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2012 MRS Fall Meeting Logo2012 MRS Fall Meeting & Exhibit

November 25-30, 2012 | Boston
Meeting Chairs: Chennupati Jagadish, Thomas Lippert, Amit Misra, Eric Stach, Ting Xu

Symposium I : Functional Materials for Solid Oxide Fuel Cells

2012-11-26   Show All Abstracts

Symposium Organizers

John A. Kilner, Imperial College London
Juergen Janek, Institut Justus-Liebig-Universit
Bilge Yildiz, Massachusetts Institute of Technology
Tatsumi Ishihara, Kyushu University
I3: Strain Effects I - Dedicated to Arthur S. Nowick
Session Chairs
Harry Tuller
Dario Marrocchelli
Monday PM, November 26, 2012
Hynes, Level 3, Room 310

2:30 AM - *I3.01
Metastable Thin Films for Energy Applications: On Structural Lattice Anomalies and Electrical Transport

Jennifer L.M. Rupp 1 2 3 Bilge Yildiz 2 Harry Tuller 3

1ETH Zurich Zurich Switzerland2Massachusetts Institute of Technology Cambridge USA3Massachusetts Institute of Technology Cambridge USA

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3:00 AM - *I3.02
Atomistic Simulations of Oxygen Vacancy Migration in Strained CeO2 Electrolytes

Roger A De Souza 1 Judith Hinterberg 1 Tobias Zacherle 1

1RWTH Aachen University Aachen Germany

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3:30 AM - I3.03
Determination of the Role of Strain on Oxygen Ion Conductivity in Epitaxial Zirconia and Ceria Multilayers

Weida Shen 1 Jun Jiang 2 Joshua L. Hertz 1 2

1University of Delaware Newark USA2University of Delaware Newark USA

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3:45 AM - I3.04
Effect of Lattice Expansion on the Ionic Conductivity in Gd-doped Ceria

Pratik Dholabhai 1 2 James B Adams 1 Peter A Crozier 1 Renu Sharma 1 3

1Arizona State University Tempe USA2Brookhaven National Laboratory Upton USA3National Institute of Standards and Technology Gaithersburg USA

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4:00 AM - I3
BREAK

I4: Electrolytes I
Session Chairs
Zhien Liu
Monday PM, November 26, 2012
Hynes, Level 3, Room 310

4:30 AM - *I4.01
From Perovskite to Apatite: Atomic-scale Insights into Defects, Transport and Surfaces of SOFC Materials

Saiful Islam 1

1University of Bath Bath United Kingdom

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5:00 AM - I4.02
Interstital Containing Complex Oxides as Potential IT-SOFC Electrolytes

Stephen Skinner 1 Ryan Bayliss 1 Ruth Sayers 2 Miguel Laguna-Bercero 3

1Imperial College London London United Kingdom2University of Liverpool Liverpool United Kingdom3Universidad de Zaragoza Zaragoza Spain

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5:15 AM - I4.03
Al-doping Effects on the Oxygen Conduction in Apatite-type Lanthanum Silicate

Ting Liao 2 Taizo Sasaki 1 Ziqi Sun 3

1National Institute for Materials Science Tsukuba Japan2University of Queensland Brisbane Australia3University of Wollongong Wollongong Australia

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5:30 AM - I4.04
Novel Oxide-ion Conduction Mechanism via Tetrahedral Moieties in Apatite-type Fast Ionic Conductors

Katsuyuki Matsunaga 1 2 Kouta Imaizumi 1 Kazuaki Toyoura 1

1Nagoya University Nagoya Japan2Japan Fine Ceramic Center Nagoya Japan

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5:45 AM - I4.05
Pulsed Laser Deposition of Gadolinium-doped Barium Zirconate Thin Films for Applications in Intermediate Temperature Solid Oxide Fuel Cells

Alex W. Skinner 1 Eric H. Remington 1 Alessandra Zenatti 2 Daniel Z. de Florio 2 Renato P Camata 1 2

