explored as next-generation switching devices due to their low operating voltage (<0.05 V), high on/off-current ratio (>106), extremely high retention time (> 10 years), and good cyclic endurance (>106). Recently, for future electronic applications, such as electronic skin and flexible devices/circuits, flexible polymer materials are considered as the most promising solid electrolyte layer for high-performance flexible atomic switching devices. Wu et al.[1] demonstrated a flexible and transparent atomic switching device with using polyethylene oxide (PEO) as an electrolyte layer, and this device showed high on/off resistance ratio (105), fast switching speed (<1 μs), and long retention time (>1 week). Hosseini et al.[2] fabricated chitosan-based atomic switching device with on/off-current ratio of 105 and operation voltage of 0.6 V.
Here, we fabricated a high-performance solid polymer electrolyte (SPE) atomic switching device with using poly-4-vinylphenol (PVP) / poly(melamine-co-formaldehyde) (PMF). Our PVP/PMF atomic switches showed low SET/RESET voltages (0.25 and –0.5 V, respectively), high on/off-current ratio (105), excellent cyclic endurance (>103), and long retention time (>104 sec). To accomplish these excellent bipolar switching property and device stability, we applied two key techniques: i) the adjustment of the number of cross-linked chains to modulate the Cu ion diffusion and electrical insulating property in the PVP/PMF electrolyte, and ii) the insertion of a Ti buffer layer to control the number of diffused Cu ions and supply electrons into the PVP/PMF electrolyte. By increasing the number of cross-linked chains through the adjustment of the PVP/PMF ratio, we improved the insulating property of the PVP/PMF electrolyte, decreasing the off-current level of the PVP/PMF switching device. The Ti-buffer layer supplied electrons to the PVP/PMF electrolyte and acted as a diffusion barrier for Cu ions. Thus, we dramatically improved the bipolar switching property (SET/RESET voltages ↓ and on/off-current ratio ↑) and device stability (maximum cyclic endurance ↑ and HRS/LRS retention time ↑).
REFERENCES
[1] Wu et al. Adv. Funct. Mater. 2011, 21, 93-99.
[2] Hosseini et al. ACS Nano 2015, 9, 419-426.
5:00 PM - MA02.05.21
Structure-to-Photovoltaic Property Relationships in New Small Molecule Acceptors
Shinyoung Choi1,Yukyung Shin1,Suhee Ro1,BongSoo Kim1
Ewha Womans University1
Show AbstractOPVs with high efficiencies at present rely on fullerene-based acceptors, which suffer from several issues such as high synthetic cost, morphological instability, limited visible light absorption, and poor electronic tunability. In this presentation, we have synthesized a series of small molecule acceptors (DFDE-R and DFDO-R) comprised of electron-rich dithienosilole (D) and electron-deficient difluorobenzodiathiazole (F), benzodiathiazole-connected, 3-ethylrhodanine (R) units, and alkyl chains of 2-ethylhexyl (E) and octyl (O) groups. However, the polymer:DFD-R devices showed low PCEs mainly due to the high HOMO energy levels of the small molecule acceptors. To lower the energy level of the HOMO, modifications to the backbone structure were made by replacing 2FBT with difluorobenzene (FBz). Inverted BHJ devices employing polymer donors and newly synthesized DFBz-R acceptors exhibited higher PCEs relative to that of polymer:DFD-R devices. Furthermore, these new non-fullerene acceptors are synthetically scalable and stable under ambient conditions. Our investigation on the various synthesized molecules revealed the structure-photovoltaic properties, which can guide in synthesis of new high-performance non-fullerene small molecules for the advancement in the field of organic solar cells.
5:00 PM - MA02.05.22
High-Performance Self-Doped Conductive Conjugated Polyelectrolytes as Hole-Transporting Layer in Organic Bulk Heterojunction Solar Cells
Suhee Ro1,Shinyoung Choi1,Boseul Choi1,Yukyung Shin1,BongSoo Kim1
Ewha Womans University1
Show AbstractWe report the synthesis of a narrow-band-gap, anionic conjugated polyelectrolyte, PCPDT-FBT-SO3K and PCPDT-F2BT-SO3K for applying to the hole-transporting layer (HTL). Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) has been extensively used as HTL in bulk heterojunction (BHJ) solar cells. However, its anisotropic electrical conduction and intrinsic acidic nature limit the device performance and stability. To overcome these drawbacks of PEDOT:PSS, PCPDT-BT-SO3K was synthesized which has properties of homogeneous electrical conduction, neutral PH. Though PCPDT-BT-SO3K enhanced power conversion efficiency (PCE), organic photovoltaic device using PCPDT-BT-SO3K displayed reduced an open-circuit voltage (Voc) compared with device using PEDOT:PSS as HTL. By contrast, newly synthesized PCPDT-FBT-SO3K and PCPDT-F2BT-SO3K polymers increasing work function of ITO substrates exhibited higher PCEs with higher Voc than PCPDT-BT-SO3K polymer. Overall, this work demonstrate the chemical tuning of conjugated polyelectrolytes can improve the photovoltaic performance of organic solar cells.
5:00 PM - MA02.05.23
The Evolution of Solution-Processed C60 Single-Crystalline Ribbons During Thermal Treatment
Qinfen Li1,Hongzheng Chen1,Hanying Li1
Zhejiang University1
Show AbstractThe pure C60 molecules tend to closely pack into hexagonal close-packing (HCP) and face-centered cubic (FCC) single crystals and the FCC structure is energetically favorable due to larger cohesive energies. Its cubic lattice often leads to polyhedral shapes in crystallization but not extended thin plates, which impede the application of C60 single crystals in electronic devices. By forming solvates, solvent-assisted methods have been proven to be effective for controlling the growth habit of C60 molecules into the desired extended ribbon morphologies that are suitable for thin-film devices such as field-effect transistors (FETs). However, for electronic application, the residual solvent molecules in crystal lattice not only impede the transport of charge carriers between semiconductor molecules, but also complicate the electronic environment due to polarization. Thus, it is essential to obtain C60 single crystals with desirable morphologies, while at the same time, the adverse effect of residual solvent is minimized. Here, well aligned C60 ribbon-like single crystals were grown from mixed solvent of m-xylene and carbon tetrachloride. After thermal treatment, the solvent molecules were extracted from the solvated structure. With partially evolving into HCP structure, FETs based on the C60 ribbons showed decreased threshold voltages between 9.09 and 24.33 V with a moderate average electron mobility of 2.19 ± 0.78 cm2 V-1 s-1.
5:00 PM - MA02.05.24
Polymer Single Crystal Dielectrics for Organic Field Effect Transistors
Yuhui Yang1,Hongzheng Chen1,Hanying Li1
Zhejiang University1
Show AbstractSingle crystal dielectrics are ideal candidates for high-performance organic field effect transistors due to the ordered molecular packing and smooth surface. However, it doesn’t obtain much attention due to the lack of facile preparation methods. Here, solution-grown smooth polymer single crystal with width in tens of microns are obtained and used as the dielectric for the organic field effect transistors (OFETs). The interface between the semiconductor and the polymer single crystal dielectrics are more favorable to the charge carrier transport than spin-coated polymer thin-film dielectrics, exhibiting much higher charge mobility. With 6,13-bis(triisopropylsilylethynyl)-pentacene (TIPS-pentacene) single crystal as semiconductor layer, the average OFET mobility reaches up to 1.70±0.97 cm2V-1s-1 with a highest value of 4.95 cm2V-1s-1. This result demonstrated that structural ordering of the polymer dielectrics is critical to further advance the high-performance OFET devices.
5:00 PM - MA02.05.27
Influence of Doping Mechanisms on Microstructure and Charge Transport of Organic Molecules
Bharati Neelamraju1,Kristen Watts1,Jeanne Pemberton1,Erin Ratcliff1
University of Arizona1
Show AbstractOrganic semiconductors (OSCs) have incredible prospects for next-generation, flexible electronic devices including bioelectronics, opto-electronics, energy harvesting and storage. They are flexible, biocompatible, printable, low cost, efficient and sustainable semiconductor materials with hybrid electrical and ionic conductivities, which can expand the functionality and accessibility of electronics beyond silicon.
Yet many fundamental challenges still exist in understanding the morphology, microstructure and charge transport processes of OSCs, with intimate connection to processing techniques and control over doping mechanisms. Firstly, solution processing prohibits definitive control over microstructure, which is fundamental for controlling electrical and ionic transport properties necessary for the development and advancement of new technologies. Second, OSCs generally suffer from poor electrical conductivities due to a combination of low carriers and low mobility, which limits overall efficiencies. Hence understanding different doping mechanisms and their influence on microstructure and charge transport properties is important for increased efficiencies of organic devices. To compete with their inorganic counterparts, characterization of the structural, electronic, and charge transport attributes of these organic semiconductor materials with respect to processing parameters and doping mechanism plays an important role for device engineering.
This effort considers the two questions of interest: (i) How does the microstructure change with chemical and electrochemical doping mechanisms and (ii) how do these changes in microstructure impact the electronic and charge transport properties. Addressing these questions will also allow us to connect the electronic and structural properties with fabrication processes and doping, to control the structural properties, and link their electronic properties with emphasis on charge transport.
Synchrotron based high energy X-ray scattering techniques, specifically grazing incidence wide angle X-ray scattering (GIWAXS) and small angle X-ray scattering (SAXS) are ideal techniques to measure intra- and inter-molecular spacings and phase segregation effects. In this work, GIWAXS was used to study the microstructural features ranging from sub angstrom to nanometer length scales, a key regime for transport in organic materials. GISAXS was used to study the structures greater than the nanometer length scale to understand phase segregations due to doping mechanisms. Electronic properties are measured using spectroscopy and correlated with electrochemical density of states. Transport properties are analyzed using cyclic voltammetry, mobility and conductivity measurements. Collectively, these measurements allow us to design organic semiconductor systems with controllable behaviors for next-generation technologies.
5:00 PM - MA02.05.28
Use of Ultrafine Silver-Pattern Printing for Organic Thin-Film Transistors—Low-Voltage Operation with Ultrathin Polymer Gate-Dielectric Layers
Gyo Kitahara1,2,Keisuke Aoshima1,Jun'ya Tsutsumi2,Hiromi Minemawari2,Shunto Arai1,Tatsuo Hasegawa1,2
The University of Tokyo1,National Institute of Advanced Industrial Science and Technology2
Show AbstractThe printing-based patterned-layer formation of electrode metal layers are one of the key printed electronics technologies. Recently, we developed a groundbreaking electrode printing technique, called as “surface photoreactive nanometal printing (SuPR-NaP)”, which allows easy manufacture of ultrafine conductive silver patterns with a high submicron resolution [1]. This technique is based on the unique chemisorption effect of silver nanoparticles (AgNPs) on a photo-activated patterned polymer surface that is manufactured by masked ultraviolet irradiation of a perfluoropolymer, Cytop (Asahi Glass Co., Ltd.), layers. The SuPR-NaP technique allows us to produce ultrafine electrode patterns with minimum line width of 0.8 micron, by which the mass production of transparent conductive electrodes is now undertaken for the use as touch screen sensors. The next important target of the printing technique is to use and accommodate the printed ultrafine electrode patterns for the production of organic thin-film transistor (OTFT) arrays on flexible plastic substrates.
In this presentation, we will present and discuss low-voltage operation of OTFTs composed of ultrafine printed source/drain electrodes produced by the SuPR-NaP technique [2]. For this purpose, we utilized the highly-insulating Cytop layer, not only for producing the photo-activated patterned surface for the SuPR-NaP technique, but also as the gate dielectric layer for producing bottom-gate, bottom contact OTFTs [3]. To realize the low-voltage operation of OTFTs, we systematically examined the thickness, voltage-durability and capacitance of the thin Cytop layers. We found that the ultrathin thickness as thin as 26 nm is useful to obtain high-voltage durability up to 2.4 MV/cm and large-capacitance of 97 nF/cm2, even after the top printed silver electrodes are deposited by the SuPR-NaP technique. Based on the examination, we successfully operated polycrystalline pentacene OTFTs using the ultrathin Cytop layer, at low voltage less than 2 V with negligible hysteresis characteristics. Additionally, we found that the surface modification of the printed silver electrodes with pentafluorobenzenethiol is effective to suppress the contact resistance and to enhance the drain current. We will discuss the stable low-voltage operation of the OTFTs in terms of the formation of high-quality semiconductor/gate insulator interface with use of the ultra-hydrophobic nature of the surfaces of ultrathin Cytop layers.
[1] T. Yamada et al., Nat. Commun. 7, 11402 (2016). [2] G. Kitahara et al., Organic Electron. 50, 426 (2017). [3] K. Aoshima et al., Organic Electron. 41, 137 (2017).
5:00 PM - MA02.05.29
Electron Transport at the Interface of Organic Semiconductors and Organic Hydroxyl-Containing Dielectrics
Jiang Huihong1,Li Hanying1
Zhejiang University1
Show AbstractHydroxyl groups are generally treated as electron traps in organic field-effect transistors (OFETs), which make it difficult to achieve high electron transport at the interface of organic hydroxyl-containing dielectrics and organic semiconductors. Here, we adopted the drop-pinned crystallization (DPC) method to obtain well-aligned C60 single-crystal ribbons on different hydroxyl-containing polymer dielectrics, such as polyvinyl alcohol (PVA), poly 4-vinyl phenol (PVP), and got a high electron mobility (more than 1 cm2 V-1 s-1). Single crystals used here were good candidates for investigating the intrinsic electrical properties of organic semiconductors owing to high orientation and purity. Also, the ambipolar performance of 6,13-bis(triisopropylsilylethynyl) pentacene (TIPS-pentacene) was firstly observed in PVP dielectric FET devices (average hole mobility: 0.436 ± 0.266 cm2 V-1 s-1, average electron mobility: 4.58 × 10-2 ± 4.82 × 10-2 cm2 V-1 s-1). These findings reveal that well-aligned single crystals can show excellent electron transport even on the surface of organic hydroxyl-containing dielectrics.
