Symposium Organizers
Graham Cross, Trinity College Dublin
Daniel Kiener, Montanuniversitat Leoben
Jun Lou, Rice University
Frederic Sansoz, University of Vermont
Symposium Support
Hysitron, Inc.
Keysight Technologies
Synton-MDP AG
S2: Soft Matter
Session Chairs
Andy Bushby
Gregory McKenna
Monday PM, November 30, 2015
Hynes, Level 2, Room 208
2:30 AM - *S2.01
Membrane Inflation in Polymers and Nanocomposites
Gregory B. McKenna 1
1Texas Tech Univ Lubbock United States
Show AbstractDetermination of the mechanical response of polymeric materials with dimensions less than 100 nm is a continuing challenge. Here we describe a novel membrane (“nano-bubble”) inflation method we have developed for the purpose of making measurements of the creep response of ultrathin polymer films and show two major findings. The first is that the material dynamics as measured by the creep response of the membranes depends dramatically on film thickness. For example, in polystyrene films, the dynamics is accelerated so much that the glass transition temperatureTg of a 11 nm thick film is reduced by approximately 50 K relative to the macroscopic Tg [1]. Furthermore, we have discovered that the nominal rubbery plateau in ultrathin films is stiffened by upwards of two orders of magnitude relative to the macroscopic state and the rate of stiffening (stiffening index S) correlates with the shape of the segmental relaxation in accordance with a recent model proposed by Ngai, Prevosto and Grassia[2]. We have elaborated this finding further and observe a strong correlation with the fragility index m that is related to glass formation according to the Angell categorization [3] of super cooled liquids. These results will be discussed in terms of current understanding of the impact of nanoconfinement on the glass transition behavior of polymers. In addition to being able to characterize the creep response of the ultrathin polymer films, we have also succeeded in adapting the bubble inflation method to make measurements on a graphene/polymer nano-sandwich structure and show that the method can be used to not only extract the stiffness of the graphene inner layer of the composite but that the method can be used to extract the interfacial shear strength of the polymer-graphene couple [4].
[1] P.A. O&’Connell, S.A. Hutcheson and G.B. McKenna, Journal of Polymer Science: Part B: Polymer Physics, 46, 1952-1965 (2008).
[2] K.L. Ngai, D. Prevosto and L. Grassia, Journal of Polymer Science: Part B: Polymer Physics, 51, 214-224 (2013).
[3] C.A. Angell, Journal of Non-Crystalline Solids, 73, 1-17 (1985).
[4] X. Li, J. Warzywoda and G.B. McKenna, Polymer, 55, 4976-4982 (2014).
3:00 AM - S2.02
Confined Layer Compression Testing: Measurement of Thin Film Stress versus Strain Mechanics in Elastic and Plastic States
Johann de Silva 1 Thomas Wyse Jackson 1 Mithun Chowdhury 1 Warren Oliver 2 John Pethica 1 Graham L. W. Cross 1
1Trinity College Dublin Dublin Ireland2Nanomechanics Inc. Oak Ridge United States
Show AbstractThe measurement of thin layer properties is important for both fundamental and technological reasons. Measurement of stress versus strain mechanics in one of the fundamental tenets upon which materials engineering is based. Direct measurements of elastic moduli and plasticity in nanometer thick polymeric glass layers is non-trivial, and one must often turn to indirect probes or small scale mechanical measurements that require complex interpretation. We introduce a novel strain-gradient free nanoscale compression test for thin soft layers on high stiffness substrates, which permits direct extraction of stress versus strain mechanics of the layer in elastic and plastic states from a single loading curve. Confined layer compression testing is built upon the compression of a precisely aligned flat probe into the layer forming a confined, stationary volume of highly compressed material in a well-defined, invariant geometry. Due to natural confinement from the surrounding material, we show that a state of uniaxial strain is created beneath the probe under small axial strains. Under a uniaxial strain stress state lateral strains within the film are zero throughout the entire volume under the probe. By this methodology we are able to directly probe via load-displacement measurement the stress-strain relationship in uniaxial flows under both reversible elastic and irreversible plastic conditions. Such nanoscale uniaxial strain testing is in some sense the complementary antithesis of nanopillar compression testing that has become so valuable for mechanical testing of size effects in hard materials. However, nanoscale uniaxial strain testing is suitable for in situ testing of both soft materials and continuous coatings on solid supporting substrates, in both elastic and plastic states. Confined compression measurements via instrumented nanoindentation apparatus or force microscopy apparatus provide new means to investigate mechanics and physics of thin films of structured or free volume materials such as glasses and biomaterials, including the plasticity of molecular materials, non-equilibrium states and behavior under the presence of high shear stress and hydrostatic pressure.
3:15 AM - S2.03
Stress-Strain Curve of a Single Antibody in Liquid
Alma P Perrino 1 Ricardo Garcia 1
1Instituto de Ciencia de Materiales, CSIC Madrid Spain
Show AbstractSecreted proteins experience multiple collisions with other biomolecules. To address how a single protein copes with collisions requires to measure its mechanical response in physiological-like conditions. Force microscopy methods have been applied to study the mechanical properties1,2 of proteins. However, most of the studies involving folded proteins are performed on two dimensional arrays3, and characterizing the nanomechanical response of a single, isolated protein remains a challenge. Here, we develop a force microscopy method to measure the stress-strain curve of a single antibody pentamer by applying forces in the 20 to 300 pN range. Elastic recovery is shown for up to 0.4 compressive strains. We report the Young modulus and the yield strength of the protein&’s central region, respectively, 3.1 MPa and 2.1 pN/nm2. The yield strength explains the capability of the protein to sustain multiple collisions without any loss of biological functionality. It also indicates the upper forces that could be used in force microscopy for the non-invasive imaging of β-sheet domains.
[1]Martinez-Martin , D., Herruzo, E. T., Dietz, C., Gomez-Herrero, J. & Garcia, R. Noninvasive protein structural flexibility mapping by bimodal dynamic AFM. Phys. Rev. Lett. 106, 198101 (2011).
[2]Dong, M.D. & Sahin, O. Determination of protein structural flexibility by microsecond force microscopy. Nature Nanotech.4, 514-517 (2009).
[3]Medalsy, I.D.; Muller, D.J. Nanomechanical properties of proteins and membranes depend on loading rate and electrostatic interactions. ACS Nano.2013,7, 2642-2650.
3:30 AM - S2.04
Determining the Viscous and Elastic Response of Soft Materials at the Nanometer Scale
David B Haviland 1 C. A. van Eysden 2 Philippe E. Leclere 3 Daniel Forchheimer 1 Hailu Kassa 3 Daniel Platz 1
1Royal Inst of Technology (KTH) Stockholm Sweden2University of Montana Bozeman United States3University of Mons Mons Belgium
Show AbstractThe Atomic Force Microscope (AFM) is an ideal tool for probing the nanometer-scale mechanical response of a free interface, with industrial applications in the design and quality control of nano-composite materials. Recent developments with dynamic AFM have enabled quantitative determination of tip-surface force with unprecedented resolution, speed and accuracy. The dominant paradigm for understanding these tip-surface forces builds upon contact mechanics, where force is considered to be a function of tip position, arising from elastic deformation in the contact volume. However, fundamental scaling arguments suggest that surface forces should dominate over volume forces at the nano-scale, especially with soft materials. Furthermore, many applications desire an understanding of the viscous, or energy-dissipating mechanical response of soft nano-fillers and their interphase to the surrounding matrix.