1University of Alabama at Birmingham Birmingham USA2Universidade Federal do ABC Santo Andre Brazil

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I1:Cathode Surfaces I
Session Chairs
Saiful Islam
Monica Burriel
Monday AM, November 26, 2012
Hynes, Level 3, Room 310

9:30 AM - *I1.01
Multilayer and Thin Film Mixed Conducting Oxides: Surface and Interface Effects

Harry L Tuller 1 Bilge Yildiz 2 Yan Chen 2 Di Chen 1 Sean Bishop 1 3

1MIT Cambridge USA2MIT Cambridge USA3Kyushu University Fukuoka Japan

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10:00 AM - I1.02
Assessing First Principles Based Descriptors for Predicting Oxygen Reduction and Oxygen Revolution Reaction Activities of Transition Metal Perovskites

Yueh-Lin Lee 1 Yang Shao-Horn 1 Dane Morgan 2

1Massachusetts Institute of Technology Cambridge USA2University of Wisconsin-Madison Madison USA

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10:15 AM - I1.03
Sources of Chemical Heterogeneities on the Surface of Thin Film Cathodes

Wonyoung Lee 1 Jeong Woo Han 1 Zhuhua Cai 1 Bilge Yildiz 1

1Massachusetts Institute of Technology Cambridge USA

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10:30 AM - I1.04
Dynamic Response of La0.6Sr0.4Co0.2Fe0.8O3-delta; Cathode under Applied Electrochemical Potential

Edith Perret 1 E. Mitchell Hopper 1 Jeffrey A. Eastman 1 Peter M. Baldo 1 Kee-Chul Chang 1 Brian J. Ingram 2 Hoydoo You 1 Paul H. Fuoss 1

1Argonne National Laboratory Argonne USA2Argonne National Laboratory Argonne USA

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10:45 AM - I1.05
Oxygen Exchange Kinetics on Solid Oxide Fuel Cell Cathode Materials - Mechanistic Interpretation and the Importance of Defects

Rotraut Merkle 1 Lei Wang 1 2 Anja Wedig 1 Yuri A. Mastrikov 1 3 Eugene A. Kotomin 1 Joachim Maier 1

1MPI for Solid State Research Stuttgart Germany2MIT Cambridge USA3University of Latvia Riga Latvia

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11:00 AM - I1
BREAK

I2: Cathodes I
Session Chairs
Jennifer Rupp
Wonyoung Lee
Monday AM, November 26, 2012
Hynes, Level 3, Room 310

11:30 AM - *I2.01
Investigation of LSM Composite Cathode Stability during Operation and Its Effect on Long Term Durability of SOFCs

Hsiang-Jen Wang 2 Zhengliang Xing 1 Zhien Liu 1 Richard Goettler 1 Mark De Guire 2 Arthur Heuer 2

1Rolls-Royce Fuel Cell Systems (US) Inc. North Canton USA2Case Western Reserve University Cleveland USA

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12:00 PM - I2.02
Degradation and Stability of Complex Perovskites for Energy Applications

Maija Kuklja 1 David Fuks 2 Onise Sharia 1 Yuri A. Mastrikov 1 3 Eugene Kotomin 3 4

1University of Maryland College Park USA2Ben Gurion University of the Negev Beer Sheva Israel3University of Latvia Riga Latvia4Max Planck Institute for Solid State Research Stuttgart Germany

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12:15 PM - I2.03
Quantitative Microstructure Analysis and Electrochemical Activity of La0.6Sr0.4CoO3-delta; Electrodes Deposited by Spray Pyrolysis

Omar M. Pecho 1 2 Lorenz Holzer 1 Zhen Yang 3 Thomas Hocker 1 Robert J. Flatt 2 Julia Martynczuk 3 Ludwig J. Gauckler 3 Michel Prestat 3

1Zurich University of Applied Sciences (ZHAW) Winterthur Switzerland2ETH Zurich Zurich Switzerland3ETH Zurich Zurich Switzerland

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12:30 PM - I2.04
Local Studies of Oxygen Vacancy Content, Vacancy Ordering, and Defect Configurations in SOFC Cathode Materials with High-resolution STEM