Symposium Organizers
Jianguo Mei, Purdue University
Hanying Li, Zhejiang University
Joon Hak Oh, Pohang University of Science and Technolog (POSTECH)
Tse Nga Ng, University of California, San Diego
Symposium Support
MilliporeSigma (Sigma-Aldrich Materials Science)
MA02.06: Multi-Functioning
Session Chairs
Thursday AM, April 05, 2018
PCC West, 100 Level, Room 102 BC
8:00 AM - MA02.06.01
Charge Transport and Thermoelectric Physics of High Mobility Organic Semiconductors
Henning Sirringhaus1
Cambridge University1
Show AbstractOver recent years several new classes of conjugated polymer and molecular semiconductors have shown promise as high mobility materials for organic field-effect transistors. We have been interested in understanding their fundamental charge transport physics and the underpinning relationship between molecular structure and charge transport properties. Information about their electronic structure can be gained from measurements of fundamental transport coefficients such as Hall effect and Seebeck coefficient. In particular, the Seebeck coefficient provides direct insight into the density of states available for transport and complements measurements of the carrier mobility as a function of temperature and carrier concentration. In this presentation we will review our current understanding of the charge transport and thermoelectric properties of these materials and discuss these in the context of applications in electronics, optoelectronics and thermoelectrics.
8:30 AM - MA02.06.02
Organic Nanofiber Neuromorphic and Deformable Electronics
Tae-Woo Lee3,Yeongjun Lee1,2,3,Jin Young Oh2,Wentao Xu1,2,3,Zhenan Bao2
Pohang University of Science and Technology1,Stanford University2,Seoul National University3
Show AbstractWe report our recent progress in printed organic nanofiber-based neuromorphic and deformable electronics. Precisely controlled organic nanofibers are promising elements for upcoming innovative electronics such as brain-inspired computation and memory, light-weight wearable electronics and biomedical electronics based on their advantages of low-cost solution printing process, high speed and large scale fabrication, high-resolution (< 1μm) patterning, and so on. We reported organic nanofiber-based neuromorphic synapses which emulated important working principles of a biological synapse, e.g., excitatory post-synaptic current (EPSC), inhibitory post-synaptic current (IPSC), paired-pulse facilitation (PPF), short-term plasticity (STP), long-term plasticity (LTP) and spike-timing dependent plasticity (STDP). Electrochemical synaptic transistor arrays with nano-feature size were produced based on aligned organic semiconducting nanofibers and ion-gel dielectric which mimic fiber-like morphology of neurons and biological synaptic cleft. These properties are promising for neuromorphic computation and memory, and the devices would serve as building blocks of future neuromorphic systems. We also recently developed aligned organic semiconducting nanofiber-based deformable electronics which are impervious to mechanical influence when mounted on the surface of dynamically-changing soft matter. Our deformable field-effect transistors can be easily deformed by applied strains (both 100% tensile and compressive strains). The mechanical durability of nanofiber can be further significantly increased by simply re-engineering the geometric structure of the nanofiber. The deformable transistors withstood 100% uniaxial stretching with minimal change of electrical properties, even after a 3D volume change (> 1700% and back to original state) of a rubber balloon. The deformable transistors robustly operated on a mechanically-dynamic soft matter surface e.g. a pulsating balloon that mimics a beating animal heart, which demonstrates potential of the deformable transistor for future biomedical applications.
9:00 AM - MA02.06.03
Mechanical Properties of Organic Semiconductors
Darren Lipomi1
University of California, San Diego1
Show AbstractThis presentation describes my group’s efforts to understand the molecular and microstructural basis for the mechanical properties of organic semiconductors for organic photovoltaic (OPV) devices. Our work is motivated by two goals. The first goal is to mitigate mechanical forms of degradation of printed modules during roll-to-roll fabrication, installation, and environmental forces—i.e., wind, rain, snow, and thermal expansion and contraction. Mechanical stability is a prerequisite for inexpensive processing on flexible substrates: to encapsulate devices in glass is to surrender this advantage. The second goal is to enable the next generation of ultra-flexible and stretchable solar cells for collapsible, portable, and wearable applications, and as low-cost sources of energy—“solar tarps”—for disaster relief and for the developing world. It may seem that organic semiconductors, due to their carbon framework, are already sufficiently compliant for these applications. We have found, however, that the mechanical properties (stiffness and brittleness) occupy a wide range of values, and can be difficult to predict from molecular structure alone. We are developing an experimental and theoretical framework for how one can combine favorable charge-transport properties and mechanical compliance in organic semiconductor films. In particular, we have explored the roles of the backbone, alkyl side chain, microstructural order, the glass transition, molecular packing with fullerenes, plasticizing effects of additives, extent of separation of [60]PCBM and [70]PCBM, structural randomness in low-bandgap polymers, and reinforcement by encapsulation, on the mechanical compliance. We are exploring the applicability of semi-empirical “back-of-the-envelope” models, along with multi-scale molecular dynamics simulations, with the ultimate goal of designing electroactive organic materials whose mechanical properties can be dialed-in. We have used the insights we have developed to demonstrate several new applications for OPV that demand extreme compliance, including biaxial stretching and conformal bonding of whole devices to hemispheres, and devices with ultrathin encapsulation mounted on human skin that survive significant cyclic mechanical deformation in the outdoor environment.
9:30 AM - MA02.06.04
Flexible, Stretchable and Healable Electronics
Fabio Cicoira1
Ecole Polytechnique de Montreal1
Show AbstractOrganic electronics, based on semiconducting and conducting polymers, have been extensively investigated in the past two decades and have found commercial applications in lighting panels, smartphone screens, and TV screens using organic light emitting diodes technology. Many other applications are foreseen to reach the commercial maturity in future in areas such as transistors, sensors and photovoltaics.
Organic electronic devices, apart from consumer applications, are paving the path for key applications at the interface between electronics and biology. In such applications, organic polymers are very attractive candidates, due to their distinct properties of mechanical flexibility, self-healing and mixed conduction, i.e the ability to transport both electron/holes and ionic species.
My group investigated the processing conditions leading to high electrical conductivity, long-term stability in aqueous media as well as robust mechanical properties of the conducting polymer poly(3,4-ethylenedioxythiophene) doped with polystyrenesulfonate (PEDOT:PSS), on rigid, flexible and stretchable substrates [1-3]. We have demonstrated that stretchable PEDOT:PSS films can be achieved by adding a fluorosurfactant to the film processing mixture and by pre-stretching the substrate during film deposition. We have achieved patterning of organic materials on a wide range of substrates, using orthogonal lithography, parylene patterning and pattern transfer [4-5]. Recently we have discovered that PEDOT:PSS films can be rapidly healed with water drops after being damaged with a sharp blade [6].
My talk will deal with processing, characterization and patterning of conducting polymer films and devices for flexible, stretchable and healable electronics. I will particularly focus on the strategies to achieve films with optimized electrical conductivity and mechanical properties, on unconventional micro patterning on flexible and stretchable substrates, on the different routes to achieve films stretchability and self-healing.
F. Cicoira et al. APL Mat. 3, 014911, 2015.
F. Cicoira et al. Appl. Phys. Lett. 107,053303, 2015.
F. Cicoira, et al. Appl. Phys. Lett., in press (APL17-AR-02492R1).
F. Cicoira et al. Chem. Mater. 29, 3126-3132, 2017.
F. Cicoira et al. J. Mater. Chem. C 4, 1382–85, 2016.
F. Cicoira et al. Adv. Mater., 29, 1703098, 2017.
9:45 AM - MA02.06.05
Stretchy, Rubbery Integrated Electronic Circuits and Sensing Devices Based on High-Performance Rubbery Semiconducting Nanocomposites
Kyoseung Sim1,Cunjiang Yu1,Haejin Kim1
Univ of Houston1
Show AbstractStretchable electronics has expanded the application scope of the electronics and sensors particularly for health monitors, medical implants, artificial skins and human-machine interfaces. To accommodate the mechanical stretchability to nonstretchable electronic materials, the structural engineering design from special mechanical structures or architectures has been widely exploited. An alternative route to eliminating the burden of constructing dedicated architectures and the associated sophisticated fabrication processes is to build stretchable electronics from rubbery electronic materials, which have potential toward scalable manufacturing, high-density device integration, and large strain tolerance. Here, we report a low voltage operational (< -3 V) high performance rubbery electronics including a field effect transistors (FETs), integrated circuit (inverter, NOR, and NAND gate), and an active matrix with pressure sensor based on all rubbery electronic components; semiconductors, electrodes, and gate dielectrics. For the high-performance devices, the semiconductor material (P3HT nanofibril and PDMS composite) is doped with multiwall carbon nanotubes, by dry transfer to enhance the field-effect mobility. The FETs and circuits show a normal operation under the mechanical stretching strain of up to 50%. The approach to constructing integrated circuits and active matrix all from elastomeric rubbery electronic materials will move forward the advancement of stretchable electronics for a wide range of applications, such as artificial skins, biomedical implants, and wearable applications.
10:30 AM - MA02.06.06
Side Chain Engineering—Evaluation of Intrinsically Stretchable Semiconducting Polymers for Soft Electronics
Wen-Chang Chen1,Hung-Chin Wu1,Han-Fang Wen2
National Taiwan Univ1,National Taipei University of Technology2
Show AbstractStretchable and deformable materials are nowadays important for the next-generation wearable electronics since they potentially can be biocompatible and possess distinct functionalities with our body movement. Stretchable devices, such as field-effect transistors, solar cells or memories based on polymeric materials have been demonstrated. However, it is still challenging to achieve stable and high electrical performance using an intrinsically-strained active layer. A semiconducting polymer system that possesses both superior electrical behavior and high stretchability, therefore, is needed.
Side chain engineering has been focused on the field of polymeric electronics very recently since rational side chain design can significantly manipulate the solution processability, solid state molecular stacking and thin film morphology. From the view of soft electronics, we aim to achieve a ductile active layer by controlling the inter-chain packing interaction and surface morphology based on the side chain substituents.
In this talk, two side chain design strategies on isoindigo-based conjugated backbone will be presented. Firstly, carbosilane side chains have been introduced with a simple synthetic pathway to evaluate long and branched side chains in high yields. A high mobility of 8.06 cm2V-1s-1 was probed using a top-contact transistor device based on carbosilane side chains consistent of a 8 carbon linear spacer plus two octyl chains after branching. More interestingly, such polymers possess a relatively low tensile modulus (< 0.4 GPa) and showed a stable mobility higher than 1 cm2V-1s-1 even under a 60% strain, which is one of the most successful example using a single conjugated polymer for soft and intrinsically stretchable transistor applications. Furthermore, the odd-even effect have been also explored for this carbosilane side chains system to understand the relationship between side chain length, thin film deformability, and stretchable device performance. Secondly, a low glass transition temperature (i.e. -54 oC) poly(butyl acrylate) (PBA) side chains has been incorporated to the conjugated polymer system. The soft PBA segment offers a great opportunity to improve the mechanical property of semiconducting polymer thin films that typically contain lots of rigid conjugated rings. As a result, this set of polymers exhibited superior thin film ductility with a low tensile modulus down to 0.12 GPa, and the mobility at 60% strain could be remained almost the same as non-stretched (i.e. 0% strain) condition. Based on our achievements, both side chain system showed not only good charge transport ability but also thin film ductility under intrinsically stretching, suggesting these newly-designed materials possessed great potential for next-generation wearable electronics.
11:00 AM - MA02.06.07
A Universal Approach for High-Performance Multi-Level Non-Volatile Organic Transistor Memory Using Small-Molecule/Polymer-Electret Blends
Wen Li1,2,Yen-Hung Lin3,Wei Huang1,4,Thomas Anthopoulos2,5
Nanjing University of Posts and Telecommunications1,Imperial College London2,University of Oxford3,Nanjing Tech University4,King Abdullah University of Science and Technology (KAUST)5
Show AbstractIn an effort to address the fast-growing demand for data storage within the emerging sector of printed electronics and its wider deployment in the Internet of Things, solution-processable polymer-electret based charge-trapping organic field-effect transistor (OFET) memory technologies have been attracting increasing attention owing to their intriguing characteristics, including non-destructive read-out, easily integrated structures for circuitry, inexpensive fabrication processes for large-area manufacturing.[1] However, to date a polymer electret OFET memory often requires multiple fabrication steps, including both vacuum- and solution-phase deposition techniques. This is mainly because full solution-processing is limited by solvent orthogonality during the sequential depositions of organic layers (i.e. polymer electrets and organic semiconductors). To simplify fabrication protocols, hence reducing manufacturing costs, alternative processing approaches and/or materials systems for polymer electret OFET memory are urgently needed.
Here we report a universal approach for developing an alternative semiconducting system based on organic blends using small molecules and polymer electrets and its application in non-volatile OFET memories. Such blend systems are known to self-assemble into two vertically separated components due to the phase separation occurring during the film deposition, hence forming a high mobility semiconductor layer (small-molecule) and a charge trapping layer (polymer electret). Using this approach, solution-grown 6,13-Bis(triisopropylsilylethynyl)pentacene (TIPS-PEN)/polystyrene (PS) blend OFET memory devices exhibit excellent non-volatile memory characteristics with a fast switching speed (~50 µs, despite the long channel length, 30 µm, employed), low operation voltages (<15 V), and highly-stable 8-level (i.e. 3 bits) data storage characteristics. This development paves the way to high-density data storage using single memory cells and could potentially minimize the overall system cost without the need for device-size downscaling and/or complex integration.
Furthermore, we were able to demonstrate flexible, non-volatile TIPS-PEN/PS based OFET memories with superb operating characteristics, such as highly-reliable memory operation with programming/erasing cycles well in excess of 10,000. Finally, the same blend material approach is successfully extended to other high-mobility organic semiconductors such as 2,7-Dioctyl[1]benzothieno[3,2-b][1]benzothiophene (C8-BTBT) blended with PS, further demonstrating the universal nature of the proposed technology. The development of such single-step deposited charge-trapping polymer electret and organic semiconductor systems not only simplifies the manufacturing protocols but also creates a new promising direction for future research in the emerging area of printed memory systems.