To understand both the viscous and elastic nature of surface forces we must go beyond contact mechanics with its assumption of quasi-static force equilibrium, and consider the tip-surface interaction as a dynamic two-body problem. We describe a multifrequency measurement technique and analysis method for AFM which, similar to Dynamic Mechanical Analysis (DMA) extracts the force that is in phase with, and quadrature to the harmonic tip motion [1]. We present measurements on several soft polymer blends that clearly show the significant effect of viscous forces arising from motion of the soft material surface. We introduce a new type of dynamic interaction model that takes in to account surface motion, allowing for a correct extraction of the elastic stiffness and viscous damping constants of the soft material interface.
[1] D. Platz et al. Nature Comm. 4, 1360 (2013).
3:45 AM - S2.05
Nanoindentation of Hydrogels and Soft Biological Tissues
Michelle L. Oyen 1
1University of Cambridge Cambridge United Kingdom
Show AbstractNanoindentation techniques have recently been adapted for the study of hydrated materials, including biological materials and hydrogels. There are unique challenges associated with testing hydrated materials in commercial instruments not designed for this application. Some key results from recent works using nanoindentation to evaluate hydrated materials including soft biological tissues, bulk hydrogels and thin hydrogel layers will be reviewed. Both natural and synthetic hydrogels have been characterized using indentation and nanoindentation across a wide range of experimental length-scales. The material response is shown to be greatly dependent on the chemical bonding within the hydrogel, i.e. whether the network is physically or chemically cross-linked. Hydrogels in particular are an attractive system for studying structure-properties relationships, as the water fraction can be systematically varied for a single polymer, and different polymers with the same water fraction can be compared. Based upon knowledge of the properties of each individual component, composite hydrogels can be created to mimic the overall response of complex biological materials to create multi-component tissue engineering scaffolds.
4:30 AM - *S2.06
Nanoindentation of Polymers: Are There Size Effects?
Andy Bushby 1
1Queen Mary University of London London United Kingdom
Show AbstractThe application of polymeric materials in engineering is rapidly increasing, in both bulk and coating form, in technologies from automotive to plastic electronics to medical applications. Determining the mechanical properties is important for structural applications, high throughput screening of materials and understanding of polymer physics. Nanoindentation is a convenient means to determine mechanical properties but the response is often difficult to interpret. Unlike metal or ceramic materials, the mechanical response of polymers can depend on strain, strain rate, strain state and load history. The test method, contact geometry and load cycle can also strongly influence the measured response. In indentation, assumptions about the contact area derived from displacement measurements may not hold, and the induced strain gradients can lead to variable time-dependent responses within the strained volume, making determination of material parameters more problematic. It is often difficult to obtain values equivalent to tensile, flexure or dynamic test methods, with measured indentation modulus and hardness values often too high, leading to the supposition of size effects.
Here we present the results of an inter-comparison study of indentation methods on a range of engineering polymers. Different indentation geometries and test methods are compared to tensile and dynamic data from the same materials. The results show that the choice of indenter geometry, load cycle and analysis method have a large influence on the measured mechanical property values obtained. The results imply that confinement of the polymer within the high pressure beneath the indenter can significantly change the elastic and flow properties, creating apparent size effects. However, comparative values for time-dependent elastic properties can be obtained using appropriate geometries and analysis methods. The work reported here formed part of the European ‘MeProVisc&’ project, providing background data for the planned ISO 14577 part 5, instrumented indentation measurement of time dependent materials.
5:00 AM - S2.07
The Effect of the Orientation of Graphene-Based Nanoplatelets upon Their Ability to Reinforce Composites
Robert Young 3 2 Zheling Li 3 2 Ian Kinloch 3 2 Neil Wilson 1
1University of Warwick Coventry United Kingdom2University of Manchester Manchester United Kingdom3University of Manchester Manchester United Kingdom
Show AbstractThere is a rapidly growing interest in using plate-like nano-fillers such as graphene to reinforce polymers. It is also known that the spatial orientation of the reinforcing elements in polymer-based composites plays a vital role in controlling mechanical properties. There is, however, no generally-accepted way of quantifying the spatial orientation at the nanoscale of plate-like fillers in nanocomposites.
It was found in our previous study that the intensity of scattering of the Raman band is dependent on the axis of laser polarization when the laser beam is parallel to the surface of the graphene plane and it was demonstrated that a generalized spherical expanded harmonics orientation distribution function (ODF) could be used to quantify the spatial orientation of the graphene. Based on this approach, polarized Raman spectroscopy has been used to quantify, as an example, the level of spatial orientation of graphene oxide (GO) flakes in different nanocomposites using a variety of polymeric matrices. It is demonstrated further how it is possible to relate the spatial orientation of nanoplatelets to the mechanical properties of the in the nanocomposites and, from the stress-induced Raman band shifts, to stress transfer to the reinforcement. In particular, it has been possible to determine the well-known Krenchel orientation factor for these plate-like fillers directly from the experimental polarized Raman data.
Apart from the quantification method for the spatial orientation of nanoplatelets in the nanocomposites, another significant finding of this study is that the Krenchel factor for 3D randomly-oriented nanoplatelets is 8/15. This means that random orientation of fillers such as graphene should reduce the Young&’s modulus of the nanocomposites by less than a factor of 2 compared with the fully-aligned material. Compared to the reduction in the modulus of a factor of 5 going from aligned to 3D randomly-oriented fibres and nanotubes, it means that better levels of reinforcement should be achievable with misaligned nanoplatelets compared with, for example, nanotubes and there is less need to ensure accurate alignment of nanoplatelets in composites. Beyond just graphene and GO, this approach should be more widely applicable to the determination of the orientation of other nanoplatelet fillers for which well-defined Raman spectra can be obtained. Moreover, the effect of spatial orientation upon the mechanical properties of composites predicted in terms of the Krenchel orientation factor will be valid for all types of 2D platelet reinforcement.
5:15 AM - S2.08
Finite Size Scaling Effect of Flexoelectricity in Langmuir-Blodgett Polymer Thin Films
Shashi Poddar 1 2 Stephen Ducharme 1 2
1Univ of Nebraska-Lincoln Lincoln United States2Nebraska Center for Materials and Nanoscience Lincoln United States
Show AbstractAn alternative approach to nanoscale electromechanical coupling is to exploit the flexoelectric effect, which is a linear coupling of strain gradient and the electric field. Flexoelectricity is functionally different from piezoelectricity, which in contrast is a linear coupling of strain to the electric field, in two significant ways. First, it lifts the restriction of the material structure being non-centrosymmetric, making it a universal effect whose magnitude depends upon the strength of the strain gradient and the geometrical arrangements of the molecular moieties. Second, the dependence on the strain gradient makes flexoelectricity a promising approach to nanoscale functionality and devices.