Albina Y Borisevich 1 Young-Min Kim 1 Anna N Morozovska 2 Donovan N Leonard 1 Michael D Biegalski 1 Eugene A Eliseev 2 Sergei V Kalinin 1

1Oak Ridge National Laboratory Oak Ridge USA2National Academy of Science of Ukraine Kiev Ukraine

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12:45 PM - I2.05
A High-temperature Moessbauer Study of Iron-doped Ruddlesden-Popper Phases Lan+1NinO3n+1

Klaus Dieter Becker 1 Piotr Gaczynski 1 Salvatore Cusenza 1 Tobias Klande 2 Armin Feldhoff 2

1Technische Universitaet Braunschweig Braunschweig Germany2Leibniz-University Hannover Hannover Germany

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2012-11-27   Show All Abstracts

Symposium Organizers

John A. Kilner, Imperial College London
Juergen Janek, Institut Justus-Liebig-Universit
Bilge Yildiz, Massachusetts Institute of Technology
Tatsumi Ishihara, Kyushu University
I7/F7: Joint Session: Heterostructures for SOFCs II
Session Chairs
Shriram Ramanathan
Tuesday PM, November 27, 2012
Hynes, Level 3, Room 310

2:30 AM - *I7.01/F7.01
Ionic Conductivity of Oxide Thin Films and Superlattices

Enrico Traversa 1

1Xi'an Jiaotong University Xi'an China

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3:00 AM - I7.02/F7.02
Design and Fabrication of Heteroepitaxial Fluorite Thin Films for Micro-solid Oxide Fuel Cells by Pulsed Laser Deposition

Simone Sanna 1 Vincenzo Esposito 1 Johan Hjelm 1 Yunzhong Chen 1 Felix Trier 1 Arvid P.L. Bamp;#246;ttiger 1 Jens Wenzel Andreasen 1 Nini Pryds 1

1Technical University of Denmark Frederiksborgvej 399, 4000 Roskilde Denmark

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3:15 AM - I7.03/F7.03
Oxygen Tracer Diffusion Measurements in Multi-layered Thin Film Systems

Stuart N Cook 1 John A Kilner 1

1Imperial College London London United Kingdom

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3:30 AM - I7.04/F7.04
Electronic Activation and Anisotropic Oxygen Incorporation Kinetics at the (La0.8Sr0.2)CoO3/(La0.5Sr0.5)2CoO4 Supperlattices at Elevated Temperature

Yan Chen 1 Jeong Woo Han 1 Zhuhua Cai 1 Yener Kuru 1 2 Harry Tuller 2 Bilge Yildiz 1

1Massachusetts Institute of Technology Cambridge USA2Massachusetts Institute of Technology Cambridge USA

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3:45 AM - I7.05/F7.05
Cation Interdiffusion Model for Enhanced Oxygen Kinetics at Oxide Heterostructure Interfaces

Milind Gadre 1 Yueh-Lin Lee 3 Dane Morgan 1 2

1University of Wisconsin-Madison Madison USA2University of Wisconsin-Madison Madison USA3Massachusetts Institute of Technology Cambridge USA

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4:00 AM - I7/F7
BREAK

I8/F8: Joint Session: Thin Film SOFCs II
Session Chairs
Jacobo Santamaria
Tuesday PM, November 27, 2012
Hynes, Level 3, Room 310

4:30 AM - *I8.01/F8.01
Thin Film Electrodes in SOFC/SOEC Research: How to Identify Different Contributions to the Polarization Resistance?