Reference
[1] W.-C. Chen, Electrical Memory Materials and Devices, Royal Society of Chemistry, Cambridge, 2015.
11:15 AM - MA02.06.08
Optimized Inkjet-Printed Line Morphology by a Novel Segmented Drop Placement Method
Gerd Grau1,Ragheb Abunahla1
York University1
Show AbstractPrinted electronics promises to fabricate low-cost microelectronics on flexible substrates for applications such as flexible displays and RFID tags. In particular, inkjet printing is a popular technique to pattern organic electronic devices because patterns can be changed dynamically. Despite of its widespread use, non-idealities are commonly observed and only partially solved. Here, we demonstrate a solution to the problem of bulging lines.
After ink has been ejected from the nozzle and deposited on the substrate, ink can flow distorting the pattern. This is mainly caused by surface tension forces and the associated Laplace pressure. Traditionally, lines are printed by linearly placing drops one behind the other. By varying the drop spacing, four different regimes are observed: outward bulging of lines, scalloping, line separation and smooth lines. Unfortunately, this approach only achieves smooth lines under certain conditions and generally not at the start of a line. When a new line is started, drops form bulges that are rounded and less line-shaped to minimize surface energy. This starting bulge grows as drops are added to the end of the line due to an imbalance of pressure within the liquid line. Ink flows from a region of high pressure to a region of low pressure (the bulge). Starting bulges can be observed not only in isolated lines but also X-, T-, and L-shapes when a new segment is started e.g. in interdigitated or serpentine patterns. This reduces yield of devices such as printed transistors or requires large margins of safety.
Here, we demonstrate that by manipulating the order of drops printed, we can avoid bulges at the beginning of inkjet-printed lines. The premise of this approach is to maintain symmetry and a net force of zero on every drop added to the line. By canceling out the high pressure at either end of the line, we have removed the pressure imbalance that leads to line bulging. This is achieved by always connecting equidistant line segments or drops of equal length/volume. The basic building blocks are segments of three drops where the middle drop is printed last. We show that these segments do not become rounded unlike three-drop segments that are printed linearly, which causes bulging. Segments are successively connected without allowing pressure imbalances to form. Crucial parameters are the drop spacing within segments as well as the spacing between segments. We show how the contact angle of the ink on the substrate affects these parameters. Finally, smooth lines can be printed with this novel method. This symmetric approach can be extended to more complex two-dimensional patterns by recursively breaking them down into segments of equal length that are connected in a binary fashion.
In summary, we present a novel approach to the inkjet printing of scaled features that can be employed in printed devices. We successfully avoid undesirable line morphologies by ensuring that the pressure within lines is always balanced.
11:30 AM - MA02.06.09
Stretchable Organic Artificial Synapse for Wireless Communication and Biomimetic Motor System
Yeongjun Lee1,2,3,Jin Young Oh2,Wentao Xu2,3,Onnuri Kim1,Taeho Kim2,Jiheong Kang2,Yeongin Kim2,Donghee Son2,Jeffrey Tok2,Moon Jeong Park1,Zhenan Bao2,Tae-Woo Lee3
POSTECH1,Stanford University2,Seoul National University3
Show AbstractArtificial synapses are rapidly emerging for neuro-inspired electronic devices that emulate biological synapses. Mimicking biological synaptic memory functions of the brain has been a main focus in neuromorphic electronics, but mimicking the complicated human sensorimotor system that performs sequential functions related to proprioception, signal processing, and motor response is also a challenging issue especially to realize bio-mimetic soft electronics. Here, we design a photo-sensory stretchable artificial synapse that implements wireless recognition, telecommunication and muscle actuation in the similar way of biological system. The stretchable artificial synapse which incorporates a single wavy organic nanowire stably operates at 100% strain and after repeated stretching cycles; this mechanical stability is favorable for soft electronics. Our stretchable artificial synapse generated typical postsynaptic behaviors in response to presynaptic photo-stimulation and showed promising features for wireless communication as well as robust operation of biomimetic motor system of soft electronics. Our stretchable artificial synapse will provide an advance toward developing bio-inspired soft electronics, neurorobotics and electronic prostheses.
11:45 AM - MA02.06.10
Human Hair Keratin for Biocompatible Flexible and Transient Electronic Devices
Wei Lin Leong1,Jieun Ko1,Thi Hien Luong Nguyen1,Abhijith Surendran1,Bee Yi Tan1,Kee Woei Ng1
Nanyang Technological University1
Show AbstractBiomaterials have been attracting attention as a useful building block for biocompatible and bioresorbable electronics due to its non-toxic property and solution processabillity. In this work, we report the integration of biocompatible keratin from human hair as dielectric layer for organic thin-film transistors (TFTs), with high performance, flexibility and transient property. The keratin dielectric layer exhibited a high capacitance value above 1.27 µF/cm2 at 20 Hz due to the formation of electrical double layer. Fully solution processable TFTs based on p-channel poly[4-(4,4-dihexadecyl-4H-cyclopenta[1,2-b:5,4-b]dithiophen-2-yl)- alt[1,2,5]thiadiazolo[3,4-c]-pyridine] (PCDTPT) and keratin dielectric exhibited high electrical property with a saturation field-effect mobility of 0.35 cm2 V-1 s-1 at a low gate bias of -2 V. We also successfully demonstrate flexible TFTs which exhibited good mechanical flexibility and electrical stability under bending strain. An artificial electronic synaptic PCDTPT/Keratin transistor was also realized and exhibited high-performance synaptic memory effects via simple operation of proton conduction in keratin. An added functionality of using keratin as a substrate was also presented, where similar PCDTPT TFTs with keratin dielectric were built on top of keratin substrate. Finally, we observed that our prepared devices can be degraded in ammonium hydroxide solution, establishing the feasibility of keratin layer as various components of transient electrical devices including as a substrate and dielectric layer.
MA02.07: Device Physics
Session Chairs
Thursday PM, April 05, 2018
PCC West, 100 Level, Room 102 BC
1:30 PM - MA02.07.01
Fabrication and Integration of Organic Electronics in Smart Sensor Tags
Robert Street1
Palo Alto Research Ctr1
Show AbstractFlexible smart sensing tags that combine sensing elements, electronic control circuits and usually silicon ICs in a flexible hybrid device are an important area of organic electronics research and development. Printing technology is a good fit for the fabrication of these devices because the device density and circuit speed are low, the materials are flexible and the need for several different materials favors additive manufacture. Organic TFTs provide the control logic and have been widely studied for many years. Complementary TFT circuits are preferred for most circuits and while OTFTs have improved greatly there is still a challenge to make printed complementary devices with the same structure and matched characteristics. Circuit design that mitigates device variability is needed. Organic electronic materials also provide many of the sensors, memory and actuator devices that provide functionality to a smart sensor tag. Organic electro-chemical TFTs (OECT) are important devices for high current circuits and as chemical and physiological sensors, and they provide novel electronic attributes that give dynamic circuit elements. Humidity sensors use the property that organic materials are permeable to moisture and hence change the device capacitance. The piezo- and ferro-electric polymer PVDF is used for memory devices and actuators. Examples will be given for each of these organic electronic technologies and their integration in prototype smart tags.
2:00 PM - MA02.07.02
Organic Thin-Film Transistors with Charge Carrier Mobilities of 20 cm2/Vs, Independent of the Gate Voltage
Zachary Lamport1,Katrina Barth1,Iain McCulloch2,3,John Anthony4,Oana Jurchescu1
Wake Forest University1,Imperial College London2,King Abdullah University of Science and Technology3,University of Kentucky4
Show AbstractThe performance of organic thin-film transistors (OTFTs) depends on a variety of factors including the type of semiconductor and processing conditions, the dielectric, the device structure, and the choice of electrodes. In particular, the quality of the source and drain contacts is of the utmost importance to facilitate efficient charge injection and minimize contact resistance. Here, we focus on the study of contact effects in OTFTs and their relation to processing conditions. We fabricate bottom-contact, top-gate OTFTs with pentafluorobenzenethiol (PFBT)-treated Au/Ti contacts, the organic semiconductor 2,8-difluoro-5,11-bis (triethylsilylethynyl) anthradithiophene (diF-TES ADT) and Cytop gate dielectric. We deposit the source and drain electrodes using thermal evaporation and vary the deposition rate from 0.1 Å/s to 2 Å/s, while maintaining the geometry of the device unmodified. We find that the field-effect mobility is dependent on the details of the electrode fabrication, with a maximum value being obtained for a rate of 0.5 Å/s, µmax = 19 cm2/Vs, and gradually decreasing to a value of µ = 8 cm2/Vs, at a rate of 0.1 Å/s, and µ = 4 cm2/Vs at 2 Å/s, a value that is consistent with earlier reports obtained under similar conditions.1 By examining the dependence of mobility on gate-source voltage, we observe an abrupt increase, followed by a plateau at the reported values, confirming that the reported mobility values are not simply an artefact of the measurement due to gated contacts. We evaluate the contact resistance through gated-TLM measurements, and find that it follows the same trend as the mobility vs. deposition rate, with the lowest value aggressively lowered to 0.5 kΩcm for 0.5 Å/s deposition rate. We discuss the factors that contribute to lowering of the contact resistance, which, in turn, gives improved device characteristics.
To determine if this drastic improvement in electrical characteristics through modifying the electrode processing is material-dependent, we further performed a similar study using another well-known semiconductor, in this case the copolymer indacenodithiophene-co-benzothiadiazole (IDTBT). Using the same device structure, we find a maximum mobility of 12 cm2/Vs at a deposition rate of 0.5 Å/s, which is approximately 4 times greater than the highest value reported in the literature for this material,2 and results from a low contact resistance of 0.2 kΩcm. The vastly improved performance exhibited by these devices indicate that the deposition rate of source and drain electrodes is a salient parameter that must be accounted for in device design and is effective for both small-molecule and polymer semiconductors.
1 P. J. Diemer, et al., Appl. Phys. Lett., 2015, 107, 103303.
2 X. Zhang, et al., Nat. Commun., 2013, 4, 1–9.
2:15 PM - MA02.07.03
Threshold-Voltage Controls in Organic Transistors by the Gate Electrode Modification
Takafumi Uemura1,Keisuke Sakaguchi1,2,Masaya Kondo1,2,3,Teppei Araki1,2,Shusuke Yoshimoto1,Noda Yuki1,Tsuyoshi Sekitani1,2
Institute of Scientific and Industrial Research, Osaka University1,Osaka University2,Advanced Photonics and Biosensing Open Innovation Laboratory, National Institute of Advanced Industrial Science and Technology (AIST), Suita, Osaka, Japan3
Show AbstractIn this study, we have realized threshold-voltage (Vth) controls by the selection of gate metals or the gate electrode modification with self-assembled monolayers (SAM) in organic transistors. The difference of work function between the gate metal and the organic semiconductor intrinsically varies the Vth. In other words, transistors with desired Vth can be fabricated by the modification of the gate electrodes. Using the gate modification, enhance-mode and depletion-like transistors have been realized for Al gate electrodes and SAM-treated Au gate electrodes, respectively. As a result, the Vth can be shifted for 0.95 V in 2-V-operating organic transistors, which is useful for designing organic logic circuits.
Recently, organic thin-film transistors (OTFTs) have attracted attention because of their low costs and simple processability. The technology of OTFTs is desired to be used for sensor applications in the IoT society, where the signal addressing and processing circuits are important. In such analog circuits, both low-voltage operation and highly-reliable electric characteristics are essential. Therefore, the precision and reproducible control of Vth is one of key technologies for organic analog circuits. It has been already shown by several groups that Vth can be shifted by modifying the surface of gate dielectrics with SAM or plasma treatment1,2. Although these methods can shift Vth largely, it has been realized only on the specific inorganic dielectrics, such as silicon dioxide or aluminum oxide. Another approach for the Vth control is the modification of gate metals. This is a universal method to shift the Vth because large variety of gate metals and dielectrics are applicable.
In this study, we fabricated OTFTs with modified gate electrodes, where the metal surface is treated with polarized SAM so that the work function of the metal is changed. Various kinds of gate metals and SAM modifications are investigated in bottom-gate and top-contact transistors. A thin parylene, DNTT and Au top-contact electrodes were used for the other components in the OTFTs. As a result, we realized enhance-mode OTFTs with Vth = - 1.05V for Al gate electrodes. On the other hand, we realized depletion-like OTFTs with SAM treated Ag or Au gate electrodes. We found that SAM treatment with pentachlorobenzenthiol changes the Vth for up to 140 mV. It should be noted that only the Vth can be shifted without changing the other parameters such as mobility. These Vth control technology is useful for designing organic circuits, and we will demonstrate improved circuits designs for some analog circuits such as inverters and Pseudo CMOS technologies.
1. S. Kobayashi, et al. Nature Mater. 3, 317-322 (2004)
2. A. Kitani, et al. J. Appl. Phys. 55, 03DC03 (2016)
3:30 PM - MA02.07.04
How Big is a Polaron in Conjugated Polymers?
Alberto Salleo1
Stanford University1
Show AbstractTypically semicrystalline conjugated polymers exhibit much higher mobility than their amorphous counterpart. The archetypal example is regio-random P3HT, with mobilities on the order of 10-6cm2/V.s as compared to regio-regular P3HT with mobilities on the order of 0.1 cm2/V.s. The oft-cited reason for these differences is the fact that in polymer crystallites charges delocalize and take a partial 2D character, enabling higher mobility. The amount of delocalization and how it depends on structure and processing is however difficult to measure. I will show that charge modulation spectroscopy in the IR with model materials allows to determine the delocalization of the polaron in P3HT, when aided by theory. In order to extract systematic trends we will use 100% regio-regular P3HT of well-defined molecular weights (PDI~1.1). I will show how delocalization depends on molecular weight and substrate interface. Furthermore, I will compare the delocalization of charge induced by field-effect with that of charges induced by doping. We find that doping strongly suppresses delocalization, which may explain why only 5% of doping-induced charges are actually mobile.