We report the results of a study on the dependence of the flexoelectric response on thickness in the ultrathin films of polar and non-polar polymers of vinylidene fluoride (VDF). The flexoelectric response was measured using a bent cantilever method and the results were corrected for the contribution from the interfacial electrode oxide layer. The results indicate enhancement of the response with decreasing film thickness in polar and non-polar polymers by up to a factor of 40 as compared to the bulk values, reaching such enhanced values in films only 10 nm thick. These results are consistent with a model accounting for interfacial contributions, and underline how large electromechanical coupling can be produced at the nanoscale.
5:30 AM - S2.09
In Situ 3D Nanomechanical Testing and Characterization of Fracture in Dentin
Robert Bradley 2 Xuekun Lu 2 Philip Withers 2 William Harris 1 Arno Merkle 1 Benjamin Hornberger 1 Hrishikesh Bale 1
1Carl Zeiss X-Ray Microscopy, Inc. Pleasanton United States2University of Manchester Manchester United Kingdom
Show AbstractDentin is a naturally occurring nano-composite material (found in teeth) consisting of a collagen matrix, mineralized hydroxyapatite, and anisotropic tubule structures. This natural structure is of interest for biomimetic applications due it&’s remarkable mechanical properties, derived largely from the strength of the mineralized component combined with the unique fracture behavior dictated by the tubule features. An understanding of the damage evolution in such a naturally occurring structure can possibly aid in the design of man-made materials with similar properties. To that end, this work will present an in situ nanoindentation study of a sample of elephant dentin, performed in a commercial nanoscale 3D X-ray microscope. The X-ray microscope system provides spatial resolution on the tens of nanometer scale for samples ranging from tens to hundreds of microns in size, enabling new scientific investigations by serving a middle ground between the length scales of 3D in situ techniques possible with higher resolution TEM and somewhat coarser resolution classical micro-CT. The 3D data is collected by performing tomographic data acquisition by rotation and imaging of the sample through a range of angular orientations. A new load stage designed specifically for manipulation of samples in this system was implemented, allowing progressive indentation steps to induce fracture in the dentin sample under increasing load. In this study, 3D imaging was performed at multiple states of applied load to monitor the crack initiation and growth processes at the nanoscale, and gain insight into the connections between the novel microstructure, crack shielding mechanisms, and the material&’s fracture toughness. Visualization and quantitative analysis will be presented to help understand the process.
5:45 AM - S2.10
Micromechanics of Wood Cell Wall
Lik-ho Tam 1 Denvid Lau 1
1City Univ of Hong Kong Kowloon Hong Kong
Show AbstractThe damage evolution and structural failure in trees and other plants are mainly originated from the plastic yielding in the wood cell wall at the microstructural level, which consists of cellulose fibers embedded in a matrix of hemicellulose and either lignin or pectin1. Understanding the mechanical behavior of wood cell wall at the plastic regime is critical to the investigation of the fracture characteristics of trees at macro-scale. In this research work, the wood cell wall, which consists of cellulose fibers, hemicellulose chains and lignin macromolecules, is modeled at the mesoscale to investigate the mechanical responses under tensile deformation. By examining the stress-strain relationship, the mechanical behaviors of the wood cell wall at the plastic yielding range will be obtained, which will be compared with experimental measurements and theoretical predictions to provide a bottom-up description of micromechanics of the wood cell wall, and to explain the damage evolution and structural failure occurred at the larger scales. The wood cell wall investigated here can be applied to the construction of wood hierarchical structure as a basic modeling unit and such application can be further extended to other natural materials.
1. L. Köhler and H.-C. Spatz, Planta 215 (1), 33-40 (2002).
S3: Poster Session I
Session Chairs
Helena Van Swygenhoven-Moens
Scott Mao
Monday PM, November 30, 2015
Hynes, Level 1, Hall B
9:00 AM - S3.01
Characterization of Dislocation Formation in R-Plane Slip Initiating Plastic Deformation in Nano-Indentation on High Quality Bulk GaN Surface
Toshiya Yokogawa 1 Sachi Niki 2 Junko Maekawa 2 Masahiko Aoki 2 Masaki Fujikane 3
1Yamaguchi Univ Ube Japan2Ion Technology Center Co., Ltd. Hirakata Japan3Panasonic Moriguchi Japan
Show AbstractBulk GaN substrate has attracted much attention because of high quality and low dislocation density. We previously reported the dislocation formation and movement in surface dimples nano-indented on the high quality bulk GaN, and also proposed the mechanism of r-plane (-1012) slip initiating plastic deformation, so called pop-in event, which is supported by molecular dynamics simulation [1,2]. However, by TEM analyses, it was difficult to confirm the clear evidence of r-plane slip initiating the plastic deformation because of the generation of several kinds of dislocation multiplications and dislocation loops as secondary and tertiary slips accompanying the r-plane slip. In this paper we present evidence of r-plane (-1012) slip mechanism in indented GaN surface by using precise nano-indentation with smaller radius indenter (~100 nm) and lower pop-in load (~400 mu;N), comparing with our previous studies, and TEM observation right after the plastic deformation.
Nano-indentation was precisely performed on the surface of c-plane and m-plane bulk GaN. We chose a Berkovich diamond indenter with smaller radius of ~100 nm. The maximum load of transition from elastic to plastic deformation (pop-in load) was observed at 400 mu;N which is relatively smaller than that of our previous studies.
Cross-sectional TEM observation was performed right after the pop-in event beneath the indented surface of the c-plane bulk GaN. The pyramidal dislocation line of r-plane slip was clearly observed which is inclined by 43 degree from c-plane surface. And the basal c-plane slip and the prism m-plane slip occurred as a secondary or tertiary slip system were not observed, which is previously observed in larger radius indenter and higher pop-in load.
From these results including the nano-indentation for the m-plane bulk GaN, we confirm the mechanism for initiating plastic deformation as follows: i) indentation stress caused small-scale shuffles of atoms at the center of the diamond tip beneath the contact surface, ii) a metastable boundary arose locally along the r-plane, and iii) plastic deformation was initiated via the r-plane slip. The characterization by TEM analyses agrees well with the initial stage of plastic deformation with r-plane dislocation predicted by the molecular dynamics simulation.
[1] Masaki Fujikane, Toshiya Yokogawa, Shijo Nagao, and Roman Nowak, Jpn. J. Appl. Phys. 52, 08JJ01 (2013).