Juergen Fleig 1 Markus Kubicek 1 Sandra Kogler 1 Andreas Nenning 1 Herbert Hutter 1 Alexander Karl Opitz 1

1TU Vienna Vienna Austria

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5:00 AM - *I8.02/F8.02
Reaching Critical Performance of Solid Oxide Fuel Cell with Thin-film Electrolyte and Nano-structure Electrode

Ji-Won Son 1

1Korea Institute of Science and Technology (KIST) Seoul Republic of Korea

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5:30 AM - I8.03/F8.03
Investigation of Defect Properties and Cathode Behavior of (Ba,Sr)(Ti,Fe)O3-delta; Mixed Conducting Oxides

Jae Jin Kim 1 Melanie Kuhn 1 Sean R. Bishop 1 2 Harry L. Tuller 1 2

1Massachusetts Institute of Technology Cambridge USA2Kyushu University Nishi-ku Japan

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5:45 AM - I8.04/F8.04
Potential Driven Chemical Expansion of La0.6Sr0.4Fe1-xCoxO3 Thin Films on Yttria Stabilized Zirconia

Kee-Chul Chang 1 Brian J Ingram 2 E. Mitchell Hopper 2 Miaolei Yan 3 Paul Salvador 3 Hoydoo You 1

1Argonne National Lab Argonne USA2Argonne National Lab Argonne USA3Carnegie Mellon University Pittsburgh USA

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I9: Poster Session
Session Chairs
John Kilner
Tuesday PM, November 27, 2012
Hynes, Level 2, Hall D

9:00 AM - I9.01
Mechanical Properties of Ni / (Sc2O3)0.1(CeO2)0.01(ZrO2)0.89 Porous Anodes

Yan Chen 1 Nina Orlovskaya 1 Thomas Graule 2 Jakob Kuebler 2

1University of Central Florida Orlando USA2Empa, Swiss Federal Laboratories for Materials Science and Technology, Laboratory for High Performance Ceramics Duebendorf Switzerland

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9:00 AM - I9.02
Enthalpies of Formation and Insights into Defect Association in Ceria Singly and Doubly Doped with Neodymia and Samaria

Salih Buyukkilic 1 2 Tatiana Shvareva 2 Alexandra Navrotsky 1 2

1UC Davis Davis USA2UC Davis Davis USA

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9:00 AM - I9.05
A Study of Oxygen Reduction Reaction on the Interface of (La,Sr)MnO3-delta; /(La,Sr)CoO3-delta; Thin Films for Solid Oxide Fuel Cells

Dongkyu Lee 1 Ethan J. Crumlin 1 Zhenxing Feng 1 Wesley T. Hong 1 Michael D. Biegalski 2 Hans M. Christen 2 Yang Shao-Horn 1

1Massachusetts Institute of Technology Cambridge USA2Oak Ridge National Laboratory Oak Ridge USA

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9:00 AM - I9.06
The Microscopic Origin of Giant Electrostriction in Oxygen Ion Conductors

Roman Korobko 1 Anitha Patlolla 1 Anna Kossoy 2 Ellen Wachtel 1 Harry Tuller 3 Anatoly I. Frenkel 2 Igor Lubomirsky 1

1Weizmann Institute Rehovot Israel2Yeshiva University New York USA3MIT Cambridge USA

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9:00 AM - I9.07
Monitoring Low Temperature Oxygen Diffusion in Gd-doped Ceria by Null-point Ellipsometry with Lock-in Detection

Guy Lazovki 1 Ellen Wachtel 1 Igor Lubomirsky 1

1Weizmann Institute Rehovot Israel

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9:00 AM - I9.08
A Direct Ethanol Solid Oxide Fuel Cell with Anode Catalytic Layer

Fabio C Fonseca 1 Shayenne D Nobrega 1 Fabio B Noronha 4 Patrick Gelin 3 Samuel George 2 Marlu C. Steil 2

1IPEN Sao Paulo Brazil2CNRS S. Martin d'Heres France3IRCELYON Lyon France4INT Rio de Janeiro Brazil

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9:00 AM - I9.09
Topological Parameters Evaluation for SOFC Cathode Microstructure

Linyun Liang 1 Kunok Chang 1 Paul A. Salvador 2 Kirk Gerdes 3 Long-Qing Chen 1

1The Pennsylvania State University University Park USA2Carnegie Mellon University Pittsburgh USA3National Energy Technology Laboratory Morgantown USA

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