4:00 PM - MA02.07.05
Phonons in Organic Semiconductors and Flexible Mechano-Electronics
Junto Tsurumi1,Jun Takeya1,Shun Watanabe1,Toshi Okamoto1,Takaya Kubo1,Akifumi Yamamura1
Univ of Tokyo1
Show AbstractSmall molecular organic semiconductor crystals form interesting electronic systems of periodically arranged “charge clouds” whose mutual electronic coupling establishes charge and spin coherence overcoming molecular fluctuation. This presentation focuses on dynamic properties of the coherent electrons in high-mobility organic single-crystal semiconductors with systematically modified phonon scattering, which strongly restricts mobility of charge carriers in single-crystal organic transistors [1,2].
We grew only a-few-monolayer thick ultra-thin single-crystal films of decyldinaphthobenzo-dithiophene derivatives (Cn-DNBDT) on a plastic substrate so that uniaxial force can be applied by bending the samples. It is crucial to use such ultrathin crystal films to reproducibly apply strain because the surface of the plastic substrates and the semiconductor films are to be deformed in the same rate without either slippage or mechanical break. We examined the reproducible modification in crystalline structure and inter-molecular phonon vibration as the function of applied strain. At maximum, 3% strain is applied without damage to the crystal so that room-temperature mobility increased by the factor of 1.7 [2]. The measured mobility is 9.7 cm2/Vs without strain, and it significantly increases up to 16.5 cm2/Vs under 3% strain. Analysis using X-ray diffraction (XRD) measurements and density functional theory (DFT) calculations reveal the origin to be the suppression of the thermal fluctuation of the molecules rather than reduction of effective mass, which is consistent with temperature dependent measurements.
We measured spin relaxation time of the electric-field induced carriers down to 4.2 K using the large-area ultra-thin single-crystal transistors to measure electron-spin relaxiation. We found that the spin-relaxation follows the Elliott-Yafet mechanism so that the spin life time is consistently elongated at low temperatures due to reduced phonon scattering via spin-orbit coupling [3]. The result suggest that charge carrier mobility can as high as 650 cm2/Vs with minimized phonon scattering at the low temperature.
The giant strain effect and very large impact of phonon scattering in room-temperature charge transport are caused by peculiar electron-phonon coupling in the soft molecular semiconductors, which promises high-performance mechano-electronics devices such as strain sensors and vibration sensors.
[1] K. Sakai, Y. Okada, T. Uemura, J. Tsurumi, R. Häusermann, H. Matsui, T. Fukami, H. Ishii, N. Kobayashi, K. Hirose, and J. Takeya, Nature Asia Mater. 8, e252, (2016).
[2] T. Kubo, R. Häusermann, J. Tsurumi, J. Soeda, Y. Okada, Y. Yamashita, N. Akamatsu, A. Shishido, C. Mitsui, T. Okamoto, S. Yanagisawa, H. Matsui, and J. Takeya, Nature Commun. 7,11156 (2016).
[3] J. Tsurumi, H. Matsui, T. Kubo, R. Häusermann, C. Mitsui, T. Okamoto, S. Watanabe, and J. Takeya, Nature Phys. 13, 994 (2017).
4:30 PM - MA02.07.06
Controlling Domain Purity in Solution-Processed Organic Solar Cells
Chris McNeill1,Wenchao Huang1,Eliot Gann2,Naresh Chandrasekaran1,3,4,Lars Thomsen5,Shyamal Prasad6,Justin Hodgkiss6,Dinesh Kabra4,Yibing Cheng1
Monash University1,National Institute of Standards and Technology2,IITB-Monash Research Academy3,Indian Institute of Technology Bombay4,Australian Synchrotron5,Victoria University of Wellington6
Show AbstractIn solution-processed organic bulk heterojunction (BHJ) solar cells, the purity of the phase-separated domains is known to play an important role in determining device function. While the effects of domain purity have been investigated by tuning of the BHJ morphology, such tuning typically results in several parameters (for example domain size and crystallinity) being varied at once. Here we show that by varying the time between spin-coating and the application of an anti-solvent treatment, the domain purity of the polymer-rich phase in PBDTTT-EFT:PC71BM blends can be tuned while keeping other morphological parameters constant. This unique approach enables the effect of domain purity on device function to be isolated and quantified. Over the purity range explored, solar cell power conversion efficiency is observed to monotonically increase from 7.2% to 9.6% corresponding to a ~ 20% increase in domain purity. The cell fill factor is found to be most affected by changes in domain purity, with transient photovoltage measurements indicating a reduction in the rate constant of bimolecular recombination with increasing domain purity.
4:45 PM - MA02.07.07
Polymorphism Controls the Degree of Charge Ttransfer in a Molecularly Doped Semiconducting Polymer
Ian Jacobs1,2,Camila Cendra Guinassi3,Thomas Harrelson1,Zaira Bedolla-Valdez1,Roland Faller1,Alberto Salleo3,Adam Moule1
University of California, Davis1,University of Cambridge2,Stanford University3
Show AbstractThe molecular doping of organic semiconductors (OSCs) has recently gained significant interest due to applications in thermoelectrics, transistors, and for selective contacts in photovoltaics or LEDs (see review by Jacobs and Moule, Adv. Mater. 2017, 1703063). Taking the p-type case as an example, molecular doping is usually assumed to occur by single electron transfer from the OSC to the dopant molecule, generating an ion pair (IP). However, over the past 5 years it has become apparent that some materials—primarily small molecule OSCs—dope by a qualitatively different process. In these systems, significant orbital hybridization occurs between the dopant and organic semiconductor, generating a charge transfer complex (CTC) which accepts both electrons from the OSC highest occupied molecular orbital (HOMO). These CTCs must thermally dissociate to generate free charge carriers, and therefore are generally seen as detrimental to efficient doping. Unfortunately, at present we do not have a clear picture of what factors control the formation of CTCs. This lack of understanding is due in large part to the fact that all currently known OSC:dopant systems appear to exclusively dope by either CTC or IP formation.
Here, we present the first system which selectively exhibits both IP or CTC formation. By varying the film casting conditions in the well-studied poly(3-hexylthiophene) : 2,3,5,6-tetrafluoro-7,7’,8,8’-tetracyanoquinodimethane (P3HT:F4TCNQ) system, we observe films with qualitatively different UV-vis-NIR absorption spectra than previously reported. These spectra are consistent with CTC formation, as are FT-IR spectra, which indicate fractional charge transfer. Solvent exposure converts these films back to the normally observed IP phase. Grazing incidence XRD studies indicate the CTC phase is crystalline, and remarkably displays an even higher degree of order than undoped P3HT processed under similar conditions. Therefore, disorder-induced charge localization cannot explain the formation of CTCs. DFT studies further support our conclusion that polymorphism directly controls the degree of charge transfer, and therefore the doping mechanism.
MA02.08: Poster Session II: Organic Electronics—Processing, Microstructure and Multifunctioning II
Session Chairs
Thursday PM, April 05, 2018
PCC North, 300 Level, Exhibit Hall C-E
5:00 PM - MA02.08.01
Urushiol Gate Dielectrics for Low-Voltage and Hysteresis-Free Organic Field-Effect Transistors—Hidden Potential of Natural Polymers
Yonghwa Baek1,Chan Eon Park1
Pohang University of Science and Technology1
Show AbstractNatural polymer materials often have inimitable properties that are superior to those of artificial products. In this research, we discuss earth-abundant and eco-friendly gate dielectric materials for organic field-effect transistors (OFETs).
“Urushi” (oriental lacquer) is a time-honored natural resin that has been applied as a coating for wood, metals, and various materials. The main component of urushi, urushiol, is a catechol derivative with a long unsaturated hydrocarbon side chain. Urushiol films require two curing steps. The first step involves oxidation of the catechol moieties in urushiol to form oligomers. The second step involves the aerobic oxidative polymerization of the double bond in the side chain to form a highly cross-linked structure. Although the reaction takes a long period of time (several hours and even days), heating can accelerate the reaction, and urushiol can be rapidly cured at low temperatures over short periods of time. Urushiol films can retain excellent chemical resistivity more than 1000 years via thermal curing process.
A plethora of studies have focused on the development of practical coatings and mimicking structures to produce functional materials. Urushiol’s utility in a broader set of applications should be explored. Polymer materials used as gate dielectrics in OFETs typically form cross-linked structures that improve their chemical resistance and dielectric properties.
Considering these factors, the formation of a high-density cross-linked network in urushiol derived from hydroxyl groups, the abundance of unsaturated double bonds makes it an attractive gate dielectric material. Urushiol films were fabricated via a facile thermal curing process (100°C, 30 min) and gave a smooth surface (Rq ∼ 0.3 nm) with a hydrophobic nature (44.6 mJ/m2). The leakage current density values remained stable at operation voltages (5 × 10-8 A/cm2 up to –3 V). Pentacene OFETs with thin (85 nm) urushiol gate dielectrics exhibited good transfer and output characteristics with a mobility of 0.07 cm2/Vs and negligible hysteresis under only +2 ∼ –3 V. An outstanding gate bias stability over 140 minutes under humid conditions (R.H. 80%) was achieved in the same devices. These outstanding electrical performance and stability properties were attributed to the densely packed structures of the urushiol films prepared via thermal curing. This research enables a plethora of opportunities in the field of gate dielectric materials and electronics as well as in the area of earth-abundant materials and eco-friendly products.
5:00 PM - MA02.08.02
A Solution-Processable and Heating-Free Organic N-Type Dopant for Graphene and Organic Semiconductor-Based Transistors
Yong Hee Kim1,Eun Kwang Lee1,Joon Hak Oh1
Pohang University of Science and Technology1
Show AbstractThe development of a simple fabrication method for solution-based organic n-type dopant is of great importance for realizing low-cost complementary organic electronic devices. In addition, a heating-free doping process for organic electronic devices is highly promising for use in flexible electronics compatible with plastic substrates. In this study, we have developed a simple fabrication method of a high-performance n-type organic dopant using an organic cationic dye and a reducing agent. After coating the dopant solution on targeted materials, the organic non-polar solvents are removed by treating the vacuum at 1 × 10-3 torr without any annealing steps. The work function of graphene is changed from 4.5 eV to 3.98 eV after solution doping at room-temperature. The multiple coating of rPyB on graphene field-effect transistors (GFETs) results in long-term air-stability, revealing that the electron mobility is maintained for 90 days in ambient condition. Also, by using graphene electrodes doped with the organic dopant, the electronic performance of n-type organic filed-effect transistors (OFETs) can be improved because of well-balanced energy levels between the electrodes and the semiconducting layer. We also demonstrate a highly efficient selective stamping method for n-type molecular doping of a large-area 16 × 16 GFET array using a polydimethylsiloxane (PDMS) stamp and the reduced cationic dye. Our findings demonstrate an important methodology for the cost-effective synthesis of n-type dopants and their versatile use for the modulation of electronic performance in graphene and organic electronics.
5:00 PM - MA02.08.03
Coexistence of Ultra-Long Spin Relaxation Time and Band-Like Charge Transport in Organic Single-Crystalline Semiconductors
Junto Tsurumi1,Takaya Kubo1,Toshi Okamoto1,Shun Watanabe1,2,Jun Takeya1
University of Tokyo1,JST2
Show AbstractOrganic semiconductors (OSCs) attracts great interest for the next generation electronics and spintronics applications. Recently, a new class of single-crystal OSCs with a mobility exceeding 10 cm2V-1s-1 has been developed, in which a band-like charge transport is realized thanks to its highly periodic electrostatic potential despite the weak van der Waals coupling. Additionally, OCSs are the candidate materials for the spin media due to their long spin relaxation time, typically 10-7—10-6 s, which is several orders longer than that of inorganic materials due to weak spin-orbit interaction. However, spin transport and relaxation mechanism of the single-crystal OCSs are not extensively investigated because of the technical difficulties of the spin detection.
Here, in our report [1], we applied operando-ESR technique to high-mobility single-crystal OCSs, and addressed the charge and spin relaxation mechanisms. Operando-ESR of single-crystal organic field effect transistor (OFET) allows to measure intrinsic spin dynamics of the gate-induced carriers. To address intrinsic charge momentum and spin relaxation mechanisms, a single crystal of our benchmarked OSC, C10–DNBDT–NW [2], was grown directly on a substrate via the continuous edge-casting method that has been developed by our group. This method produces an ideal single crystal with over an inch in size, which allows to observe ESR signal with the good signal-to-noise ratio. For the precise evaluation of momentum relaxation time τp, firstly, the band-like transport is evidenced by the observation of Hall effect and the negative temperature (T) dependence of mobility. The measured mobility, and thus τp, clearly increases as T decreases, where the temperature dependence of mobility can be fitted with T-0.85. Spin-lattice relaxation time T1 and spin-spin relaxation time T2 were estimated by operando-ESR. T1, T2, and τpT-2 respect to temperature agree perfectly with T-2.85; that is, they satisfy the relationships predicted from Elliott-Yafet mechanism. This leads to the conclusion that the EY mechanism is dominant in OSCs. The EY mechanism describes the spin conserving/flipping probability at an ordinary scattering event with the presence of SOC.
The demonstrated operando-ESR measurement would be useful to fully understand the charge and spin transport in OSCs under low-temperature regimes. On the basis of the verified EY mechanism, T1 ∝τpT-2 holds even at low-temperature regimes, and the intrinsic drift mobility free from any traps and defects may reach 650 cm2V-1s-1 at 4 K. In addition, the spin diffusion length is estimated to be 840 nm at 300 K, and is likely to approach 1.6 μm at 50 K. The extraordinarily long spin diffusion length is expected due to the coexistence of ultra-long spin coherence times and relatively high band-like mobility.