[2] Toshiya Yokogawa, Masaki Fujikane, Shijo Nagao, and Roman Nowak, 2015 MRS Spring Meeting & Exhibit, San Francisco, FF2.09, April 07, 2015
9:00 AM - S3.02
Microstructure and Mechanical properties of Al0.7CoCrFeNi High Entropy Alloy (HEA)
Adenike Monsurat Giwa 1 Peter K Liaw 2 Karin A. Dahmen 3 Julia R. Greer 1
1California Institute of Technology Pasadena United States2The University of Tennessee - Knoxville Knoxville United States3University of Illinois- Urbana Champaign Urbana United States
Show AbstractHigh Entropy alloys (HEAs) are solid solution alloys containing five or more principal elements in equal or near equal atomic percent (at %). In this study, the Al0.7CoCrFeNi HEA was synthesized by vacuum arc melting and homogenized at 1250 0C for 50 hours. The microstructure shows the presence of 2 phases. The BCC (A2+B2) and the FCC phase. Nano-pillars were fabricated from the single crystal Al0.7CoCrFeNi HEA in the [001] of the BCC (A2+B2) phase and [324] of the FCC phase having diameters ranging from 400 nm to 2 mu;m using the focused ion beam and compressed using the Hysitron Nanoindenter. High yield strengths of about 2.2 GPa was observed in the BCC (A2+B2) phase and about 1.2 GPa for the FCC phase. Size effect occurs in both phases, the smaller pillars having the highest strength values. Comparing the BCC phase of the HEA with pure BCC metals shows a reduced size dependence with increased yield strength but the FCC phase in comparism with pure FCC metals shows similar size dependence with increased yield strength. This is attributed to the difference in lattice resistance of the two phases.
9:00 AM - S3.03
Plasticity of GaN under Highly-Localized Nanoindentation Stress Fields
Rodrigo Prioli Menezes 1 2 Paula Galvatilde;o Caldas 1 Elizandra Martins Silva 1 Jingyi Huang 2 Reid Juday 2 A. Fischer 2 Fernando A. Ponce 2
1Univ Catolica-Rio de Janeiro Rio de Janeiro Brazil2Arizona State University Tempe United States
Show AbstractDuring the manufacturing process of electronic devices, semiconductor materials are subject to handling and contact with surfaces that could lead to plastic deformation or even fracture. Thus, an understanding of the mechanical deformation mechanisms of semiconductor materials is important. This can be achieved using nanoindentation techniques that allow the study of mechanical deformation mechanisms in nanoscale. Studies have been performed on the mechanical properties of gallium nitride (GaN) using nanoindentation with sperical tips with radius of curvature between 4 mu;m and 5 mu;m, but the early stages of plastic deformation and the dynamics of the deformation process are still unclear. In this work, we present a nanoindentation study using a conespherical tip with a radius of curvatore of 260 nm, which is approximatelly ~ 20 times smaller than the radius of curvature of the tips used in the literature. Therefore, our nanoindentations were able to produce highly-localized stress fields allowing a discussion on the incipient plasticity of GaN at the nanoscale. We report the deformation mechanism of GaN thin films with a [0001] orientation and the optical properties associated with the plastic deformation resulting from stress fields produced by nanoindentation. The residual indentation pits were studied using atomic force microscopy, transmission electron microscopy, and cathodoluminescence spectroscopy. The incipient plasticity was observed to be initiated by metastable atomic-scale slip events that occur as the crystal conforms to the shape of the nanoscale tip. Dislocation locking leads to pop-in events associated with the introduction of large volumetric material displacements at the indentation site. A large number of non-radiative defects were observed directly below the indentation. Regions under tensile strain extending from the nanoindentation were also observed. An insight of a plastic deformation process based on dislocation nucleation under highly-localized stress field is presented.
9:00 AM - S3.04
Fracture Toughness of Rare Earth Doped Magnesium Aluminate Spinel Using a Micro Cantilever Deflection Test
Yuwei Cui 1 Onthida Kosasang 1 Animesh Kundu 1 Martin Harmer 1 Richard P. Vinci 1
1Lehigh Univ Bethlehem United States
Show AbstractMicro-cantilever deflection testing has been used to determine fracture toughness at magnesium aluminate spinel bicrystal interfaces. Focused ion beam milling was used for micro beam fabrication and prenotch preparation. In the present study, the micro cantilever beams were fabricated along the bi-crystal grain boundary of magnesium aluminate spinel doped with either Ytterbium or Europium. The boundary location was confirmed using Electron Backscatter Diffraction after milling and a prenotch aligned with the interface was cut using a lower ion beam current. An in-situ nano mechanical test system, the Hysitron PI-85 Picoindenter, was used to perform the test and record the loading and displacement. A 3D finite element model of the micro cantilever beam was built in ANSYS APDL. A dedicated solver called Frac3D was utilized to calculate the finite specimen width correction term and estimate the fracture intensity factor. High resolution electron microscopy was used to identify the structure and chemistry of the boundaries. By combining the microscopy and mechanical testing results, a direct correlation between different complexion types and grain boundary mechanical behavior is to be established.
9:00 AM - S3.05
Shuffling-Controlled Mg{10-12}
Akio Ishii 1 Ju Li 3 Shigenobu Ogata 1 2
1Osaka University Toyonaka Japan2Kyoto University Kyoto Japan3Massachusetts Institute of Technology Cambridge United States
Show AbstractDeformation twinning is a critical component of HCP Mg&’s deformation mechanisms. Recently, anomalies were detected in an important {10-12}<10-1-1> twinning system[1]. This experimental result hinted that deformation twinning in Mg could be fundamentally different from traditional models for cubic metals. Theoretically, this topic has also been controversial and unsettled: shear-controlled or shuffling-controlled issue [2][3]. In this study, we computed atomistic pathways of deformation twinning with First-principles calculation, and quantified the pathways by two variables: strain which describes shape change of a periodic supercell, and shuffling which describes non-affine displacements of the internal degrees of freedom. The minimum energy path involves juxtaposition of both. If one can obtain the same saddle point by continuously varying the strain and relaxing the internal degrees of freedom by steepest descent, we call the path strain-controlled, and vice versa. With this way, we find the {10-12} <10-1-1> twinning of Mg is shuffling-controlled, that is, the reaction coordinate is dominated by non-affine displacement instead of strain. This has important consequences on the temperature and strain-rate dependences of {10-12} <10-1-1> deformation twinning due to the reduced importance of long-range elastic interactions. Thus, the room-temperature deformation twinning in magnesium is markedly and qualitatively different from traditional understanding.
[1] B. Yu, et al. Nature Comm. 5 (2014) 3297
[2] B. Li & E. Ma, Phys. Rev. Lett. 103 (2009) 035503.
[3]A. Serra, D. J. Bacon and R. C. Pond, Phys. Rev. Lett. 104 (2010) 029603.