[1] J. Tsurumi et al., Nature Phys. 13, 994 (2017). [2] C. Mitsui et al. Adv. Mater. 26, 4546 (2014).
5:00 PM - MA02.08.04
Band-Like Transport in Two-Dimensional Monolayer Organic Field-Effect Transistors
Akifumi Yamamura1,Hiromasa Fujii2,Balthasar Bluelle1,Hirohito Ogasawara3,Dennis Nordlund3,Toshihiro Okamoto1,4,Yusuke Wakabayashi2,Shun Watanabe1,4,Jun Takeya1
The University of Tokyo1,Osaka University2,SLAC National Accelerator Laboratory3,PRESTO, JST4
Show AbstractTwo-dimensional ultrathin organic single crystals are an ideal platform for printable, wearable electronic device applications because of their high carrier mobility above 10 cm2/Vs and the minimized resistance of accessing the charge-accumulated channel. However, monolayer (1L) organic field-effect transistors (OFETs) often show much poorer electronic properties than those in bilayer (2L) OFETs.[1,2] In this presentation, we focus on the origin of the electronic performance degradation in 1L-OFETs and propose a new approach to overcome drawbacks.
1L and 2L single crystals of 3,11-dioctyldinaphtho[2,3-d:2’,3’-d’]benzo [1,2-b:4,5-b’]dithiophene (C8–DNBDT–NW) were grown by meniscus-guided solution process.[3] In order to address the origin of serious mobility degradation in the 1L crystals, we investigated differences in microstructure of 1L and 2L single crystals using X-ray reflectivity (XRR) measurements. Although the slight distortion in electron density is seen particularly at the edge of the substrate, it is found that such a small deviation does not explain drastic degradation of the carrier transport. Accordingly, we assume that the process to form contact electrodes may give a crucial impact on the molecular orientation of 1L crystals. To confirm the hypothesis, we compare the differences in molecular orientation before and after gold evaporation on the film using Near-edge X-ray absorption fine spectroscopy. In the pristine 1L crystals, intensity of the peaks corresponding to the transition from C1s core to π* orbitals dramatically increases as the X-ray incident angle approaches to the normal direction of the substrate plane. This significant angular dependence of the peak intensity shows that the C8–DNBDT–NW in the pristine 1L crystals are highly ordered in an up-right geometry. However, the angular dependence of the π* peaks are apparently depressed in the 1L crystals after gold evaporation, which supports that thermal/radiation damage can have a significant impact to 1L crystals.
In order to evaluate the intrinsic properties of 1L-OFETs free from any damages caused by evaporation, we adapt a lamination contact process, where polydimethylsiloxane (PDMS) film with contact electrodes is laminated on the 1L crystal. The 1L-OFET with the laminated electrodes shows the excellent performance with the mobility of 10 cm2/Vs. In addition, Hall effect measurements were performed on the 1L-OFET, where the Hall carrier density is in a perfect agreement with the carrier concentration estimated from gating. The result shows the coherent band-like transport is realized in the 1L crystal.
[1] Q. Wang et al., Adv. Funct. Mater. 2016, 26, 3191.
[2] A. Yamamura et al., under reviewing.
[3] J. Soeda et al., Appl. Phys. Express 2013, 6, 076503.
5:00 PM - MA02.08.06
Electrical and Optical Properties of Highly Crystalline TPBi Thin Films
Jordan Dull1,Barry Rand1,Michael Fusella1
Princeton University1
Show AbstractOrganic semiconductors, and in particular organic LEDs (OLEDs), have found commercial outlets in the cell phone and television display markets, even though their full potential has not yet been realized. Current technology uses disordered films even though organic materials, like rubrene, have been shown to crystallize over large areas [1]. Furthermore, it has been demonstrated that when these materials crystallize both the charge mobility and diffusion length significantly improve [2,3]. One reason silicon and III-V semiconductors perform so well in modern device applications is because enormous amounts of time and effort were put into making highly crystalline wafers with very few structural and chemical impurities. This history of inorganic semiconductors and the fact that organic materials can crystallize indicate that understanding and controlling how organic materials form ordered films is crucial for improving the performance of organic electronic devices. However, there exists major gaps in understanding of how these crystals form and grow, how defects impact electrical and optical properties, and how interfaces between crystalline layers effect device physics. Yet other than rubrene, there are no known materials that are able to form large area crystalline films. We therefore attempt to search for and understand how other organic semiconductors make long-range-ordered films.
One such material we have found to crystallize is 2,2’,2”-(1,3,5-benzinetriyl)-tris(1-phenyl-1-H-benzimidazole) (TPBi) which is an electron transport layer commonly used in OLEDs. Here we show that a thermal annealing process on thin films (20 nm) of TPBi results in large crystalline domains (~2-4 mm). We will discuss our efforts to control nucleation density, and thus crystalline domain size, as well as peculiarities (voids and wavelike features) that form on the TPBi crystal surface upon longer annealing times. Additionally, we will present optical, structural, and electrical measurements, highlighting the differences between amorphous and crystalline thin films.
References:
[1] M.A. Fusella, et al. Chem. Mater., 29 (16), 6666–6673 (2017)
[2] I.G. Lezama, A.F. Morpurgo, MRS Bull. 38, 51-56 (2013).
[3] H. Najafov, B. Lee, Q. Zhou, L.C. Feldman, V. Podzorov. Nature Mater. 9, 938-943 (2010).
5:00 PM - MA02.08.07
Improved Performance of Inverted Polymer Solar Cells Using Wrinkle and Flat Structures of ZnO Formed by Low-Temperature Static Annealing
Hassan Hafeez1,Chang Min Lee1,Seung Yoon Ryu1
Korea University1
Show AbstractA considerable attention has been drawn to improve the performance of inverted polymer solar cells (IPSCs) by intensive study of various electron transport layers such as TiOx, ZnS and Cs2CO3. Among all, zinc oxide (ZnO) is the most promising candidate due to its high transparency, good environmental stability, low conduction band and improved electron mobility. In reported studies, ZnO layers with different morphologies have been fabricated using high temperature dynamic annealing (DA) process, which significantly damages the polymer device and reduces the device efficiency and stability.
In this work, we report the fabrication of amorphous ZnO wrinkle (wavy) and flat (crystal-like) structures using low temperature static annealing (SA) sol-gel method and demonstrate the effect of these morphologies on the IPSC performance. A variable ramping/heating rate provided by SA process induced a variable solvent evaporation and transformation rate in comparison to constant ramping rate by DA. The quick initial solvent evaporation followed by a slow heating in SA, induced tensile stresses in the layer and formed wrinkle structures at much lower temperature of ~150 °C. Flat structures were fabricated at 200 °C annealing temperature with a slightly higher heating rate, which enabled a faster transformation of layer in to crystal-like structures instead of wrinkle structures. The device performance analysis demonstrated that a better short circuit current (Jsc) was obtained by utilizing wrinkle structures due to light scattering and trapping which was in accordance with the weaker transmission efficiency analyzed by this layer. Interestingly, devices with flat ZnO layer demonstrated a remarkable improvement in the fill factor (FF), power conversion efficiency (PCE = 6.33%) and lower leakage current in comparison to devices with wrinkle ZnO morphology. The ZnO layer with flat structures had better packing density and less surface defects due to absence of undissolved solvent which consequently improved the hole blocking and charge transport properties thus enhancing device efficiency.
The work demonstrates that distinctive solvent evaporation dynamics and transformation rates provided by only SA process can enable us to fabricate wrinkle and crystal-like structures of ZnO at much lower annealing temperatures than presented by DA process. Better charge transport properties and improved IPSC device efficiency indicates that this technique has a high potential to be utilized in flexible and polymer electronics, especially where low-temperature processing is necessary.
5:00 PM - MA02.08.08
Realization of Recombination Zone Movement in Green Phosphorescent OLEDs Through Interface Excitons
Justin Jesuraj Periyanayagam1,TaeKyoung Kim1,Seung Yoon Ryu1
Korea University1
Show AbstractIn general, the internal quantum efficiency, external quantum efficiency (or out coupling ability) and charge balance in emissive layer are the essential parameters in determining a phosphorescent organic light emitting diodes (PhOLED) efficiency. Significantly, the charge balance and the resulting recombination zone (RZ) position in PhOLED is mainly determined by the transport layers and device architecture.
In this scenario, we have controlled and monitored the RZ movement in green PhOLED without employing any sensing layers. Green PhOLED consisting of ITO[tin doped indium oxide] / PEDOT:PSS[Poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate)] / NPB[N,N-bis-(1-naphthyl)-N,N'-diphenyl-1,1'-biphenyl-4,4'diamine] / TCTA[Tris(4-carbazoyl-9-ylphenyl)amine] / EML (CBP:Ir(ppy)3) [4,4′-Bis(N-carbazolyl)-1,1′-biphenyl:Tris[2-phenylpyridinato-C2,N]iridium(III)]]) / TPBi [2,2′,2"-(1,3,5-Benzinetriyl)-tris(1-phenyl-1-H-benzimidazole)] / LiF/Al have been fabricated with various thickness of EML. Significantly, at low EML thickness (10 nm), RZ moves towards TCTA/EML interface due to the higher mobility and reduced path way of electrons. The suspected RZ movement in PhOLED revealed in electroluminescence (EL) spectra by a tiny emission around 450 nm. While, increasing the thickness of EML, RZ moves towards cathode direction that encountered with the absence of TCTA emission and corresponding red shift observed in electroluminescence (EL) spectra. PhOLED with enhanced current and quantum efficiencies (50 cd/A and 14.4% respectively) is extracted with 15 nm thick EML devices. To further improve the device efficiency quantum well (QW) structure consisting of EML (7.5 nm)/TCTA (5 nm)/EML (7.5 nm) infused in PhOLED architecture as EML that yielding a 52 cd/A and 14.6% current and quantum efficiencies at 1000 cd/m2.
To clearly depict the RZ movement tactics, we have recorded the Time resolved area normalized emission spectra (TRANES) and solid state photoluminescence (SSPL) for multi layers films namely ITO/NPB, ITO/TCTA, ITO/TCTA/EML (10 nm) and ITO/TCTA/QW. TRANES of 10 nm EML sample clearly show an interesting energy transfer from TCTA to Ir(ppy)3 indicating a charge recombination process at TCTA/CBP:Ir(ppy)3 interface. In addition, pure TCTA films exhibit certain excimer emission upon excitation and is responsible for generating a blue peak in EL. Interestingly, the EL of PhOLED with 10 nm EML found to blue shifted as compared its corresponding photo luminescence profile. Hence, it is confirmed that the movement of RZ towards TCTA/EML, inducing an exciplex generation between Ir(ppy)3 and the TCTA excimers which contributing the blue shift in EL. On the other hand, TRANES of QW based multi layers indicating a relative quick energy transfer from TCTA to EML. Hence, the RZ movement in green PhOLED is clearly monitored without any sensing layer by varying the EML thickness and QW infusion.
5:00 PM - MA02.08.09
Organic-Inorganic Heterojunctions Toward High Performance Field Effect Transistor Applications
Chao Jiang1,Molin Li1,Jiawei Wang1
National Ctr for Nanoscience1
Show AbstractA hybrid structure of organic-inorganic heterojuctions has been highly expected to realize more flexible design of functional devices in opto-electronics and electronics for ubiquitous applications in reality. Especially, with tremendous increasing of novel materials, the divers device applications are coming true. Here, we present several examples of organic-inorganic heterojunctions to illustrate the possible strategy for device design in phototransistors and ambipolar transistors.
Organic/Perovskite hybrid thin film transistor photodetectors consist of C8BTBT molecular film and CH3NH3PbI3 film prepared by two-step vacuum deposition. By implementing perovskite CH3NH3PbI3 film onto the organic active layer, the organic/perovskite hybrid photodetector exhibited a photoresponsivity of 33 A/W and fast response time and well gate tunable ability. Improvement of photodetection performance is attributed to the balance between light absorption in perovskite layer and an effective transfer of photogenerated carriers entering from perovskite into organic C8BTBT channel.
Secondly, as showing large potentials for applications in integrated logic circuits with low power dissipation, wide noise margins, and higher robustness, ambipolar transistors have attracted widely attentions in recent. Here, we utilize IGZO and organic semiconducting molecular materials—DNTT/C8BTBT, to fabricated ambipolar transistors. The transistors show much balance mobilities for n- and p-type channels, in addition, ideal reliability was observed in the prolonged bias stress test. Converters based on above were also built up, which showed promising behaviors with gain value as extremely high as 100. The organic-inorganic hybrid heterostructures may open up a path way for the flexible design of functional devices and its integrations.
5:00 PM - MA02.08.10
Wavy Buckled Organic Light-Emitting Diodes with Multiaxial High Strain Ratio Stretch and Compression
Dong Hyun Kim1,Hyung Ju Chae1,Hassan Hafeez1,Seung Yoon Ryu1
Korea University1
Show AbstractWith recent developments in the field of wearable and biomedical electronics, fabrication of stretchable organic light-emitting diodes (SOLEDs) has received great attention. Most of the reported SOLEDs were analyzed for uniaxial (x or y-axis) tensile strains only. However, due to wide angular moments of human body organs, ‘wearable electronics’ are expected to perform under multi-axial tensile as well as compression strains. The strain ratio (SR) of the demonstrated devices has also reached a maximum value of 0.5 and needs improvement.
This work presents the fabrication of wavy organic light-emitting diode (WOLED), which is capable of performing under multi-axial tensile and compression strains with higher strain ratios. The OLED device was first fabricated using conventional methods on a silicon substrate and then the device was peeled off and transferred to a thermally pre-strained PDMS, using kinetic transfer method. The pre-strain temperature was 150 °C and it induced a thermal expansion of about 1.3%. Random two-dimensional (2D) wavy buckles were formed by cooling down the PDMS substrate due to the difference in thermal coefficients. Instead of a universally used mechanical pre-strain method, we could make a device with multiaxial buckles through thermal pre-strain. The WOLED device was analyzed at 1.5% and 3% tensile and compression strains with a SR of 1.16 and 2.33, respectively. The device demonstrated good performance in the green light region up to 1.5% and showed comparable results even at 3% tensile and compression strains. A slight blue-shift in the electroluminescence analysis demonstrated that a various wavelength luminescence can be obtained by just altering the buckle size which can be controlled by the amount of pre-strain. Finite element simulation analysis was conducted, which provided valuable information about the presence of neutral plane in the device and a coherence between simulation and experimental results was observed.
The fabricated WOLED device presented a strong capability of performing under multi-axial tensile and compression strains with large strain ratios. The facile fabrication by conventional methods introduced in this work has a high potential to find its way to the next generation fields of stretchable/wearable electronics, electronic newspapers and curvilinear/expandable displays.
5:00 PM - MA02.08.11
Increased Photo-Stability in Small Molecule Organic Semiconductor by the Addition of a Crystalline Polymer
Jihee Kim1,Kyungkon Kim1
Ewha Womans University1
Show AbstractThe binary-blend bulk heterojunction (D073:PC71BM) demonstrates increased performance by the addition of a highly crystalline conjugated polymer poly[(2,5-bis(2-hexyldecyloxy)-phenylene)-alt-(5,6-difl uoro-4,7-di(thiophen-2-yl)benzo[c] [1,2,5]-thiadiazole)] (PPDT2FBT). The power conversion efficiency (PCE) of the D073-based OPV was improved from 4.62 % to 5.36 % by the addition of 5 vol % PPDT2FBT to the photoactive layer, which was composed of D073 and a fullerene derivative. This increased power conversion efficiency (PCE) is achieved due to improvements in Voc, Jsc, and FF.
Furthermore, the addition of PPDT2FBT enhanced the photo-stability of the D073-based OPV by decreasing the burn-in loss. The binary-blend bulk heterojunction (D073:PC71BM) maintains 17% of the initial efficiency, while the ternary-blend bulk heterojunction (D073:PPDT2FBT:PC71BM) maintains 76% of the initial efficiency after 1500 hours under a light soaking intensity of 1 sun. The most noticeable difference between binary and ternary-blend bulk heterojunction is Voc and FF. The binary-blend shows rapid Voc drop and it finally maintains 41% , 47% of initial Voc and FF respectively, while ternary-blend maintains initial Voc and 80% of initial FF. The huge decrease in Voc and FF may be due to charge recombination in photo-active film.
In order to explain changes in the blend after 1500 hours light soaking test, we performed GIWAXS, AFM, and various electrical characterizations were conducted.
5:00 PM - MA02.08.12
Bulk-Heterojunction with Long-Range Ordering—C60 Single Crystal with Incorporated Conjugated Polymer Networks
Hanying Li1,Jie Ren1
Zhejiang University1
Show Abstract
Bulk-heterojunction (BHJ) blends are commonly used as active materials for optoelectronic applications. BHJ with long-range ordering, by virtue of its high crystallinity, should leads to improved optoelectronic performance. However, the difficulty in controlling nucleation during blending process limits the improvement of crystallinity. In this work, C60 single crystals are prepared in organogels of Poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenvinylene] (MEH-PPV), a typical conjugated polymer. Instead of pure crystals, C60 crystals containing MEH-PPV nanofibers are obtained. Essentially, nanofiber networks of MEH-PPV gel are incorporated into growing C60 crystals and penetrate through the crystals, resulting in a crystal/gel-network interpenetrating composites. The single-crystallinity of the crystalline component is demonstrated by X-ray analysis. And the composite structures are revealed by the transmission electron microscopy. Furthermore, the steady-state and time-resolved photoluminescence (PL) spectroscopy indicates that the PL decay of the composite crystals is significantly faster than both MEH-PPV film and C60/MEH-PPV blends. As such, through gel incorporation, we obtain a bulk-heterojunction composed of C60 single crystal and MEH-PPV nanofiber network, which has potential to be high performance optoelectronic materials.
5:00 PM - MA02.08.13
A Novel Unsymmetrical Small Molecule as a Sensitizer for a Solution Processable Photo-OFETs
DaeHee Lim1,Minji Kang1,2,Soo-Young Jang1,2,Youn-Jung Heo1,Jueng-Eun Kim1,Yunseul Kim1,Dong-Yu Kim1,2
Gwangju Institute of Science and Technology1,Research Institute for Solar and Sustainable Energies2
Show AbstractA phototransistor is a light-sensitive transistor that have integrated function of photodiode and transistor. They convert light signals, which are very low intensity or wavelength range of limited human vision, into perceivable electrical signals. Such phototransistors have attracted a great deal of research attentions because they show various applications such as optical communication, remote control systems, and biological health monitoring and imaging.
In most studies on phototransistors, organic semiconductors have been intensively considered as promising materials owing to their flexibility, low-temperature and solution processability. Photo-OFETs (photo-organic field effect transistors) generally use a single semiconductor layer that can offer both light-sensing and amplification. However, it can be a trade-off in terms of material selection because photo-induced charge excitation and charge-carrier transportation appear within the same channel. An approach for efficient electrical modulation and light sensing is to employ a sensitizer, providing high absorption and heterogeneous integration with the FET channel. Moreover, the concept of the isolated sensitizer on the channel layer has been proposed for enhanced absorption, ideally without interfering with the electrical modulation.
In this presentation, we report synthesis of novel unsymmetrical small molecule as a sensitizer of the photo-OFETs. The cross-conjugation system as a strategy of enhancing the intramolecular charge transfer (ICT) interactions and extending the absorption range is proposed for the molecular design of donor-acceptor-donor type, TFP (triphenlyamine-fluorinated thiadiazole-pyrene), with π-conjugated spacer. The TFP presents wide absorption coverage (250 nm to 700 nm), attributed to the structural property of donor-acceptor-donor type, and has high solubility in various solvent caused by a tilted unsymmetrical an end group. The well-dissolved TFP in orthogonal solvents of the semiconducting materials enable to form a thin film through solution processing without damage to the underlying semiconducting layer. Moreover, in sensitized photo-OFET devices, it exhibits broadband photoresponse with enhanced charge carrier mobility and On/Off ratio. The various properties of TFP are analyzed by a combination of Differential Scanning Calorimetry (DSC), Thermogravimetric analysis (TGA), UV-Vis absorption, cyclic voltammetry and atomic force microscopy (AFM). The results indicate that the molecular design of organic sensitizer in the proposed system is a new approach not only for improving the photosensitivity, but also for ideal FET performance.
5:00 PM - MA02.08.14
Synthesis of Isomer-Free Quinoidal Small Molecules via Introducing Short Side Chain and Characterization of Their Charge Transport Properties
Yunseul Kim1,Hansu Hwang1,Minji Kang1,Youn-Jung Heo1,Jueng-Eun Kim1,DaeHee Lim1,Dong-Yu Kim1
Gwangju Institute of Science and Technology1
Show AbstractConjugated molecules based on quinoidal unit have attracted much attention as organic semiconductors for application in OFETs due to its structural features with high planarity and rigidity. Their planar conjugated structures induce extension of delocalization of π-electrons along the molecular backbone and strong intermolecular interaction via π-π stacking; therefore, quinoidal molecules manifested excellent charge transport properties. Recently quinoidal conjugated molecules end-capped by the isatin have been reported owing to easy and facile synthesis for forming the quinoidal structure and availability to control the solubility via tuning alkyl chains at the N-lactam position of isatin. However, isatin terminated quinoidal molecules have the possibility to exist geometrical isomers due to be connected to a double bond linkage between aromatic rings. Thereby, these molecules have difficulty purifying unavoidably produced isomers as well as understanding the exact molecular packing model and structure-property relationship.
In this work, the concept of incorporating short side chain into the quinoidal core unit was introduced to obtain the isomer-free isatin terminated quinoidal molecules, quinoidal bis-3,4-dimethoxythiophene (QuMeOBT) and quinoidal bis-ethylenedioxythiophene (QuEDOBT). These quinoidal molecules were clearly identified as isomer-free by NMR analysis. Their thermal, optical, electrochemical properties were characterized. Interestingly, a QuMeOBT single crystal could be obtained by the solvent evaporation method, and the crystal structure was determined via single-crystal X-ray diffraction. To investigate intrinsic charge carrier transport properties of the QuMeOBT, single-crystal field-effect transistors (SCFET) were fabricated in bottom-gate/top-contact configurations.
5:00 PM - MA02.08.17
Nanostructured PEDOT Polymer-Graphene Composite Structures for Flexible and Stretchable Electronics Applications
Mohamed Serry1,Shady Abd El-Nasser1,Mahmoud Sakr1
The American University in Cairo1
Show AbstractOne of the major drawbacks for successful application of graphene in energy storage and conversion applications is its cone shaped band gap.Poly (3,4-ethylenedioxythiophene) (PEDOT) has shown its applicability in several applications i.e. flexible devices, energy harvesting, energy storage, electrochemical supercapacitors and solar cells. In this work we discuss the synthesis and characterization of PEDOT/Graphene composite which has led to 196 enhancement in current output. The new composite structure is consisting of nanostructured conducting polymer deposited on the surface of graphene-Schottky-diode (Conducting-Polymer/Graphene/Pt/n-Si). PEDOT was selected as the organic semiconductor material because of its low band gap (1.5−1.7 eV), long-term stability as well as good electrical conductivity. Pt thin film was deposited using Atomic Layer Deposition (ALD) on a substrate of an N-silicon wafer and graphene layers were deposited using Plasma Enhanced Chemical Vapor Deposition (PECVD). Fabrication and Experimental section included spin coating (PEDOT) with different thicknesses and depositing different Pt thicknesses and I-V and I-t measurements were done for the samples under dark condition to neglect opto-electric effect to study the current enhancement. I-V measurements showed that by increasing polymer thickness the current decreases and the highest value was for the thinnest polymer layer. I-t test confirmed I-V value as the 100uL polymer has the highest current value in comparison to the other volumes. To show the Pt thickness effect, a 100uL of the polymer was spin coated on different Pt thicknesses and the highest current value was noticed for the 30nm while 5, 40, 50nm have low current. The proposed device consists of three interfaces between organic-semiconductor, semiconductor-metal, metal-semiconductor. The first interface between the metal-semiconductor in our case is Pt-N-silicon, this interface is a pure schottky diode. Moreover, the interface between the graphene and the platinum causes p-doping for the graphene and shifting the fermi-level downwards because of the Phys-sorption interaction between graphene layers and the thin film of Pt and result in increasing the number of holes in the structure. Finally, by adding PEDOT on the surface, increased p-doping level and by increasing polymer thickness the p-doping increases and will decrease current value. On the other hand, by increasing Pt-thickness, the higher the probability of graphene growth. Significant enhancement in the dark current from 99 µA for the bare graphene-Schottky devices to 20 mA for the PEDOT composite structures at −10V bias which corresponds to more than 196 times enhancement in current. The current response was extensively increased upon the deposition of PEDOT reaching 4.7 mA for the 100 µl PEDOT volume. The proposed device has shown consistency and enhancement in the current values and it could target flexible and stretchable devices.
5:00 PM - MA02.08.18
Symmetry Broken of Supramolecular Interaction in Multi-Scale Self-Assembly of Spiro-Arene Semiconductor and Opto-Electronic Properties
Zong-Qiong Lin1
Nanjing Tech University1
Show AbstractOrganic semiconductive nanocrystal is considered as a novel semiconductor for future organic electronic, where involving a serials advantage as the designable of energy gap of organic semiconductor, highly order molecular packing in crystal, nano-effects in nanomaterial. Herein, a serial of uniform nano-morphology is synthesis, where the symmetry broken driven multi-scale self-assembly is proposed, to investigate the nano effect on the performance of photo-response memory devices. The multi-scale self-assembly of bulky π-system and their opto-electronic properties are summarized as a smart building block. With the respect of the intrinsic feature of organic nanostructure self-assembly, the precisely morphology prediction of micro-/nano- crystal based on thermodynamic mechanism is firstly proposed to guide the multi-scale self-assembly of nano-structures through the calculation of supramolecular interaction energy. We propose the approach of symmetry broken of suparmolecular interactions under the non-equilibrium conditions, leading to the 1st, 2nd, 3rd symmetry broken of driven forces, as a result of 2D nanosheet, 1D nanowire (or quesi-1D nanobelt) and 3D polyhedra in multi-scales morphology, respectively, where the cruciformed spiro-arene SFX and its derivate are introduced as modeling compounds. In order to gain the 2D ultra-thin nano-structures for organic thin-film devices, the approach of deep symmetry broken is proposed on the supramolecular interactions, where a batch of flexible ultra-thin 2D freestanding nanosheet is obtained in ~10 nm thick, with multi-color emission, uniformity and well-defined shape.
The synthesis of uniform nano-structure, especially the ultra-thin 2D architecture, provides a novel material supporting as well as the idea model in the mechanism of device operation. The as prepared 2D ultrathin nanosheet is incorporated into highly ordered crystalline uniform thin-film with large area through ecofriendly aqueous processing. The organic diode is designed with such crystalline thin film as the active layer, making use of the nano-tuning effect between nanosheets, and performs a remarkable non-volatile electronic bi-stable feature accompanied by a photo-switching property. Such well-shaped orgnanic semiconductive nanosheets also can be introduced into organic transistor memory as the charge storage element and exhibits a typical multi-bit photo-programmable charge trapping behavior. The excellent charge storage property of devices may due to the highly ordered molecular packing of organic semiconductive nanostructure and the nano-effects at the interface. The organic nano-semiconductor and its hetero-structures with abundant opto-electronic property not only benefit for the construction of high density reliable memory devices, but also potentially for the development of organic opto-electronics towards highly smart behavior.