9:00 AM - S3.06
Influence of Indenter Angle on Small-Scale Cracking in Fused Quartz during Nanoindentation
Brittnee A. Mound 1 George M. Pharr 1 2
1University of Tennessee Knoxville United States2Oak Ridge National Laboratory Oak Ridge United States
Show AbstractIndenter angle effects on the cracking behavior of fused quartz were studied using nanoindentation experiments with different triangular pyramidal indenters with the centerline-to-face angles ranging from 35.3° to 85.0°. The indentation loads were varied from 10 to 500 mN to examine both the initial stages of cracking as well as the propagation of well-developed cracks with lengths much greater than size of the contact impression. Images of the indentations were obtained in a high-resolution scanning electron microscope (SEM) to observe the general features of the cracking and measure the indentation sizes and crack lengths for each indenter. The observations are used to examine the mechanisms of crack nucleation and crack growth in this classical brittle material.
9:00 AM - S3.07
Ion Bombardment-Induced Brittle-to-Ductile Transition of Submicron-Sized Crystalline Si
Yuecun Wang 1 Zhiwei Shan 1 Degang Xie 1
1Xirsquo;an Jiaotong University Xi'an China
Show AbstractSi pillars fabricated by focused ion beam (FIB) had been reported to have a critical size of 310-400 nm, below which their deformation behavior would experience a brittle-to-ductile transition at room temperature [1]. However, the potential effects from the high energy ion bombardment have been overlooked so far. Here, we demonstrated that the amorphous Si (a-Si) shell introduced during the FIB fabrication process was much softer and more ductile than the crystalline Si (c-Si), which can effectively inhibit the crack propagation in the c-Si core. Hence, the reported size-dependent brittle-to-ductile transition was actually stemmed from the imperfect sample fabrication method. Once the a-Si shell was crystallized by thermal treatment, Si pillars would behave brittle again with their modulus comparable to their bulk counterpart, showing that the crystalline Si is inherently brittle no matter in bulk or in submicron size. We also developed an effective analytical core-shell model to predict the modulus of as-FIBed Si pillars and derive the modulus of both crystalline Si core and a-Si shell, which fits well with the experiment results.
References
[1]Fredrik Östlund, Karolina Rzepiejewska-Malyska, Klaus Leifer, Lucas M. Hale, Yuye Tang, Roberto Ballarini, William W. Gerberich, and Johann Michler, Adv. Funct. Mater. 19, 2439 (2009).
9:00 AM - S3.08
Tensile Behavior of Fully Nanotwinned Cu-Based Binary Alloys
Nathan Heckman 1 Andrea Maria Hodge 1 2
1University of Southern California Los Angeles United States2University of Southern California Los Angeles United States
Show AbstractThere has been much research on highly nanotwinned Cu due to its potential for simultaneous high strength and ductility. Single element systems have limited engineering applications, though, and introducing alloying elements allows for a wide range of new materials with lower stacking fault energies which are more likely to produce fully twinned microstructures. In this study, the tensile properties of fully nanotwinned Cu-based binary alloys containing different alloying elements were determined with a custom-built small-scale tensile tester utilizing digital image correlation to generate in-situ strain maps. The effects of varying microstructure are examined for different alloy systems in order to understand their mechanical behavior. Yield strengths between 800 and 1500 MPa and strains to failure between 2 and 6% were achieved with varying twin thickness, grain size, and composition. Samples were synthesized by magnetron sputtering with stacking fault energies ranging from 6 to 45 mJ/m2.
9:00 AM - S3.09
Size Dependent Compressibility of Nano Ceria
Philip Rodenbough 1 Junhua Song 1 Siu-Wai Chan 1
1Columbia Univ New York United States
Show AbstractWe report the crystallite-size-dependency of the compressibility of nanoceria under hydrostaticpressure for a wide variety of crystallite diameters and comment on the size-based trends indicating an extremum near 33 nm. Uniform nano-crystals of ceria were synthesized by basic precipitation from cerium (III) nitrate. Size-control was achieved by adjusting mixing time and, for larger particles, a subsequent annealing temperature. The nano-crystals were characterized bytransmission electron microscopy and standard ambient x-ray diffraction (XRD). Compressibility, or its reciprocal, bulk modulus, was measured with high-pressure XRD at LBL-ALS, using helium, neon, or argon as the pressure-transmitting medium for all samples. As crystallite size decreased below 100 nm, the bulk modulus first increased, and then decreased, achieving a maximum near a crystallite diameter of 33 nm. We review earlier work and examine several possible explanations for the peaking of bulk modulus at an intermediate crystallite size.
9:00 AM - S3.10
Mechanical Properties of Al-Doped-ZnO ALD Thin Film Deposited on Polyimide as Transparent Electrode
Gyeong Beom Lee 1 Myeong Woo Lee 1 Yun-Jae Kim 1 Byoung-Ho Choi 1
1Korea University Seoul Korea (the Republic of)
Show AbstractFlexible display is promising electronic devices which can act bending motion in anywhere. For some time past, it has been concerned from numerous manufacturer to apply flexible technology in e-paper, mobile phone and consumer electronics. Even if flexible display has many potentials in industry fields, it still has been issues to resolve yet. Traditionally, semiconductors and glass materials have been used as substrate. But these materials have trouble with manufacturing a flexible devices owing to material property such as brittleness, rigidity and weight.
Polymer (polycarbonate, PET, etc.) regarded as complementary materials instead of silicon and glass because device which is composed of the plastic material can be curved deeply as bendable display. Al-doped-ZnO (AZO) thin film was well known as low-cost transparent conductive oxide film instead of indium tin oxide (ITO). And Al-doped-ZnO is one of the most widely investigated electrode materials. Previous reports demonstrated that resistivity of their AZO film exhibited 2.2*10^-3 #8486;cm when 2 at% of Zn atoms were replaced by Al atoms.1 However, not only electrical property but also mechanical property of AZO thin film as electrode is very significant in flexible devices.
Reports of mechanical property of AZO film are not enough, relatively. Especially, mechanical property such as strength, stiffness can be crucial factor to predict reliability, life time of device under environmental loading conditions. In this research, we fabricated AZO on polyimide film using atomic layer deposition (ALD) process. ALD is a thin film deposition technique allowing low process temperature, uniformity and controllability of thickness. Moreover, separated injection of the precursors in a reaction chamber allows use of highly reactive precursors and control of reaction time for each step. This facilitate to make thin film at low temperature and can be key of application of flexible display.
And electric-micro tensile test was performed to compare of the performance of the conductive oxide film deposited on polyimide substrate under process conditions such as deposition temperature, %Al doping ratio, O2 plasma. As tensile force was loaded on specimen, electrical resistance & stress value was measured under %strain in DAQ system. Especially, it brought the result that elastic modulus of O2 plasma treated-PI deposited with AZO was increased up to 20% then before. And in situ LFM (Lateral force microscopy) was performed to investigate interaction between thin film and substrate. An x-ray diffraction (XRD) was employed to reveal the structure of AZO using Cu Κα radiation. The surface morphology was analyzed by using the scanning electron microscope (SEM). To quantify the bonding strength, x-ray photoelectron spectroscopy (XPS) was used in this experiments.