5:00 PM - MA02.08.19
Selective Response of all PEDOT:PSS Organic Electrochemical Transistor
Marta Tessarolo1,Erika Scavetta1,Isacco Gualandi1,Federica Mariani1,Domenica Tonelli1,Rita Mazzoni1,Beatrice Fraboni1
University of Bologna1
Show AbstractThe selective detection of dopamine (DA) is currently a subject of significant interest. Its real-time determination is of great importance in the diagnosis of neurological disorders, such as Parkinson’s disease. DA concentration is very low in biological samples and the common chemical sensors do not exhibit an adequate sensitivity for in vivo applications. A very interesting device, that has recently attracted large attention for its high sensitivity and low limit of detection, is the organic electrochemical transistor (OECT). Thanks to the intrinsic signal amplification due to transistor configuration, OECT could be a tool for a reliable detection of dopamine in biological fluids. Nevertheless, its widespread use in real-life applications is hindered by the lack of selectivity due to some interfering compounds like uric and ascorbic acids. Potentiodynamic techniques are commonly employed to separate the redox waves associated to different analytes, for amperometric sensors, but this approach had not yet been explored for OECT sensing. This work explores a new approach to selectively identify and determine the contributions of different analytes to the OECT electrical output signal through a linear scan of the gate potential. We have used OECTs entirely made of PEDOT:PSS (both conductive channel and gate) in order to take advantage of the peculiar electrochemical properties of the conducting polymer. We assessed how OECTs can profit from PEDOT:PSS electrochemical features by selectively detecting the electro-oxidation of three different analytes (ascorbic acid, uric acid and DA) present in the same solution, as it occurs at different gate potentials. The signal related to each one of the three analytes can be individually detected and resolved by recording the trans-conductance, obtaining a linear response for all the analytes. The here reported results also demonstrate that all-PEDOT:PSS OECTs sensitivities and limits of detection are comparable or even higher than sensitivities of the differential pulse voltammetry (DPV), a technique that employs a sophisticate potential wave and read-out system and that can hardly be considered a viable readout method in practical applications. An increase of the selectivity can be alternatively obtained through a proper chemical functionalization of the PEDOT gate electrode. In particular our research is addressed toward the covalent immobilization of Ferrocene-terminated alkyl chains of different lengths in the PEDOT film via “click chemistry” (i.e. copper-catalyzed azide–alkyne cycloaddition). Our results show that the presence of ferrocene redox mediator on the gate electrode allows to eliminate the interference of ascorbic acid in DA detection.
The here described results offer new perspectives on a simple tool that greatly improves the performance of all-PEDOT:PSS OECTs, demonstrating their selectivity and, thus, the possibility to employ them as bioanalytical sensors in real-life applications.
5:00 PM - MA02.08.20
Impact of Morphology, Side Chains and Crystallinity on Charge Transport Properties of π-Extended Double Helicenes
Janice Lin1,Ilhan Yavuz2,Takao Fujikawa3,Yatsutomo Segawa3,Kenichiro Itami3,Kendall Houk1
University of California, Los Angeles1,Marmara University2,Nagoya University3
Show AbstractPolycyclic aromatic hydrocarbons (PAHs) have been of interest in the scientific community as organic semiconductors in field-effect transistors (FETs), light-emitting diodes (LEDs), and organic photovoltaics (OPVs). In the last 100 years, interest has evolved towards curved aromatic hydrocarbons, such as corannulenes and helicenes, that are three-dimensional and can be either chiral or achiral. These materials usually pack in a columnar manner or with partial π-π stacking, which allows for close orbital contacts between molecules for high multi- dimensional charge transport. We report a computational study on the effect of side-chain substitution and unique crystal packing on the charge transport of two double helical molecules, whose synthesis and crystal structure were reported by the Itami group. These molecules, which we refer to as double helicenes (DHs) are structural hybrids of nonplanar [6]helicene and planar tribenzo[b,n,pqr] perylene (TBP). Using a previously described method rooted in Marcus theory and kinetic Monte Carlo (kMC) simulations, we calculated charge-transport properties and hole mobilities for perfect order and disordered DH systems. We find that side-chain substitution has small effect on intrinsic electronic properties in DHs molecular structure but dramatically impacts the packing arrangement, morphologies and transport network. Using these methods, we have established a direct link between the morphology, transport connectivity and hole mobilities. The results show that both unsubstituted and substituted DHs have high hole mobilities in the crystal phase. However, with the inclusion of positional disorder, mobility of crystalline DH1 was relatively lower while the mobility of DH2 remained nearly unchanged. We relate this effect to the dimensionality of their unique transport network. Both DH1 and DH2 are promising organic semiconductors with high mobilities in crystal and crystalline phases, with predicted values that lie in the range of ~1 to 10 cm2 V-1 s-1.
5:00 PM - MA02.08.22
Towards Melt Processed Organic Field-Effect Transistors
Alberto Scaccabarozzi1,Giorgio Ernesto Bonacchini1,Mario Caironi1
Italian Institute of Technology1
Show AbstractOrganic electronics have attracted considerable interest over the last decades promising an alternative to conventional, inorganic electronics platforms. To fully exploit the touted potential of this plastic electronics platform, however, other prerequisites need now to be fulfilled: for example, good mechanical stability, ease of processing and device reliability. A possible method to overcome these issues is the employment of insulating:semiconducting polymers blends, which have been demonstrated to display favourable rheological and mechanical properties without negatively affecting the electric performance.1–4
In this work we show how this approach can be extended in order to produced self-standing, fully printed, top-gate top-contact transistors as a possible route towards melt processed fully printed field-effect transistors. We selected here high-density polyethylene (HDPE) as the insulating polymer, since it is one of the most extensively used commodity polymers for the production of industrial thin films. We show how HDPE can be blended with commonly used semiconducting polymers and processed by solution and melt to achieve high efficiency OFETs.
1. Scaccabarozzi, A. D., & Stingelin, N. Semiconducting:insulating polymer blends for optoelectronic applications—a review of recent advances. Journal of Materials Chemistry A, 2, (28), 10818 (2014)
2. Müller, C. et al. Tough, Semiconducting Polyethylene-poly(3-hexylthiophene) Diblock Copolymers. Advanced Functional Materials 17, 2674–2679 (2007).
3. T. A. Ferenczi, C. Müller, D. D. C. Bradley, P. Smith, J. Nelson, and N. Stingelin, “Organic semiconductor:insulator polymer ternary blends for photovoltaics.,” Advanced materials (Deerfield Beach, Fla.), 23, (35), 4093-7, (2011)
4. Wolfer, P., Müller, C., Smith, P., Baklar, M.A. & Stingelin-Stutzmann, N., “α-quaterthiophene-polyethylene blends: phase behaviour and electronic properties” Synth. Met. 157, 827 (2007)
5:00 PM - MA02.08.23
Melt-Processable Semiconducting Polymer Blends
Jianguo Mei1
Purdue Univ1
Show AbstractA scalable and green approach to manufacture semiconducting microfibers from polymer melts has been demonstrated. The polymer chains are highly aligned along the microfiber’s long axis direction, and exhibit highly anisotropic optical properties. In addition, the polymer microfibers show good flexibility and stretchability with a yield point around 10% under a reversible stress and can be stretched up to 180% without breaking. These features are desired for future flexible, stretchable, and conformable electronics. The origin of this stretchability is studied with diketopyrrolopyrrole (DPP) derivatives using different conjugation break spacers and side chains. In addition, stretchable conducting microfibers can be obtained by doping with FeCl3, which are further evaluated as organic conductors and source/drain electrodes in organic field-effect transistors.
5:00 PM - MA02.08.25
Highly Efficient Bipolar Blue Light-Emitting Polyfluorenes Containing Ibenzothiophene-S,S-Dioxide Moiety
Wei Yang1
State Key Laboratory of Luminescent Materials and Devices, South China University of Technology1
Show AbstractRecently, polymer light-emitting diodes (PLEDs) have attracted much more attention both in academic institutions and in commercial companies, due to their great potential applications in full-color flat-panel displays and solid-state lightings based on large area flexible substrates. As one of the most extensively investigated blue light-emitters, polyfluorenes (PF) was particularly interesting because of their high photoluminescent quantum yield, good charge transport property, outstanding thermal stability, and facilely structural modification on the carbon-bridge. However, PF always suffer from unstable spectral stability induced by keto-defects and from poor electroluminescent (EL) performances caused by unbalanced charge carrier injection/transport, which could be overcome by incorporating electron-deficient moieties into the polyfluorene backbone or side chain. The dibenzothiophene-S, S-dioxide (SO) is an electron-deficient unit with high electron affinity and high fluorescent efficiency due to the -SO2 group in SO unit. Herein, we present our current progress on the realization of the highly efficient blue ligh-emitting polyfluorenes containing SO unit (PFSO) via intruducing hole-transporting units, such as carbazole(Cz) or triphenylamine(TPA)/derivatives (TF) into the main chain, the end group, and the side chain of the polymers, respectively. EL spectra of the PFSO-Cz containing SO/Cz units in the backbone exhibited broadening tendency with the increase of Cz unit, indicating ICT effect existed in polymers. The luminous efficiency of 5.2 cd A-1 was obtained with the CIE coordinates of (0.16, 0.17). The end-capped PFSO-TFs effectively prevented the ICT effect between SO and TF units. The PFSO-TFs exhibit an obviously enhanced performances compared with that of the pristine PFSO. PFSO-TF16 based device achieved an unprecedented low turn-on voltage of 2.7 V. In addition, LE of 4.4 cd A-1 was much higher than that of 2.8 cd A-1 from the control device of PFSO. The intrducing carbazole or triphenylamine substituents in the side chain of PFSO obviously facilitated a hole injection, leading to significant improvement in hole/electron flux. Interestingly, the copolymers containing either carbazole or triphenylamine substituent exhibited dramatically enhanced luminous efficiencies. LE of 7.1 cd A-1 and a sustained LE as high as 7.0 cd A-1 were achieved at a brightness of 1000 cd m-2, with CIE coordinates of (0.16, 0.18), the highest efficiency reported so far for blue-emitting polymers based on single-layer devices. These findings demonstrated that our simple and straightforward molecular design strategy may facilitate the development of new blue light-emitting polymers with high-performance.
5:00 PM - MA02.08.26
One-Step Fabrication of OFETs with a Smectic Liquid Crystalline Organic Semiconductor
Jun-ichi Hanna1,Ryota Yano1,Hiroaki Iino1
Tokyo Inst of Technology1
Show AbstractOFETs have a layered structure consisting of a gate insulator and an organic semiconductor on the substrate. Because of solubility of the materials in organic solvents, it gives a limit to both a process and materials to be used for fabrication of OFETs, when both organic insulator and semiconductor are used. One of the method to solve this problem is to adopt one-step fabrication of both gate insulator and organic semiconductor layers. We challenged this with a smectic liquid crystalline material, which shows self-organization favorable for the phase separation and for fabrication of a layered film favorable for 2D carrier transport.
We have succeeded in fabricating OFETs by one-step fabrication of bottom-gate and top-contact OFETs with a solution of a polymeric insulator and a smectic liquid crystalline organic semiconductor, Ph-BTBT-10. FET mobility was as high as 2.5cm2/V in the saturation regime when polymethylmethacrylate was used as a gate insulator.
5:00 PM - MA02.08.27
Theoretical Calculations of Carrier Mobilities of Bora- and Aza-Fullerenes
Nobuyuki Matsuzawa1,Alexander Goldberg2,Masaru Sasago1,H. Kwak2,Mathew Halls2
Panasonic Corp1,Schrödinger Inc2
Show AbstractMaterials exhibiting higher mobilities than conventional organic semiconducting materials such as fullerenes and condensed thiophenes are in highly demand for applications such as printed electronics. In order to explore new class of compounds that might show improved mobility, theoretical calculations of electron and hole mobilities of all possible isomers of bora- and aza-fullerenes of C58B2 and C58N2 in the amorphous state were performed. The calculations were performed by combining molecular dynamics simulations with quantum chemical calculations. The amorphous phase of candidate molecules was obtained by applying molecular dynamics calculations using the program Desmond [1], and transfer integrals were calculated for pairs of molecules in the obtained amorphous state using the DFT (density functional theory) program Jaguar [2]. Marcus theory in combination with the percolation treatment as derived by Evans et al. [3] was then applied to obtain estimated carrier mobilities of molecules. The calculated results showed that for several isomers of C58B2 and C58N2, electron and hole mobilites were predicted to be improved with a factor of 2 - 3 as compared to those for C60. Further discussions will be made to clarify factors that control the isomer dependence of mobilities.
[1] K.J. Bowers et al., Proceedings of the 2006 ACM/IEEE Conference on Supercomputing, ACM, Tampa, Florida, 2006, p. 84. [2] A.D. Bochevarov, et al., Int. J. Quantum Chem. 113 (2013) 2110. [3] D.R. Evans et al., Org. Electronics, 26 (2016) 50.
5:00 PM - MA02.08.28
Emission Area Patterning of Blade-Coated Organic Light-Emitting Diodes (OLEDs) via Printed Dielectrics
Donggeon Han1,Yasser Khan1,Karthik Gopalan1,Ana Arias1
University of California at Berkeley1
Show Abstract
Current innovations in displays and sensors require light sources with a tunable shape of light emission. Organic light-emitting diodes (OLEDs) provide a large degree of freedom in designing the light emission, as the shape of the light emission is defined by the active area of the OLEDs. Conventionally, pattering the active area involves procedures that use subtractive methods, such as photolithography or etching. Here, we show multiple ways to pattern the emission area of the OLEDs with printing techniques. A number of printing schemes such as stencil printing, spray coating, and screen printing are studied and utilized. We use spray coating and screen printing to deposit dielectric layers with desired patterns. At a luminance of 1000 cd/m2, the OLEDs with circular emissive areas demonstrate current density of 7.8 and 11 mA/cm2, EQE of 2.4 and 2.2 %, and luminous efficacy of 6.3 and 5.3 lm/W, respectively for spray-coated and screen-printed pattered dielectrics. The dielectric patterning methods presented here can be used to fabricate OLEDs with varied shapes of light emission, enabling novel displays and sensors.
5:00 PM - MA02.08.29
Fordable Flash Memories with Low Operating Voltage and Long Retention Time Using Polymer Dielectrics
Hanul Moon1,Seungwon Lee1,Hyejeong Seong1,Sung Gap Im1,Seunghyup Yoo1
Korea Advanced Institute of Science and Technology1
Show AbstractFlash memories are most successful and essential non-volatile memory devices to store data in modern electronic products from thumb-scale devices to smart-phones and tablets, and are also the most promising candidate for wearable or both-attachable devices in future. Significant amount of studies have been proposed flexible flash memories, but favorable devices satisfying all key characteristics including low programming/erasing voltages, long retention time and high flexibility simultaneously have not been reported yet. The memory operations of programming, erasing, and retention are dominantly governed by two dielectric layers of a tunneling dielectric layer (TDL) and a blocking dielectric layer (BDL), that sandwich a floating gate (FG) to store controlled amount of charges. The insulating property satisfying the role of TDL can be found in ultra-thin dielectric layers, in which the carrier conduction behavior classified to direct tunneling in low field and Fowler-Nordheim (F-N) tunneling in high field. The major bottleneck to develop flexible flash memories is a lack of dielectric layers having both excellent insulating property based on ideal tunneling conduction and good flexibility itself. Here, we propose flexible flash memories by using polymer dielectric layers produced by initiated chemical vapor deposition (iCVD) for TDL and BDL, and by rational design based on flash memories operation mechanisms
We employed two kinds of iCVD processed polymers of pV3D3 and pEGDMA, and they showed different dielectric constant of 2.2 and 3 respectively and similarly excellent tunneling-based insulating property. By using pV3D3 as TDL and pEGDMA as BDL, electric field inside TDL can be much increased comparing to that in BDL due to lower dielectric constant, and thus much higher carrier transport through TDL by F-N tunneling occurs while carrier transport through BDL remains significantly low by direct. This rational design causing asymmetric carrier transport in two dielectric layers is highly favorable to flash memory operation. And with an ultrathin ca. 15 nm thick- pV3D3 layer and a ca. 40 nm-thick pEGDMA, the organic flash memory with a C60 channel showed sufficient memory window of 5 V with programming and erasing voltage of 10 V, and low retention time over 10 years simultaneously. In terms of flexibility, the device maintained the excellent memory operation for the mechanical strain of up to 2.8 %, attributed to the high durability of iCVD polymer dielectric layers. And finally the organic flash memories fabricated on a 6 um-thick Mylar substrate showed homogeneous characteristics with significantly deformation such as folding with bending radius of 300 um of over 1000 times. This result is the first flexible flash memories showing commercially considerable memory performance and outstanding flexibility at the same time, and will be a promising candidate for highly deformable products such as wearable devices or electronic patches.
5:00 PM - MA02.08.30
Fullerene Single-Crystalline Nanostructures for Organic Electronics
Xiaoming Zhao1,Tianjun Liu1,Wenda Shi1,T. John S. Dennis1
Queen Mary University of London1
Show AbstractSingle crystals of organic semiconductors, being free of grain boundaries and molecular disorders, have been shown to exhibit high performance such as the superior charge carrier mobility and long exciton diffusion. On this point, organic single crystals would be ideal candidate for high performance electronic devices and for intrinsic property studies.
Fullerene materials are among the most widely-used materials for organic electronics. For instance, organic field-effect transistors (OFETs) based on C60 single crystals exhibit electron mobilities exceeding 10 cm2 V−1 s−1, one of the highest among n-channel OFETs. For organic photovoltaics (OPVs), the fullerene derivative of [6,6]-phenyl C61 butyric acid methyl ester ([60]PCBM) is the most widely used electron acceptor and has important functions in OPVs with high power conversion efficiency.
However, most of these organic electronic devices are yet based on fullerene in amorphous phase, which limits the enhancement of the device performance. Grain boundaries and molecular disorder in amorphous thin films scatter the charge carriers by the effect of coulomb scattering, which results in the reduction of charge carrier mobility. Thus, this challenge remains a major bottleneck in the advancement of device performance. In this presentation, I will talk about our research progress on the application of fullerene single crystals in organic electronics. This talk will discuss not only the performance enhancement of OFETs, OPVs, organic photodetectors and perovskite solar cells via crystal engineering, but also the fundamental studies concerning charge transport, excitonic and photovoltaic properties of the nitrogen atom encapsulated fullerene (N@C60) single crystals, [60]PCBM single crystals and single-crystalline p-n heterojunctions.
Reference
1. X. Zhao, T. J. S. Dennis,* et al., Antisolvent-assisted controllable growth of fullerene single crystal microwires for organic field effect transistors and photodetectors. Manuscript Submiited.
2. X. Zhao, T. J. S. Dennis,* et al., Understanding charge transport in endohedral fullerene single crystals. Manuscript Submiited.
3. X. Zhao, T. J. S. Dennis,* et al., [60]PCBM single crystals: remarkably enhanced band-like charge transport, broadband UV-Visible-NIR photo-responsivity and improved long-term air-stability. Manuscript Submiited.
4. X. Zhao, S. Wang,* I. D. W. Samuel,* T. J. S. Dennis,* et al., Organic single-crystalline p-n heterojunction as a model to study the intrinsic photovoltaic behaviors: exciton diffusion and charge transport. Manuscript Submiited.
5. X. Zhao, T. J. S. Dennis,* et al., Vertical grown fullerene single crystals for organic photovoltaics. Manuscript in Preparation.
6. X. Zhao, T. J. S. Dennis,* et al., Crystal engineering of charge transporting materials for perovskite solar cells. Manuscript in Preparation.
5:00 PM - MA02.08.31
A Novel Intelligent Biomimetic Skin of Chameleon with Performance of Self-Healing and Electrochromic
Rongzong Zheng1,Yi Wang1,Zhongquan Wan1,Chunyang Jia1,Jianlian Xie1
University of Electronic Science and Technology of China1
Show AbstractThe animals, such as chameleon, have the capability to change the skin colors to protect itself against any external threats, and can self-healed the wound of skin tissues. Inspired by this, here we present a novel copolymer film possessing biomimetic properties, which simultaneously integrates the electrochromic triphenylamine (TPA) and self-healing Diels-Alder groups. The flexible and stretchable film DFTPA-PI-MA based on TPA polyimide Diels-Alder copolymer acts like the natural chameleons skin. Remarkable electrochromic properties and excellent self-healing performance of the polymer were presented: Switching the colors from faint yellowish to olive green, excellent electrochemical cycle stability comprising more than 100 cycles with only minor decay of 1.12%. The coloration efficiency was 82.8 cm2C-1, coloring and bleaching response times were 5.3 and 12.2 s, respectively. The scars were self-healed just about 3 minutes at different color states, and the self-healed copolymer film can maintain the excellent electrochromic performance as before. The self-healing efficiency of the stretchable free-standing copolymer films is about 90%, experimentally proven by re-healing two halves of copolymer film into a single stretchable film. These remarkable features make it very promising material to overcome the crack generation problem inherited by conventional biomimetic chameleon skin. Moreover, the flexible copolymer was coated on silver conductive fabric to get the self-healing electrochromic fabric, and further assembled into the flexible wearable all-solid electrochromic skin successfully. The electrochromic skin like the versatile biomimetic chameleon skin, has good reliability for unprecedented applications such as civil and defense applications like flexible displays, artificial skins and stealth military hardware. The verified electrochromic and self-healing properties proves that the electrochromic skin like the versatile intelligent biomimetic chameleon skin, has good reliability for unprecedented applications such as civil and defense applications like flexible displays, artificial skins and stealth military hardware.
5:00 PM - MA02.08.32
Modification of Polymer Surfaces for Organic Electronics by Few-Layer Molecular Film
Tomoyuki Yokota1,Takashi Kajitani2,Ren Shidachi1,Takeyoshi Tokuhara1,Martin Kaltenbrunner3,Yoshiaki Shoji2,Fumitaka Ishiwari2,Tsuyoshi Sekitani4,Takanori Fukushima2,Takao Someya1
The University of Tokyo1,Institute of Innovative Research, Tokyo Institute of Technology2,Linz Institute of Technology (LIT), Johannes Kepler University3, The Institute of Scientific and Industrial Research (ISIR), Osaka University4
Show AbstractThe nature of the interface between the gate dielectric and organic semiconductor material in organic thin-film transistors has a significant impact on the resulting device characteristics, and therefore careful design and engineering is required to optimize device performance. In this study, we demonstrate organic modifiers based on space-filling paraffinic tripodal triptycenes, which form a self-assembled, completely oriented 2D (hexagonal triptycene array) + 1D (layer stacking) structure on polymers[1]. When a thin layer of the species is deposited onto the gate dielectric material, it acts as a universal surface energy modifier, yielding surface energies of 22.2 mJ/m2 regardless of the gate dielectric species. Consequently, the thin layer triptycene film was also applied to the gate dielectric layers of low-operating voltage OTFTs with a DNTT channel layer, and to integrated circuits constructed from these devices. Device characteristics were enhanced by the triptycene layer, while modification was not found to change the operating voltage of either the OTFTs or the circuits: the organic CMOS ring oscillator circuits operated at low voltages of just 0.8 V, and exhibited single-stage signal delay values of 9 μs at 10 V. To our knowledge, this is the lowest delay value among low-voltage, organic CMOS ring oscillators based on devices using polymer gate dielectrics.
This work was supported by the Someya Bio-Harmonized ERATO grant.
[1] N. Seiki, et al., Science 348, 1122–1126 (2015).
5:00 PM - MA02.08.33
Synthesis of Organic Semiconductor Bearing B←N Bridged Thienylthiazole and Diketopyrrolopyrrole for the Application of High Open-Circuit Voltage Organic Photovoltaics
KaYeon Ryu1,Wonsuk Kim1,Kyungkon Kim1
Ewha Womans University1
Show AbstractNew small molecular semiconductors (SMs) with small band gap and low-lying highest occupied molecular orbital (EHOMO), namely TBDPPOT, TBDPPEH, and TBDPPEHT4 were synthesized by incorporating the B←N bridged thienylthiazole and diketopyrrolopyrrole (DPP) derivatives. TBDPPOT and TBDPPEH were prepared, respectively, using two different DPPs having 1-octyl and 2-ethylhexyl moiety as the solubilizing group. In addition, the band gap of the TBDPPEH is further reduced by introducing planar thienothiophene unit, which was used for the preparation of TBDPPEHT4. These synthesized SMs are blended with fullerene derivative to construct a photo-active layer for organic photovoltaics. Among OPVs utilizing those SMs, the TBDPPEH exhibits highest power conversion efficiency of 3.21% with an exceptionally high VOC of 0.92 V, which is ascribed to low-lying HOMO energy level of -5.62 eV. It is expected that the utilization of TBDPPEH as a photo-active layer for OPVs would enhance the oxidation stability of the OPVs.
5:00 PM - MA02.08.34
High Contrast and Low-Power Consuming Electrochromic Polymer Windows
Eunkyoung Kim1,Younghoon Kim1,Minsu Han1,Woojae Lee1
Yonsei University1
Show AbstractElectrochromism is the reversible color change upon doping and dedoping. Recently, electrochromic devices (ECDs) have been actively pursued because of their various potential applications, such as electrochromic sunglasses, smart windows, data storage device, e-paper, and displays. In terms of the materials for these applications, fast response, and high color contrast, and stability are key elements to becoming a successful candidate. Further, to access the portable applications, lightness, flexibility, and low-power consumption are desired. To meet these needs, π-conjugated polymers(CPs) have intensively researched as a promising materials demonstrating a high coloration efficiency, fast response, and high reversibility.1 As these properties are influenced by not only the chemical structure of EC materials but also by the electrochromic reaction in a device, both factors are crucial. Of the various electrochromic CPs, the transmittance changes of the poly(3,4-propylenedioxythiophene) derivatives (PRs) having different side groups can reach high color contrast maintaining the high cycle stability. We synthesized several PRs for high color contrast and bistability.2 Further control on the potential at both working electrode and counter electrode, through charge balancing reactions, afforded ECDs with a high color contrast, long stability, and high bistability.3 Here, the optimum material combination for working electrode and counter electrode will be discussed along with charge balancing mechanism and demonstrate the application of the low-power consuming display into an automatic electrochromic windows.
1. P. M. Beaujuge and J. R. Reynolds, Chem. Rev., 2010, 110, 268-320.
2. H. Shin, S. Seo, C. Park, J. Na, M. Han and E. Kim, Energy. Environ. Sci., 2016, 9, 117-122.
3. Y. Kim, H. Shin, M. Han, S. Seo, W. Lee, J. Na, C. Park and E. Kim, Adv. Funct. Mater., 2017, 27, 1701192
5:00 PM - MA02.08.35
In Situ Area-Selective Positioning of Nanostructured Self-Assembling Films Enabled by Chemical Guide Templates and Temperature-Controlled Spin-Casting
Jung Hye Lee1,Hak-Jong Choi2,Heon Lee2,Yeon Sik Jung1
KAIST1,Korea University2
Show AbstractArea-selective positioning of organic/inorganic/hybrid thin films with high selectivity has been considered a long-lasting goal especially for high-performance in micro/nanoscale device applications. In general, for the patterning of functional thin films, there are several essential steps such as coating of hard mask, patterning, etching, and removing of the mask, which can often alter the fundamental properties. Here, we introduce a useful patterning method for thin film positioning, which can both realize selective positioning and exempt the requirement of a subsequent lift-off step. This advancement is use of chemical template with different surface energies and temperature-controlled spin-casting, called cold spin-casting (CSC). We found that sub-microscale area selectivity of sub-10 nm nanostructured block copolymer thin films increased through this CSC method, the optimized solution temperature was –5 degrees Celsius. This method is applicable to a case in microscale positioning of inorganic materials such as CdSe quantum dot solutions. This CSC method may suggest a new way for formation of two-dimensional nanoscale complex pattern customization.