Reference
J. W. Elam , D. Routkevitch , S. M. George , J. Electrochem. Soc. 2003,150 , G339
9:00 AM - S3.11
Resolving Strain Rate Variations in Nanocrystalline Metals
Douglas D. Stauffer 1 Ryan Kraft 1 Verena Maier 2 S.A. Syed Asif 1
1Hysitron, Inc. Eden Prairie United States2Montanuniversitauml;t Leoben Leoben Austria
Show AbstractThe use of nanoindentation to test through a range of strain rates is a growing field, with applications to both beginning, e.g. metal forming, and end of lifetime, e.g. impact deformation in many materials. The use of dynamic indentation methodology, superimposing an oscillating AC load over the DC quasistatic load, can be used to measure properties such as Hardness and Modulus as a function of time and depth. However, several assumptions need to be made to do so reliably. One such requirement is that the material response be such that the area function remains valid. For many materials, including the nanocrystalline copper tested here, that assumption is violated when the amount of pile-up varies with the strain rate. Theoretical strain rate pile-ups are compared to the experimental result, using both in and ex situ testing. A simple method for correcting the hardness as a function of the strain rate is presented. Additionally, a MEMS based transducer is used to test at strain rates approaching 10, to further extend the range of nanoindentation strain rate testing.
9:00 AM - S3.12
Correction of the Tensile Post-Necking Flow Curve in Metals Using Nanoindentation Data
Ivan Romero-Fonseca 1 2 Qiuming Wei 1
1University of North Carolina at Charlotte Charlotte United States2Universidad ECCI Bogota Colombia
Show AbstractA good understanding of the true plastic stresses and strains are of vital importance in studying metal forming processes and in the fracture mechanics field. The information extracted from the tensile test has been used traditionally to derive the flow curve and to compute plastic properties of the metals like the strength coefficient and the strain hardening exponent. However, knowledge of the plastic behavior beyond necking is uncertain due to the triaxial state of the stresses generated in the sample, and therefore, the flow curve does not replicate the uniaxial condition sought during the tensile test. In this research, a correction method for the post-necking section of the flow curve is proposed by linking nanoindentation measurements, performed along the tensile axis, to the flow curve. Three bulk materials were studied, steel G101800, copper C11000 and stainless steel S30400. The true flow curve after the onset of necking was corrected utilizing the nanohardness data converted to true stress values through the constraint factor C proposed by Tabor. It was observed that this constraint factor is not constant for all materials as reported in various preceding works. The corrected section of the curves showed a strain hardening behavior different to that before the onset of necking since the converted nanohardness to flow stress revealed the uniaxial character of the deformation, in this manner, separating out the effects of triaxiality in the uniaxial true flow curve.
9:00 AM - S3.13
Self-Healing of Cracks in Alumina by SiO2 and Core Shell SiC/SiO2 Nanoparticles
Pankaj Rajak 1 2 Rajiv Kalia 1 2 3 Aiicniro Nakano 1 2 3 Priya Vashishta 1 2 3
1University of Southern California Los Angeles United States2University of Southern California Los Angeles United States3University of Southern California Los Angeles United States
Show AbstractMultimillion-atom reactive molecular dynamics simulations are performed to study self-healing of cracks in Al2O3 by SiO2 nanoparticles and by SiC/SiO2 core shell nanoparticles embedded in the Al2O3 matrix. These simulations are carried out at 300 K and 1800 K for three different system sizes: 400Å*300Å*100Å, 600Å*300Å*150Å and 1600Å*800Å*400Å containing approximately 1.2 million to 60 million atoms. Brittle fracture is observed in alumina at 300K, while void nucleation and coalescence are observed to cause ductile fracture at 1800 K. Silica is found to be highly effective in healing cracks in the Al2O3 matrix at high temperatures. In addition, silica causes strain hardening and gives higher fracture toughness to alumina. Detailed analysis of atomistic mechanisms shows that crack healing is due to the flow SiO2 into the crack, which stops the crack growth. Results will be presented for (1) stress distributions in alumina with and without SiO2 and SiC/SiO2 core shell nanoparticles, (2) size and shape of cavities in the damage zone, and (3) atomic diffusivities of silicon and oxygen during healing of cracks and damage cavities in alumina.
This work was supported by Department of Energy (DOE), Office of Science, Basic Energy Sciences, Materials Science and Engineering Division, Grant #DE-FG02-04ER-46130. Some of the simulations were performed on the 262144-core IBM Blue Gene/Q supercomputer at Argonne National Laboratory under the DOE INCITE program.
9:00 AM - S3.14
Deformation and Failure Micromechanisms in Nanocrystalline Mg at the Atomic Scale
Garvit Agarwal 1 Ramakrishna R. Valisetty 2 Raju Namburu 2 Arunachalam M. Rajendran 3 Avinash M. Dongare 1
1University of Connecticut Storrs United States2US Army Research Laboratory Aberdeen Proving Ground United States3University of Mississippi University United States
Show AbstractHCP materials like magnesium and magnesium alloys due to their high strength to weight ratio have been deemed as promising candidates for next generation armor materials. A fundamental understanding of the deformation and failure response of the material during high strain rate deformation and shock loading is required in order to develop the capability to withstand ballistic/blast impact. The mechanical response of these materials is primarily determined by the active deformation modes operating (slip, twinning, etc.) as well as the micromechanisms (voids, shear bands, etc.) related to failure. Of particular importance is the role of twinning in Mg due to the limited number of slip systems in HCP metals. The aim of this study is to identify the contribution and dependence of different atomic scale deformation mechanisms like basal, prismatic, pyramidal slip and twinning on the loading conditions (strain rates, shock pressures etc.), microstructure of the system (loading orientation, grain size) and temperature.
Molecular dynamics (MD) simulations allow the characterization and investigation of the evolution of defect structures at the atomic scales during deformation and failure. Large-scale MD simulations are therefore carried out to investigate the deformation and failure micromechanisms in nanocrystalline Mg with grain sizes up to 100 nm under uniaxial strain and shock loading conditions. The evolution of twinning during deformation, the mechanisms for nucleation, growth, and coalescence of voids, and the variation of the spall strength as a function of strain rate and grain size in comparison to that for single crystal Mg will be presented.
9:00 AM - S3.16
Hydrogen Point Defects Weaken Interlayer Bonding in Layered Transition Metal Sulfide, Mackinawite (Fe1+xS)
Aravind Krishnamoorthy 1 Minh A Dinh 1 2 Bilge Yildiz 1 2
1MIT Cambridge United States2MIT Cambridge United States
Show AbstractThe protectiveness and performance of passive corrosion films as effective barrier layers depends greatly on their mechanical integrity under corrosion conditions. This mechanical stability is particularly important for two-dimensional layered surface films like mackinawite (Fe1+xS), which are known to fail by delamination, leading to exposure of the bare metal and subsequent catastrophic localized corrosion [1,2].
In an effort to explain the mechanism behind this facile failure, we show, by analogy to three-dimensional passive films [3,4], how hydrogen point defects generated by cathodic proton reduction can weaken the interlayer van der Waals bonding in mackinawite leading to delamination. Specifically, we use density functional theory calculations to identify dominant hydrogen defects in mackinawite based on their formation energies and quantify their effect on important mechanical metrics like binding energies, elastic moduli and tensile and shear strengths by mapping the stress-strain behavior of mackinawite crystals containing hydrogen point defects.
We find that hydrogen is most detrimental to film passivity and protectiveness when it is present as molecular H2 interstitials in the interlayer region. This configuration results in up to 80% degradation in the mechanical strength of mackinawite crystal and therefore increases the chances of passive film failure by delamination.
References
[1] D.W. Shoesmith, P. Taylor, M.G. Bailey, D.G. Owen, Journal of the Electrochemical Society 127 (1980) 1007.
[2] X.M. Dong, Q.C. Tian, Q.A. Zhang, Corrosion Engineering Science and Technology 45 (2010) 181.
[3] S.N. Rashkeev, K.W. Sohlberg, S. Zhuo, S.T. Pantelides, The Journal of Physical Chemistry C 111 (2007) 7175.
[4] M. Youssef, B. Yildiz, Physical Chemistry Chemical Physics 16 (2014) 1354.
9:00 AM - S3.17
Novel Cross-Slip Behavior of the Pyramidal Screw Dislocations in Mg
Mitsuhiro Itakura 1 Hideo Kaburaki 1 Masatake Yamaguchi 1 Tomohito Tsuru 1
1Japan Atomic Energy Inst Kashiwa, Chiba Japan
Show AbstractDislocations in fcc and hcp metals usually dissociate into a planar shape, and their slip is confined in the corresponding slip planes. Cross-slip usually requires transformation of the planar dislocation core into a linear, perfect dislocations, which requires some activation energy. Using an extensive DFT calculations, we have found a notable exception to this conventional view. The pyramidal screw dislocation in Mg consists of two partial dislocations connected by a stacking fault, and the stacking fault can migrate perpendicular to the plane by atom shuffling, enabling the dislocation to cross-slip without transforming into a perfect dislocation.
9:00 AM - S3.18
The Effect of a Reversible Shear Transformation on Plastic Deformation of Amorphous Materials
Nikolai Priezjev 1
1Wright State University Dayton United States
Show AbstractThe mechanical properties of bulk metallic glasses, such as high strength and low ductility, are both of fundamental scientific interest and technological importance. It is now well recognized that the plastic deformation of metallic glasses below their glass transition temperature involves irreversible rearrangements of small clusters of atoms. In the present study, molecular dynamics simulations are performed to investigate the plastic response of a model glass to a local shear transformation in a quiescent system. The deformation of the material is induced by a spherical inclusion that is gradually strained into an ellipsoid of the same volume and then reverted back into the sphere. We show that the number of cage-breaking events increases with increasing strain amplitude of the shear transformation. The results of numerical simulations indicate that the density of cage jumps is larger in the cases of weak damping or slow shear transformation. Remarkably, we also found that, for a given strain amplitude, the peak value of the density profiles is a function of the ratio of the damping coefficient and the time scale of the shear transformation.
9:00 AM - S3.19
Mechanisms of Plastic Deformation of Metal-Organic Framework-5
Kiettipong Banlusan 1 Edwin Antillon 1 Alejandro Strachan 1
1Purdue University West Lafayette United States
Show AbstractMetal-organic frameworks (MOFs) are a new class of porous materials with important applications ranging from gas sequestration to medicine. Understanding the processes of deformation of MOFs beyond the elastic limit is critical for several applications and processing where they are subjected to significant stresses. In this study, mechanisms of plastic deformation of metal-organic framework-5 (MOF-5) are investigated using large-scale molecular dynamics simulations. Atomistic-level details from the simulations of uniaxial compression along [001], [101], and [111] directions reveal that structural collapse of MOF-5 during compression occurs by slips along <100> directions on {001} planes due to the flexibility of the connection between Zn-O clusters and 1,4-benzenedicarboxylate (BDC) ligands. A dramatic decrease in stress of the system occurring during plastic deformation corresponds to the collapse of extensive free volume of the crystal structure. In addition to resolved shear stress, compressive stress normal to the active slip plane is essential for driving the plastic deformation depending on the orientation and this explains the anisotropic behaviors of this material. Plastic deformation of MOF-5 shows very interesting behaviors of strain localization that significantly affects the mechanical properties. Structural collapse propagates on the active slip planes along the directions perpendicular to slip directions and this is reminiscent of the glide of screw dislocation. The process exhibits interesting interaction between collapsing regions due to the effects of stress relieving by the volume shrinkage.
9:00 AM - S3.20
Experimental Variations in Nanoindentation Testing
Michelle L. Oyen 1
1University of Cambridge Cambridge United Kingdom
Show AbstractNanoindentation testing has a “typical” protocol for execution of experiments and for data analysis, but there are many alternatives available. The choice of experimental parameters and technique for the analysis of data can depend on the stiffness of the material, its hydration state, the material constitutive response, and the presence or absence of pores in the material. Systematic experiments have been undertaken to examine a wide range of choices for nanoindentation experiments, particularly in the context of biological materials. Samples have been tested in dry and rehydrated conditions. Spherical and Berkovich indenter probes have been utilized, including spheres with radii across several orders of magnitude. Data analysis has been considered within elastic-plastic (Oliver-Pharr), viscoelastic and viscoelastic-plastic and poroelastic frameworks. Results suggest that the hydration state, probe geometry and the limitations and assumptions of each analysis method significantly influence the measured mechanical properties in materials such as bone. This systematic study has been carried out to illustrate that the discrepancies in the nanoindentation properties found in the literature should not be attributed only to the differences between the materials themselves, but also to the testing and analysis protocols.
9:00 AM - S3.21
Nanoscale Chemical, Morphological and Mechanical Characterization of Polymer Matrix Composites
Dhriti Nepal 1 Allison Ecker 2 Brittanie Rooths 2 Jack Chalker 3 Evan Mungall 2 Stephen Barr 4 James Moller 5 Rajiv J. Berry 1 Timothy Breitzman 1
1Air Force Research Lab Wright Patterson AFB United States2University of Dayton Dayton United States3Wright State University Dayton United States4Universal Technology Corporation Dayton United States5Miami University Oxford United States
Show AbstractUnderstanding the molecular network structure of polymer matrix composite and its relationship with mechanical performances can lead to a complete understanding of failure mechanisms. This work investigates the nanoscopic nature of PMC matrix as well as interphases in terms of topography, chemical mapping/bonding, thermal and mechanical properties to find a bridge between nanoscopic, microscopic and macroscopic mechanical properties. It is guided by ongoing simulations aimed at an understanding of bond scission, interphase structure and mechanical properties at the nanoscale level via a multiscale computational approach. DGEBA epoxy resins with known chemical structures are processed in-house with varying molecular weight, controlled stoichiometric ratios (resin and cross-linker) and degrees of cure, both in the presence and absence of carbon fiber. AFM-IR is used to investigate the chemical structure at ~ 100 nm resolution, which is calibrated by controlled experimental characterization at varying conditions using FTIR (mid-IR and near-IR) in bulk. The chemical mapping results show that there is a variation in the chemical network structure between the matrix and the interphase as well as within the matrix. Control experiments using spectroscopy and thermal analysis confirm that this variability in the three-dimensional network is due to differences in cross-linker density and degree of cure. To understand if these local chemical variations have any influence on the property, thermal AFM was used to investigate the glass transition temperature and modulus mapping was done by Peak-force tapping AFM on ultramicrotome surfaces. It is confirmed that these network structure variations resulted in changes in local thermal and mechanical properties.
9:00 AM - S3.23
Exploiting Multi-Parametric Force Measurement to Map the Heterogeneity of Copolymers
Tuza Adeyemi Olukan 1 Yun-Hsiang Chang 1 Chia-Yun Lai 1 Harry Apostoleris 1 Khalid Marbou 1 Sergio Santos 1 Amal Al Ghaferi 1 Matteo Chiesa 1
1Masdar Institute of Science and Technology Abu Dhabi United Arab Emirates
Show AbstractHere we define a set of standard for providing data originating from atomic force microscopy AFM force measurements to be used to compare between sample properties, parameters or more generally, heterogeneity with a minimum number of points and conclusively. We exemplify our case by employing sapphire as a model system because it presents a homogeneous surface, that is, where the force of adhesion FAD should be homogeneous even in the nanoscale. After setting the standards, we select a more challenging model system consisting of copolymer to show that approximately 100 suffice to conclusively establish the presence of nanoscale heterogeneity with a resolution of 10pN in FAD. Employing the work of adhesion WAD as an alternative parameter requires approximately ~200 data points to arrive at the same conclusion. . Our findings reinforce the relevance of multi-parametric models and analysis in the field of nanoscale force spectroscopy.
Keywords: nanoscale, adhesion, work, force
9:00 AM - S3.24
Investigation on the Nanostructure Evolution in Thermotropic Copolyester by Simultaneous WAXS/SAXS
Adriana Reyes-Mayer 1 2 Bonifacio Alvarado-Tenorio 5 Rosario Benavente 3 Ernesto Perez 3 Arturo Molina-Ocampo 2 Michael Jaffe 4 Angel Romo-Uribe 1
1UNAM Cuernavaca Mexico2Universidad Autonoma Edo Morelos Cuernavaca Mexico3Instituto de Ciencia y Tecnologiacute;a de Poliacute;meros Madrid Spain4New Jersey Institute of Technology Newark United States5Universidad Autoacute;noma de Ciudad Juaacute;rez Cd. Juarez Mexico
Show AbstractThe thermally-induced nanostructure evolution in the thermotropic copolyester based on 1,3-hydroxybenzoic acid (B) and 2,4-hydroxynaphthoic acid (N) was investigated by small-angle X-ray scattering (SAXS). Heat treatments were carried out on extruded tapes at temperatures close to the solid-to-nematic transition (Ts→n) for up to five hours, under dry air conditions. Wide-angle X-ray scattering (WAXS) showed that the as-received tape exhibited fiber-like macromolecular orientation along the extrusion axis, along well defined crystalline reflections, denoting crystalline order. On the other hand, SAXS elucidated a highly anisotropic nanovoid morphology elongated along the extrusion axis over 17 nm and aspect ratios (axial/lateral dimension) in excess of 15. Upon heat treatment the crystalline reflections sharpened suggesting better molecular packing, and the degree of crystallinity increased. At the same time, SAXS showed that the lateral dimension of the nanovoids significantly decreased and the aspect ratio dramatically increased up to nearly 30, suggesting better molecular packing. There was also sharpening of azimuthal intensity around the 110 equatorial reflection, thus indicating an increase of molecular alignment along the extrusion axis. The quality of molecular alignment was quantified by the order parameter P2. The thermally-induced molecular and nanometer scale changes correlated with a significant increase of mechanical Young&’s modulus, E, along the extrusion axis.
9:00 AM - S3.25
Coupling of InAs and SbAs Nanoparticles in GaAs
Vladimir V. Chaldyshev 1 2 Nikolay A. Bert 1 Vladimir N. Nevedomskii 1 Valerii Preobrazhenskii 3 Mihail Putyato 3 Boris R. Semyagin 3
1Ioffe Institute Saint Petersburg Russian Federation2Peter the Great St.Petersburg Polytechnic University St. Petersburg Russian Federation3Institute of Semiconductor Physics Novosibirsk Russian Federation
Show AbstractComplex nanostructures with semiconductor quantum dots (SQDs) and metallic nanoparticles (MNP) assembled in a close vicinity of each other provide a possibility for hybridization of the local intrinsic excitations, namely excitons in SQD and plasmons in MNP. Such hybridization gives rise to interparticle energy transfer, enhancement of local electromagnetic field and light-matter interaction with numerous practical applications if the host material, fabrication technology and target structures are compatible with those common for device production.
In this paper we show a possibility to self-organize InAs SQDs and SbAs MNPs in a close vicinity to each other in the GaAs matrix. For that we develop a combined process of the molecular beam epitaxy (MBE), in which self-organization of the InAs SQDs was achieved in the Stranski-Krastanow mode, whereas self-organization of the SbAs MNPs was realized by the low-temperature MBE with the subsequent anneal. Coupling of the InAs SQDs and SbAs MNPs was revealed by transmission electron microscopy. The distance between the SQD and MNP arrays was 10 nm. This phenomenon originates from local strain-stress fields surrounding both InAs SQDs and SbAs MNPs. We analyze the specific feature of the mechanical fields and their impact on the self-organization processes in our system.
9:00 AM - S3.26
Bioinspired Ceramic-Polymer Campsite: Transparency, Piezoelectricity, and Stretchability Multifunctionality
Majid Minary 1
1The University of Texas at Dallas Richardson United States
Show AbstractNatural composites, like Nacre and wood, have attracted a lot of attention lately in the field of biomimetic materials given their unique combination of light-weight along with high strength and toughness. If the structure of natural composites could be successfully transferred to the conventionally man-made materials which are made of ceramics and polymer, it would benefit a wide area of fields, such as transportation and construction, biomedical implants and sensors. Inspired by unique microstructure of nacre, we present a new method to fabricate a material through layer-by-layer (LBL) deposition technique using an organic polymer poly(vinylidene fluoride-trifluoroethylene) [P(VDF-TrFE)] and an inorganic material (alumina platelets). The platelets are transferred to a silicon wafer substrate by dip-coating and a layer of organic polymer [P (VDF-T